苏州混凝土水泥制品研究院有限公司

头部文案

发布时间:2020-01-06 00:00:00
全国建材科技期刊
全国中文核心期刊
中国科技论文统计源期刊
万方数据-数字化期刊群入网期刊
中国学术期刊(光盘版)全文收录期刊
华东地区优秀科技期刊
江苏省期刊方阵“双效期刊”
中国期刊网全文收录期刊
中国科技期刊数据库全文收录期刊
蛋白质型发泡剂的制备及其对泡沫混凝土性能的影响
Preparation of Protein Foaming Agent and Its Effects on Properties of Foamed Concrete
2013年第11期
蛋白质型发泡剂;泡沫稳定性;复配改性;孔结构
Protein foaming agent; Foam stability; Compound modification; Pore structure
2013年第11期
1000-4637(2013)11-23-06
史星祥
苏州混凝土水泥制品研究院江苏省高耐久性混凝土工程技术研究中心,215004

史星祥

浏览量:
1000
摘 要:以鸡毛为原料,采用Ca(OH)2水解法制备蛋白质型发泡剂,系统考察原料预处理、Ca(OH)2用量、水解时间与水解温度对发泡剂泡沫性能的影响。并向该发泡剂中掺加正丁醇与粘性物质羧甲基纤维素钠(CMC)进行复配改性,以改善发泡剂泡沫性能。最后使用4种不同类型发泡剂制备泡沫混凝土,研究其对泡沫混凝土强度以及孔结构的影响。结果表明,制备蛋白质型发泡剂最佳工艺参数为:Ca(OH)210g、水解温度110℃、水解时间2h;复配改性时正丁醇与CMC掺量分别为0.2%、0.03%时,泡沫稳定性最好,1h泌水率由38.89%降至11.59%。以改性蛋白质型发泡剂制备的300kg/m3级泡沫混凝土,其强度相对其他3种发泡剂制备的要高,28d抗压强度达到0.85MPa,且其孔径在0.5mm左右,孔分布较为均匀规整。 Abstract: Protein foaming agent is produced by the method of Ca(OH)2 hydrolysis using chicken feather as the raw material, and the effects of pretreatment of raw material, mass of Ca(OH)2, hydrolysis time, hydrolysis temperature on the foam performance of the foaming agent are investigated systematically in this paper. The foam performance is further improved by compound modification with the addition of buryl alcohol and viscous substance sodium carboxy methyl cellulose (CMC). At last, the compressive strength and pore structure of foamed concrete prepared by four different kinds of foaming agent is also investigated. Results show that the best process parameters are 10g Ca(OH)2, hydrolysis temperature 110℃, hydrolysis time 2h. The simultaneous addition of 0.2% normal butanol and 0.03% CMC is proved the most effective to the foam stability, which presented its 1h bleeding ratio reducing from 38.89% to 11.59%. 300kg/m3 foamed concrete prepared by modified protein foaming agent with the 28d compressive strength 0.85MPa is founded to have higher strength than the others, and its pores distributed uniformly with the pore size 0.5mm.
英文名 : Preparation of Protein Foaming Agent and Its Effects on Properties of Foamed Concrete
刊期 : 2013年第11期
关键词 : 蛋白质型发泡剂;泡沫稳定性;复配改性;孔结构
Key words : Protein foaming agent; Foam stability; Compound modification; Pore structure
刊期 : 2013年第11期
DOI :
文章编号 : 1000-4637(2013)11-23-06
基金项目 :
作者 : 史星祥
单位 : 苏州混凝土水泥制品研究院江苏省高耐久性混凝土工程技术研究中心,215004

史星祥

摘要
参数
结论
参考文献
引用本文

摘   要:以鸡毛为原料,采用Ca(OH)2水解法制备蛋白质型发泡剂,系统考察原料预处理、Ca(OH)2用量、水解时间与水解温度对发泡剂泡沫性能的影响。并向该发泡剂中掺加正丁醇与粘性物质羧甲基纤维素钠(CMC)进行复配改性,以改善发泡剂泡沫性能。最后使用4种不同类型发泡剂制备泡沫混凝土,研究其对泡沫混凝土强度以及孔结构的影响。结果表明,制备蛋白质型发泡剂最佳工艺参数为:Ca(OH)210g、水解温度110℃、水解时间2h;复配改性时正丁醇与CMC掺量分别为0.2%、0.03%时,泡沫稳定性最好,1h泌水率由38.89%降至11.59%。以改性蛋白质型发泡剂制备的300kg/m3级泡沫混凝土,其强度相对其他3种发泡剂制备的要高,28d抗压强度达到0.85MPa,且其孔径在0.5mm左右,孔分布较为均匀规整。

Abstract: Protein foaming agent is produced by the method of Ca(OH)2 hydrolysis using chicken feather as the raw material, and the effects of pretreatment of raw material, mass of Ca(OH)2, hydrolysis time, hydrolysis temperature on the foam performance of the foaming agent are investigated systematically in this paper. The foam performance is further improved by compound modification with the addition of buryl alcohol and viscous substance sodium carboxy methyl cellulose (CMC). At last, the compressive strength and pore structure of foamed concrete prepared by four different kinds of foaming agent is also investigated. Results show that the best process parameters are 10g Ca(OH)2, hydrolysis temperature 110℃, hydrolysis time 2h. The simultaneous addition of 0.2% normal butanol and 0.03% CMC is proved the most effective to the foam stability, which presented its 1h bleeding ratio reducing from 38.89% to 11.59%. 300kg/m3 foamed concrete prepared by modified protein foaming agent with the 28d compressive strength 0.85MPa is founded to have higher strength than the others, and its pores distributed uniformly with the pore size 0.5mm.  

关键词:
蛋白质型发泡剂;泡沫稳定性;复配改性;孔结构
扫二维码用手机看
未找到相应参数组,请于后台属性模板中添加
(1)采用NaHSO3对鸡毛进行预处理能有效提高水解反应时的效率。预处理工艺为: NaHSO34g、预处理温度60℃、预处理时间4h,水解效率为100%;采用Ca(OH)2水解法制备蛋白质型发泡剂的工艺参数为: Ca(OH)210g、水解温度110℃、水解时间2h,将发泡剂母液稀释成40%溶液后,发泡倍数为21.43,1h泌水率为38.8%。
(2)采用正丁醇与CMC进行二元复配改性可有效改善蛋白质型发泡剂的泡沫性能,正丁醇与CMC掺量分别为0.2%、0.03%时,泡沫稳定性最好,1h泌水率由38.89%%降至11.59%。
(3)四种发泡剂制备的泡沫混凝土,FA-PM对应的抗压强度最高,28d达到0.85MPa;FA-R发泡剂经过改性后,泡沫稳定性增强,28d抗压强度较改性前提高了0.15MPa;FA-S泡沫稳定性最低,其泡沫混凝土强度也最低,28d仅为0.52MPa。
(4)发泡剂对泡沫混凝土的性能影响较大,泡沫稳定性越好,泡沫混凝土孔结构更加均匀、规整、有害孔越低、强度越高;泡沫稳定性越差,气孔越大、均匀性越差,甚至会出现连通孔的现象,不利于泡沫混凝土保温隔热。
[1] 李文博. 泡沫混凝土发泡剂性能及其泡沫稳定改性研究[D]. 大连: 大连理工大学, 2009.
[2] M R Jones, A McCarthy. Preliminary views on the potential of foamed concrete as a structural material[J]. Magazine of Concrete Research, 2005, 57(1): 21-31.
[3] Oyasato Yumiko, Toshida kentaro. Foam and method for producing the same[P]. JP2006096942A, 2006-04-13.
[4] Maldonado-valderram A J, Langevin D, Martin-Molina A, et al. Surface properties and foam stability of protein/surfactant mixtures. Theory and experiment[J]. Journal of Physical Chemistry C, 2007, 111(6): 2715-2723.
[5] 马志珺,李小云,马学雷, 等. 蛋白质型混凝土发泡剂的研究[J]. 建筑科学, 2009, 25(5): 73-76.
[6] 郑洁. 污泥蛋白发泡剂的制备与泡沫性能研究[D]. 天津: 天津大学, 2010.
[7] 刘佳奇, 霍冀川, 雷永林,等. 一种新型蛋白质混凝土发泡剂的研制及性能研究[J]. 现代化工, 2010, 30(3): 54-56.
[8] 王翠花. 泡沫混凝土制备技术研究[D]. 南京: 南京工业大学, 2006.
[9] 史星祥, 潘志华. 泡沫混凝土发泡剂的稳定性[J]. 精细化工, 2012, 29(5): 94-98.
[10] 闫振甲. 泡沫混凝土实用生产技术[M]. 北京: 化学工业出版社, 2006: 48.
[11] Schmitt, Silva, Bovay. Effect of Time on the Interfacial and Foaming Properties of β-Lactoglobulin/Acacia Gum Electrostatic Complexes and Coacervates at pH 4.2[J]. Langmuir, 2005(21): 7786-7795.
[12] 王翠花, 潘志华. 混凝土发泡剂的泡沫稳定性研究[J]. 化学建材, 2006, 22(3): 47-50.

相关文件

暂时没有内容信息显示
请先在网站后台添加数据记录。

关注《混凝土与水泥制品》

总访问量 468,401   网站统计

官方微信公众号关闭
苏州混凝土水泥制品研究院有限公司

关于我们    |    联系我们    |    订购杂志    |    回到顶部

版权所有:中国混凝土与水泥制品网  苏ICP备10086386号   网站建设:中企动力 苏州

版权所有:中国混凝土与水泥制品网

苏ICP备10086386号

网站建设:中企动力 苏州