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ASR-氯盐腐蚀协同作用下混凝土的损伤特点
Distinguishing Characteristicts of Concrete Damage under Cooperation of ASR and Chloride Corrosion
2006年第1期
混凝土;碱硅酸反应;氯盐腐蚀;膨胀;动弹性模量损失;损伤
Concrete; Alkali Silica Reaction(ASR); Chloride corrosion; Expansion; Loss of dynamic elastic modulus; Damage
2006年第1期
1000-4637(2006)01-04-04
国家重点基础研究发展规划 (973项目) 项目(编号:2001CB610706)
沙建芳1,孙 伟2,詹炳根2,李天艳1
1. 江苏省建筑科学研究院,南京 210008; 2. 东南大学材料科学与工程系,南京 210096

沙建芳1,孙 伟2,詹炳根2,李天艳1

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摘 要: 以碱+氯盐复合溶液浸泡的方式进行了ASR-氯盐腐蚀协同作用下混凝土加速劣化的实验。通过定期测量长度和动弹性模量,研究了混凝土在承受ASR、氯盐腐蚀双重破坏因素作用下的损伤特点以及混凝土初始碱含量、氯盐溶液浓度对损伤发展的影响。试验结果表明,不同浸泡液中当混凝土碱含量高时,各龄期的膨胀值均大于混凝土低碱时的膨胀值,同期的动弹性模量损失也更大。浓度较高的氯盐溶液主要在短期内对ASR膨胀的加速显著,但浓度较低的氯盐溶液则具有持续的加速作用。ASR-氯盐腐蚀作用下动弹性模量变化的具体特点是:劣化初期混凝土动弹性模量即急剧下降,当剩余动弹性模量在70%左右时,其下降减缓,随后发展极其缓慢至完全失效。分析动弹模量损失和膨胀率之间的关系,发现膨胀率低于0.5%时动弹性模量对因膨胀引起的混凝土损伤更为敏感。 Abstract: By measuring the expansion rate and relative dynamic elasitc modulus of concrete speciments at different age, that are immersed in the solution with 1M NaOH and a few different contents of NaCl, the tests of concrete under twofold factors of ASR and chloride corrosion are carried out. The rezults show that the expansion of concrete with high alkali content, immersed in different solution and in different age, is greater than that with low aklali content, and the loss of dynamic elastic modulus of former is also greater. The solution with higher concentration of chloride will obviousely accelerate the ASR expansion, mainly in the short time of early age, but the solution with lower content of chloride will continually keep the acceleration. And the change of dynamic elastic modulus for this time is as follow: at the initial stage of deterioration the modulus decreases rapidly and when the remainded modulus is at about 70% the drop slows down, then the progress of decreasing is very slow and up to lose efficacy entirely. Analysed the relationship between the dynamic elastic modulus and expansian rate, it is found that the damage of concrete by expansion is more sensitive when the expansion rate is lower than 0.5%.
英文名 : Distinguishing Characteristicts of Concrete Damage under Cooperation of ASR and Chloride Corrosion
刊期 : 2006年第1期
关键词 : 混凝土;碱硅酸反应;氯盐腐蚀;膨胀;动弹性模量损失;损伤
Key words : Concrete; Alkali Silica Reaction(ASR); Chloride corrosion; Expansion; Loss of dynamic elastic modulus; Damage
刊期 : 2006年第1期
DOI :
文章编号 : 1000-4637(2006)01-04-04
基金项目 : 国家重点基础研究发展规划 (973项目) 项目(编号:2001CB610706)
作者 : 沙建芳1,孙 伟2,詹炳根2,李天艳1
单位 : 1. 江苏省建筑科学研究院,南京 210008; 2. 东南大学材料科学与工程系,南京 210096

沙建芳1,孙 伟2,詹炳根2,李天艳1

摘要
参数
结论
参考文献
引用本文

摘   要: 以碱+氯盐复合溶液浸泡的方式进行了ASR-氯盐腐蚀协同作用下混凝土加速劣化的实验。通过定期测量长度和动弹性模量,研究了混凝土在承受ASR、氯盐腐蚀双重破坏因素作用下的损伤特点以及混凝土初始碱含量、氯盐溶液浓度对损伤发展的影响。试验结果表明,不同浸泡液中当混凝土碱含量高时,各龄期的膨胀值均大于混凝土低碱时的膨胀值,同期的动弹性模量损失也更大。浓度较高的氯盐溶液主要在短期内对ASR膨胀的加速显著,但浓度较低的氯盐溶液则具有持续的加速作用。ASR-氯盐腐蚀作用下动弹性模量变化的具体特点是:劣化初期混凝土动弹性模量即急剧下降,当剩余动弹性模量在70%左右时,其下降减缓,随后发展极其缓慢至完全失效。分析动弹模量损失和膨胀率之间的关系,发现膨胀率低于0.5%时动弹性模量对因膨胀引起的混凝土损伤更为敏感。

Abstract: By measuring the expansion rate and relative dynamic elasitc modulus of concrete speciments at different age, that are immersed in the solution with 1M NaOH and a few different contents of NaCl, the tests of concrete under twofold factors of ASR and chloride corrosion are carried out. The rezults show that the expansion of concrete with high alkali content, immersed in different solution and in different age, is greater than that with low aklali content, and the loss of dynamic elastic modulus of former is also greater. The solution with higher concentration of chloride will obviousely accelerate the ASR expansion, mainly in the short time of early age, but the solution with lower content of chloride will continually keep the acceleration. And the change of dynamic elastic modulus for this time is as follow: at the initial stage of deterioration the modulus decreases rapidly and when the remainded modulus is at about 70% the drop slows down, then the progress of decreasing is very slow and up to lose efficacy entirely. Analysed the relationship between the dynamic elastic modulus and expansian rate, it is found that the damage of concrete by expansion is more sensitive when the expansion rate is lower than 0.5%.
 
关键词:
混凝土;碱硅酸反应;氯盐腐蚀;膨胀;动弹性模量损失;损伤
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(1)不同浸泡液中碱含量高的混凝土在各龄期的膨胀率均大于低碱混凝土,由此造成更为严重的损伤,因此,高碱量混凝土的同期动弹性模量损失也更大。
(2)浸泡溶液中氯盐浓度对混凝土膨胀值的影响与龄期有关,其中浓度较高的氯盐溶液主要在短期内对ASR膨胀的加速显著,但浓度较低的氯盐溶液具有持续加速作用。溶液盐度对混凝土动弹性模量损失的影响也因此与龄期有关。
(3)混凝土在ASR-氯盐腐蚀协同破坏作用下,其动弹性模量在劣化初期即急剧下降,当剩余动弹模量在70%左右时下降速率大大减缓,随后极其缓慢地发展至试件完全失效,这有别于材料损伤发展一般规律。
(4)在ASR-氯盐腐蚀加速劣化作用下,混凝土的动弹性模量损失和膨胀率之间具有较好的对应关系,动弹性模量可以表征ASR膨胀引起的材料损伤且对前期损伤尤为敏感。
[1] A Shayan. Effects of NaOH and NaCl Solutions and Temperature on the Behavior of Specimens Subjected to Accelerated AAR Tests [J]. Cement and Concrete Research, 1998, 28(1): 25-31
[2] M A Berube, J F Dorion, J Duchesne et al. Laboratory and field investigations of the influence of sodium chloride on alkali-silica reactivity [J]. Cement and Concrete Research, 2003, 33:77-84
[3] M A Berube, J Frenette. Testing Concrete for AAR in NaOH and NaCl solutions at 38℃ and 80℃ [J]. Cement and Concrete Composites, 1994, 16:189-198
[4] Chatterji S, Jensen A D, Thaulow N, et al. Studies of alkali-silica reaction. Part 3-Mechanisms by which NaCl and Ca(OH)2 affect the reaction[J]. Cement and Concrete Research, 1986, 16(2): 246~254
[5] M Kawamura, Makoto Ichise. Characteristics of Alkali-Silica Reaction in the Presence of Sodium and Calcium Chloride [J]. Cement and Concrete Research, 1990, 20: 757-766
[6] M Kawamura, K Takeuchi, A Sugiyama. Mechanisms of Expansion of Mortars Containing Reactive Aggregate in NaCl Solution [J]. Cement and Concrete Research, 1994, 24(4): 621-632
[7] M Kawamura, K Takeuchi, A Sugiyama. Mechanisms of the influence of externally supplied NaCl on the expansion of mortars containing reactive aggregate [J]. Magazine of Concrete Research, 1996, 46(176):237-248
 

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