碱激发矿渣胶凝材料的水化机理与性能研究综述

A review on the hydration mechanism and properties of alkali-activated slag cementitious materials

浏览量:

关键词:

碱激发矿渣胶凝材料;水化机理;力学性能;收缩;抗硫酸盐侵蚀性能

Key words:

Alkali-activated slag cementitious material; Hydration mechanism; Mechanical property; Shrinkage; Sulfate attack resistance

刊期:

2025年第7期

DOI:

10.19761/j.1000-4637.2025.07.097.05

文章编号:

基金项目:

新疆维吾尔自治区科技计划项目(2022D01C684、2022B03036)。

作者:

王泽平1,张 萌1,2,*,窦 智1,曹建青3,郭虎虎1

单位:

1.新疆大学 建筑工程学院,新疆 乌鲁木齐 830017;2.新疆土木工程技术研究中心,新疆 乌鲁木齐 830017;3.新疆工程学院 土木工程学院,新疆 乌鲁木齐 830023

摘要

摘   要:分析了矿渣的组成和碱激发机理,总结了碱激发矿渣胶凝材料的力学性能(抗压、抗折强度)和耐久性能(收缩、抗硫酸盐侵蚀性能)的研究现状,指出了当前研究的局限性,并对其未来发展方向进行了展望。

Abstract: The composition and alkali-activated mechanism of slag are analyzed, the current research statuses of mechanical properties(compressive strength and flexural strength) and durability(shrinkage and sulfate attack resistance) of alkali-activated slag cementitious materials are summarized, the limitations of the current research are pointed out, and the future direction of its development is prospected.

结论

碱激发矿渣胶凝材料具有早强、后期强度高、低碳等优势,但仍面临较多挑战,如原材料成分波动性大导致性能不稳定、收缩率较高制约工程应用等。未来研究可聚焦原材料标准化预处理、收缩调控技术开发、多尺度微观机理解析等方面,同时深化其在严酷环境(如硫酸盐、氯盐等盐渍土环境)下的长期耐久性能评估,以推动该绿色材料在实际工程中的规模化应用。

参考文献

[1] 徐阳晨,邢国华,赵嘉华.碱矿渣水泥基材料的干燥收缩及减缩技术研究进展[J].材料导报,2023,37(7):85-95.
[2] 姜奉华.碱激发矿渣微粉胶凝材料的组成、结构和性能的研究[D].西安:西安建筑科技大学,2008.
[3] WANG A G,ZHENG Y,ZHANG Z H,et al.The durability of alkali-activated materials in comparison with ordinary portland cements and concretes: A review[J].Engineering,2020,6(6):237-261.
[4] 史才军,何富强.碱激发水泥的类型与特点[J].硅酸盐学报,2012,40(1):69-75.
[5] 徐彬,蒲心诚.矿渣玻璃体微观分相结构研究[J].重庆建筑大学学报,1997(4):53-60.
[6] SUN J Y,GU X.Study on hydration mechanism of slag activated by alkaline[J].Advanced Materials Research,2011,374-377:1582-1588.
[7] QIANG F,ZHAO R Z,WEN R X,et al.Hydration characteristics and microstructure of alkali-activated slag concrete:A review[J].Engineering,2023,20(1):162-179.
[8] KUMAR S,GARCIA T P,TEIXEIRA P A,et al.Development of alkali activated cement from mechanically activated silico-manganese (SiMn) slag[J].Cement and Concrete Composites,2013,40:7-13.
[9] 权娟娟,王宁,郭磊,等.碱矿渣胶凝体系的水化特性及机理分析[J].硅酸盐通报,2016,35(7):2171-2176.
[10] ALY A M,El-FEKY M S,KOHAIL M,et al.Performance of geopolymer concrete containing recycled rubber[J].Construction and Building Materials,2019,207:136-144.
[11] El-TAIR A M,SHAROBIM K G,MOHAMMEDIN H,et al.Improving the reactivity of clay nano-partciles in high strength mortars through indirect sonication method[J].International Journal of Scientific and Technological Research,2020,9:1045-1054.
[12] TALAAT A,EMAD A,TAREK A,et al.Factors affecting the results of concrete compression testing: A review[J].Ain Shams Engineering Journal,2021,12(1):205-221.
[13] 周浩雪,马倩敏,郭荣鑫,等.养护方式对碱激发矿渣/粉煤灰胶凝材料抗压强度影响研究[J].材料导报,2024,38(增刊1):329-334.
[14]  BERNAL S A,GUTIERREZ R M,PEDRAZA A L,et al.Effect of binder content on the performance of alkali-activated slag concretes[J].Cement and Concrete Research,2011,41(1):1-8.
[15] KOMNITSAS K,ZAHARAKI D,PERDIKATSIS V.Effect of synthesis parameters on the compressive strength of low-calcium ferronickel slag inorganic polymers[J].Journal of Hazardous Materials,2009,161(2):760-768.
[16] 张耀君,赵永林,李海宏,等.水玻璃激发矿渣制备纳米地质聚合物研究[J].非金属矿,2009,32(1):39-41,44.
[17] 王玲玲,司晨玉,李畅,等.氢氧化钾-钠水玻璃激发剂对碱激发矿渣胶凝材料性能的影响[J].硅酸盐通报,2022,41(8):2654-2662,2695.
[18] 焦贞贞.碱激发矿渣胶凝材料砌块砌体基本力学性能研究[D].哈尔滨:哈尔滨工业大学,2019.
[19] LUO L,YAO W,LIANG G,et al.Workability, autogenous shrinkage and microstructure of alkali-activated slag/fly ash slurries: Effect of precursor composition and sodium silicate modulus[J].Journal of Building Engineering,2023,73:106712.
[20] 杨凌艳.碱激发矿渣微结构优化及性能研究[D].南京:东南大学,2015.
[21] MA Y,ZHANG B,WANG B,et al.Fluidity, mechanical properties, shrinkage of alkali-activated slag/stainless steel slag mortars with composite activators[J].Journal of Building Engineering,2023,75:106877.
[22] 孙小巍,吴陶俊.碱激发矿渣胶凝材料的试验研究[J].硅酸盐通报,2014,33(11):3036-3040.
[23] LOTHENBACH B,SCRIVENER K,HOOTON R D.Supplementary cementitious materials[J].Cement and Concrete Research,2011,41(12):1244-1256.
[24] MOUSAVINEZHAD S,GONZALES G J,TOLEDO W K,et al.A comprehensive study on non-proprietary ultra-high-performance concrete containing supplementary cementitious materials[J].Materials,2023,16(7):2622.
[25] BAI Z,HONG Z,PAN F,et al.A review on shrinkage-reducing methods and mechanisms of alkali-activated/geopolymer systems: Effects of chemical additives[J].Journal of Building Engineering,2022,49:104056.
[26] GUANG W L,WU Y.Effect of diatomite on the reaction kinetics, early-age chemical shrinkage and microstructure of alkali-activated slag cements[J].Construction and Building Materials,2023,376:131026.
[27] HOJATI M,FARSHAD R,ALEKSANDRA R.Drying shrinkage of alkali-activated cements: effect of humidity and curing temperature[J].Materials and Structures,2019,52(1):61-66.
[28] YE H L,ALEKSANDRA R.Shrinkage mechanisms of alkali-activated slag[J].Cement and Concrete Research,2016,88:126-135.
[29] HANSEN W,ALMUDAIHEEM J A.Ultimate drying shrinkage of concrete-influence of major parameters[J].Materials Journal,1987,84(3):217-223.
[30] FANG S,LAM S S E,LI B,et al.Effect of alkali contents, moduli and curing time on engineering properties of alkali activated slag[J].Construction and Building Materials,2020,249:118799.
[31] COLLINS F,SANJAYAN G J.Effect of pore size distribution on drying shrinking of alkali-activated slag concrete[J].Cement and Concrete Research,2000,30(9):1401-1406.
[32] AYDIN S,BARADAN B.Effect of activator type and content on properties of alkali-activated slag mortars[J].Composites Part B:Engineering,2014,57:166-172.
[33] CARTWRIGHT C,FARSHAD R,ALEKSANDRA R.Shrinkage characteristics of alkali-activated slag cements[J].Journal of Materials in Civil Engineering,2014,27(7):B4014007.
[34] ANTONIO A,MELO N,MARIA A C,et al.Drying and autogenous shrinkage of pastes and mortars with activated slag cement[J].Cement and Concrete Research,2007,38(4):565-574.
[35] 李爽,刘和鑫,杨永,等.碱激发矿渣/偏高岭土复合胶凝材料干燥收缩机理研究[J].材料导报,2021,35(4):4088-4091.
[36] SANT G,LURA P,WEISS J.Measurement of volume change in cementitious materials at early ages: Review of testing protocols and interpretation of results[J].Transportation Research Record,2006,1979(1):21-29.
[37] LEE N K,JANG J G,LEE H K.Shrinkage characteristics of alkali-activated fly ash/slag paste and mortar at early ages[J].Cement and Concrete Composites,2014,53:239-248.
[38] 李爽,刘青科,肖啸,等.碱激发矿渣/偏高岭土复合材自收缩特性研究[J].非金属矿,2023,46(1):91-94,98.
[39] LIANG G W,YAO W.Effect of diatomite on the reaction kinetics, early-age chemical shrinkage and microstructure of alkali-activated slag cements[J].Construction and Building Materials,2023,376:131026.
[40] 廖佳庆,杨长辉,陈科.碱矿渣水泥化学收缩研究[J].水泥,2008(4):6-8.
[41] FANG Y H,GU Y M,KANG Q B.Effect of fly ash, MgO and curing solution on the chemical shrinkage of alkali-activated slag cement[J].Advanced Materials Research,2010,168-170:2008-2012.
[42] CHEN W W,LI B,WANG J,et al.Effects of alkali dosage and silicate modulus on autogenous shrinkage of alkali-activated slag cement paste[J].Cement and Concrete Research,2021,141:106322.
[43] 吴智铨.膨胀剂对碱激发材料收缩影响研究[D].广州:广州大学,2021.
[44] 李军,单继雄,胡艳民,等.氧化钙膨胀剂减少碱激发矿渣混凝土自收缩的研究[J].混凝土,2023(1):78-81.
[45] 贺北斗.碱激发粉煤灰矿渣胶凝材料在硫酸盐侵蚀下的性能研究[D].西安:长安大学,2020.
[46] 孙道胜,叶哲,刘开伟,等.碱矿渣胶凝材料的固砂特性及抗硫酸盐侵蚀性能[J].材料导报,2020,34(10):10061-10067.
[47] 白应华,余胜,陈伟.碱矿渣混凝土抗硫酸盐侵蚀研究[J].混凝土,2019(9):43-46.
[48] YE H,CHEN Z,HUANG L.Mechanism of sulfate attack on alkali-activated slag: The role of activator composition[J].Cement and Concrete Research,2019,125:105868.
[49] ZHANG J,SHI C J,ZHANG Z H,et al.Reaction mechanism of sulfate attack on alkali-activated slag/fly ash cements[J].Construction and Building Materials,2022,318:126052.
[50] COPPOLA L,COFFETTI D,CROTTI E,et al.The durability of one-part alkali-activated slag-based mortars in different environments[J].Sustainability,2020,12(9):3561.
[51] MITHUN B M,NARASIMHAN M C.Performance of alkali activated slag concrete mixes incorporating copper slag as fine aggregate[J].Journal of Cleaner Production,2016,112:837-844.

引用本文

王泽平,张萌,窦智,等.碱激发矿渣胶凝材料的水化机理与性能研究综述[J].混凝土与水泥制品,2025(7):97-101.

WANG Z P,ZHANG M,DOU Z,et al.A review on the hydration mechanism and properties of alkali-activated slag cementitious materials[J].China Concrete and Cement Products,2025(7):97-101.


上一个: 固废基胶凝材料对水泥和混凝土性能的影响及机理分析

下一个: 酸激发钢渣对UHPC性能的影响及机理分析

相关文件