不同激发剂对钢渣活性及水泥强度的影响

The Influence of Different Activator on Activity of Steel Slag and Strength of Cement

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关键词:

钢渣;活性;激发剂;水泥强度;硫酸钠;铝酸钠;偏铝酸钠

Key words:

Steel slag; Activity; Activator;Compressive strength of cement; Sodium sulfate; Sodium aluminate; Sodium metaaluminate

刊期:

2018 No.4

DOI:

文章编号:

1000-4637(2018)04-07-05

基金项目:

国家自然科学基金项目(51672236);江苏省产学研前瞻性联合研究项目(BY2016065-35)。

作者:

王 毓1,2,张长森2,吴发红3,杨风玲2,李 杨2,朱宝贵2,冯桢哲2,胡志超2

单位:

1.安徽理工大学土木建筑学院,淮南232001;2.盐城工学院材料科学与工程学院,224051; 3.盐城工学院土木工程学院,224051

摘要

摘   要:研究了5种不同激发剂(单掺、复掺)对钢渣活性及水泥强度的影响。通过水泥细度负压筛、压力试验机、X射线衍射仪、扫描电子显微镜等测试和检测方法揭示了钢渣的宏观性能和微观结构的内在联系。结果表明,掺加了激发剂和糖蜜的钢渣粉磨效率更高。单组分激发剂中,掺入硫酸钠的钢渣试样早期强度提升明显;偏铝酸钠的早期强度很低而后期强度高。在复合激发剂中,硫酸钠与铝酸钠复掺的效果最好,28d强度较纯钢渣试样提高了42%,活性指数K28达到88.2%,其次是硫酸钠与硅酸钠复掺,28d钢渣强度较纯钢渣试样提升了35%,活性指数K28达到82.5%。

Abstract: The effects of 5 kinds of activators on the activity and strength of cenment with steel slag were studied. By means of cement fineness, negative pressure screen, pressure test machine, XRD and SEM, the macroscopic and microscopic internal relations of steel slag are revealed. The results show that the grinding efficiency of steel slag added with activator and molasses is higher. When the activators is singly added, the early strength of steel slag samples with sodium sulfate significantly enhanced, and early strength of steel slag samples with sodium aluminate is very low, but the later strength is high. When the activators is compound added, the compound effect of sodium sulfate and sodium aluminate admixture is the best, compared with the pure steel slag sample, its 28d strength increases 42%, and the K28 activity index reaches 88.2%, the followed compound effect is sodium sulfate and sodium silicate admixture, compared with the pure steel slag samples, the 28d strength increases 35%, and the K28 activity index reaches 82.5%.

结论

(1)掺加了激发剂和糖蜜的钢渣在相同粉磨的条件下,比不掺激发剂和糖蜜的钢渣粉磨效果更好,粉磨30min时,大于45μm的颗粒在5%左右,比表面积可达500m2/kg左右。
(2)在钢渣粉细度及比表面积的相同情况下,不同激发剂的激发效果不同,Na2SO4的早期强度(3d和7d)效果好,3d强度相比纯钢渣提高117%,7天强度亦提高了89%;而NaAlO2的后期强度(28d)效果较好,而在早期的强度很低;当采用激发剂复配时,Na2SO4和NaAlO2复配效果最好,钢渣水泥的早期和后期强度均明显提高,3d抗压强度提高133%,7d抗压强度提高了92%,28d抗压强度亦提高了42%,且钢渣活性指数K28达到88.2%。
(3)掺入激发剂后可以促进钢渣水泥的水化,如掺入Na2SO4和NaAlO2试样水化产物中出现大量的AFt钙矾石晶体和C-S-H凝胶等水化产,其水化速率快,试样结构密实,强度提高。

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引用本文

王毓,张长森,吴发红,等.不同激发剂对钢渣活性及水泥强度的影响[J].混凝土与水泥制品,2018(4):7-11.

WANG Y,ZHANG C S,WU F H,et al.The Influence of Different Activator on Activity of Steel Slag and Strength of Cement[J].China Concrete and Cement Products,2018(4):7-11.


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