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陈腐生活垃圾固化体的路用性能及其重金属稳定性研究
Road-constructional Properties of Solidified Body Made by aged Life-wastes and the Leaching Stability in Heavy Matals
2006年第6期
陈腐生活垃圾;固化剂;路用性能;浸出毒性;稳定性
Aged life-wastes; Solidification agent; Properties of road building materials; Leaching toxicity; Stability
2006年第6期
1000-4637(2006)06-08-04
王志新1,孙家瑛2,邱慧琴3,顾 超3,王星宇3
1.上海静安市政工程有限公司,200042; 2.上海市市政工程研究院,200036; 3.上海大学环境与应用化学工程学院,200072

王志新1,孙家瑛2,邱慧琴3,顾 超3,王星宇3

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摘 要:目前,生活垃圾处理技术仍以填埋为主,而填埋处理技术又面临着选址、年处理垃圾量增加和很多填埋场填埋年限到期的问题。受循环经济启发,将陈腐5年以上的填埋场生活垃圾,加入固化剂及工业废渣进行固化处理,可以解决填埋场内陈腐垃圾的出路问题,而制成的固化体强度及耐久性还可达到路用地基材料的技术要求,同时符合环境排放要求,不会带来二次污染,文章探讨了陈腐垃圾固化体重金属的稳定性问题。 Abstract: “Burying” is still a primary technology for the manergement of municipal wastes at the present. But it faces the lots of problems swch as choosing the locations, increasing the working capacities year by year and reaching the dateline for the greater parts of locations. There is a method can be used to solve the above-mentioned problems, i.e. to adding a solidification agent and the mineral admixtures of industrial wastes to the aged wastes baried over 5 years, then a solidified substance will be taken and which properties including strength and durability will meet the requirments of road building materials of standard, moreover, the leaching toxicity of heavy metals in this substance will be lower than the discharge requirments of national standard. So, the second pollution dose not take place. Besides, the stability of heavy metals in the solidified substance made of aged wastes is discussed.
英文名 : Road-constructional Properties of Solidified Body Made by aged Life-wastes and the Leaching Stability in Heavy Matals
刊期 : 2006年第6期
关键词 : 陈腐生活垃圾;固化剂;路用性能;浸出毒性;稳定性
Key words : Aged life-wastes; Solidification agent; Properties of road building materials; Leaching toxicity; Stability
刊期 : 2006年第6期
DOI :
文章编号 : 1000-4637(2006)06-08-04
基金项目 :
作者 : 王志新1,孙家瑛2,邱慧琴3,顾 超3,王星宇3
单位 : 1.上海静安市政工程有限公司,200042; 2.上海市市政工程研究院,200036; 3.上海大学环境与应用化学工程学院,200072

王志新1,孙家瑛2,邱慧琴3,顾 超3,王星宇3

摘要
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引用本文

摘   要:目前,生活垃圾处理技术仍以填埋为主,而填埋处理技术又面临着选址、年处理垃圾量增加和很多填埋场填埋年限到期的问题。受循环经济启发,将陈腐5年以上的填埋场生活垃圾,加入固化剂及工业废渣进行固化处理,可以解决填埋场内陈腐垃圾的出路问题,而制成的固化体强度及耐久性还可达到路用地基材料的技术要求,同时符合环境排放要求,不会带来二次污染,文章探讨了陈腐垃圾固化体重金属的稳定性问题。

Abstract: “Burying” is still a primary technology for the manergement of municipal wastes at the present. But it faces the lots of problems swch as choosing the locations, increasing the working capacities year by year and reaching the dateline for the greater parts of locations. There is a method can be used to solve the above-mentioned problems, i.e. to adding a solidification agent and the mineral admixtures of industrial wastes to the aged wastes baried over 5 years, then a solidified substance will be taken and which properties including strength and durability will meet the requirments of road building materials of standard, moreover, the leaching toxicity of heavy metals in this substance will be lower than the discharge requirments of national standard. So, the second pollution dose not take place. Besides, the stability of heavy metals in the solidified substance made of aged wastes is discussed.

 

关键词:
陈腐生活垃圾;固化剂;路用性能;浸出毒性;稳定性
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(1)用固化剂对陈腐垃圾进行固化,固化体的7d强度达到20.21MPa,28d强度达到22.97MPa,具有抗硫酸盐侵蚀和抗氯盐侵蚀的能力,完全能满足路用地基材料的路用性能要求。
(2)固化体3d时的重金属离子浸出毒性均小于国标的要求,而且随养护时间的增加各重金属离子浸出的质量浓度有逐渐减小的趋势,养护到56d时各重金属离子浸出质量浓度均远远小于国家标准的要求。在苛刻浸取环境下,重金属离子的TCLP浸出毒性在28d时都能够满足国家排放要求。而且随养护时间的增加,浸出毒性呈递减的趋势。
(3)四种代表重金属离子Zn、Cd、Cr、Pb的含量中有70%以上以非晶形氧化铁态、晶形氧化铁态、残渣态存在,以这三种形态存在的重金属离子很难浸出。而其它重金属离子则可进入C-S-H凝胶晶格中,经固化被稳定在固化体中,这种固化效果显著,不会给环境造成二次污染,同时随固化时间的增加,固化效果会不断提高。从而可以安全地在道路建设中使用。
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