盐碱-干湿条件下混凝土强度及耐久性问题研究

Study on Strength and Durability of Concrete under Saline-alkali-dry- wet Conditions

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关键词:

纳米混凝土;盐碱-干湿条件;抗压强度;质量损失率;相对动弹性模量

Key words:

Nano-concrete; Saline-alkali-dry-wet condition; Compressive strength; Mass loss rate; Relative dynamic modulus of elasticity

刊期:

2019年第11期

DOI:

10.19761/j.1000-4637.2019.09.012.05

文章编号:

基金项目:

四川省成都凉山工业园区项目管理及规划模式研究(5816)。

作者:

邓 鹏

单位:

西昌学院,615013

摘要

摘  要:分析了纳米CaCO3掺入量、盐碱浓度等因素对混凝土在盐碱-干湿循环后的强度及耐久性的影响,通过150次的干湿循环,研究了混凝土抗压强度耐蚀系数、质量损失率、相对动弹性模量等耐久性指标随干湿循环的变化规律。试验结果表明,掺入1%的纳米CaCO3可以使28 d混凝土试件获得较高的抗压强度,盐碱-干湿循环条件下2%掺量的纳米CaCO3混凝土试件强度下降最低。纳米CaCO3对混凝土干湿循环中后期的耐久性有明显的提高作用,其最佳掺量为2%,掺量超过2%后则会造成耐久性指标的下降。盐碱浓度对纳米混凝土耐久性的影响随干湿循环次数的增加而增大,且相对动弹模量较质量损失率指标更易受盐碱浓度的影响。
Abstract: The strength and durability of concrete after saline-alkali-dry-wet cycle were analyzed around the factors such as nano-CaCO3 content and saline-alkali concentration. Through the maximum 150 cycles of dry-wet cycle, the changing rules of durability indexes such as compressive strength, corrosion resistance coefficient, mass loss rate and relative dynamic elastic modulus of concrete with dry-wet cycle were studied. The experimental results show that 1% nano-CaCO3can increase the compressive strength of 28 d concrete specimens, and 2% nano-CaCO3 can reduce the strength decrease of concrete specimens at the lowest level under saline-alkali-dry-wet cycling conditions. The durability of concrete could be improved by nano-CaCO3 in the middle and late stage of dry-wet cycle, and the optimum content of nano-CaCO3 is 2%. As the content of nano-CaCO3 exceeds 2%, the durability index will decrease. The influence of saline-alkali concentration on the durability of nano-concrete increases with the growth of wet-dry cycles and the relative dynamic modulus of elasticity is more sensitive to the influence of saline-alkali concentration than the mass loss rate index.
     

结论

(1)乙醇胺(ETA)、四正丁基溴化胺(TBA)和氯化十六烷基吡啶(CPC)三种阳离子型阻锈剂的掺入对腐蚀电流影响不大,但腐蚀电流密度明显减小,可有效减缓钢筋地腐蚀速率,属于混合型阻锈剂。
(2)NaCl浓度低时,阻锈剂能更好地发挥阻锈效果,因此,需首先降低钢筋附近氯离子浓度,再在此基础上进行电迁移阻锈剂防护。
(3)CPC阻锈剂因其大分子量,阻锈率更高,其阻锈机理主要通过在钢筋表面吸附成膜而延缓钢筋的腐蚀过程。

(4)盐碱-干湿循环中后期,混凝土试件的质量损失率、相对动弹模量受纳米CaCO3影响变得显著,但纳米CaCO3掺量高于2%后反而会降低试件的耐久性指标。

(5)盐碱浓度对耐久性指标的影响随干湿循环次数的增加逐步明显,且纳米CaCO3混凝土的相对动弹模量受盐碱浓度的影响程度高于质量损失率。

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引用本文

邓鹏.盐碱-干湿条件下混凝土强度及耐久性问题研究[J].混凝土与水泥制品,2019(11):12-16.

DENG P.Study on Strength and Durability of Concrete under Saline-alkali-dry-wet Conditions[J].China Concrete and Cement Products,2019(11):12-16.

 


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