张承志1,王爱勤2
混合材对碱-硅反应的作用 Ⅱ.混合材对碱-硅反应膨胀作用的机理
张承志1,王爱勤2
摘 要:在70℃条件下硅灰、矿渣和粉煤灰对碱-硅反应膨胀规律研究的基础上,进一步分析研究了混合材对碱-硅反应膨胀作用的机理。结果表明,混合材对碱-硅反应的作用主要是化学作用和表面物理化学作用。在适当的条件下,化学作用可以使碱-硅反应得到有效抑制,而表面物理化学作用只能使碱-硅反应得到延缓。混合材的化学作用和表面物理化学作用与体系中的Ca(OH)2含量有着密切的关系,在有大量Ca(OH)2存在的条件下,混合材不能有效地抑制碱-硅反应膨胀。只有当Ca(OH)2含量低到一定程度时,混合材才有可能抑制碱-硅反应膨胀。
Abstract: Based on study of the influence of silica fume, slag and fly ash on alkali-silica reaction under the condition of 70℃, the mechanism of the effect of mineral admixtures on alkali-silica reaction is studied further. The results show that the effects of mineral admixtures on alkali-silica reaction are mainly in chemistry effect and surface physichemistry effect. Under the suitable condition, the chemistry effect may make alkali-silica reaction to be inhibited effectively, but the surface physichemistry effect only make alkali-silica reaction to be delayed. The chemistry effect and the physichemistry effect of mineral admixture are closely relative to the content of Ca(OH)2 in system. Under the condition that there is a large quantity of Ca(OH)2 in system, the mineral admixture cannot inhibit alkali-silica reaction effectively. Only when the Ca(OH)2 in the system is very small, it is possible that the mineral admixture can inhibit alkali-silica reaction effectively.
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