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电镀污泥制备辅助性胶凝材料的试验研究
Experimental Research on Auxiliary Cementitious Materials Prepared by Electroplating Sludge
2018年第8期
电镀污泥;辅助性胶凝材料;力学性能;重金属溶出率;无害化处理
Electroplating sludge; Auxiliary cementitious material; Mechanical properties; Heavy metal dissolution; Innocuous treatment
2018年第8期
1000-4637(2018)08-81-04
国家自然科学基金项目(51672236);江苏高校品牌专业建设工程资助项目(PPZY2015A025)
王效良,张长森,倪佳佳,杨 旭,张萌萌
盐城工学院材料科学与工程学院,224051

王效良,张长森,倪佳佳,杨 旭,张萌萌

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摘 要:以工业固体废弃物电镀污泥和钢渣为原料,制备了一种辅助性胶凝材料。研究了不同配比的辅助性胶凝材料及辅助性胶凝材料掺量对水泥力学性能的影响,测定了重金属溶出率,并利用XRD、SEM研究了辅助性胶凝材料对水泥水化产物和微观形貌的影响。结果表明,适当比例的辅助性胶凝材料可以改善水泥强度,当电镀污泥∶钢渣=8∶2时,制备的辅助性胶凝材料在掺量为15%的情况下,其7 d、28 d强度比纯水泥熟料分别高5.9 MPa和1.4 MPa。此外,水泥浆体可以有效固化电镀污泥中的重金属,实现对电镀污泥的无害化处理。 Abstract: The preparation, microstructure and mechanical performance of auxiliary cementitious material prepared with electroplating sludge and steel slag as raw materials are studied. The effect of content and material ratio of auxiliary cementitious material on compressive strength of cement is studied. The microstructure and hydration products of cement with auxiliary cementitious material are characterized by XRD and SEM. In addition, the heavy metals elements in the electroplating sludge are also examined. The results show that the electroplating sludge could be mixed with steel slag at appropriate ratios to make auxiliary cementitious material that posses certain compressive strength. The auxiliary cementitious material could increase the compressive strength of cement when substitute for cement in appropriate proportion. Compared with portland cement, the compressive strength of specimen with 15% S2 at 7 d increases 5.9 MPa, meanwhile, 28 d increases 1.4 MPa. The heavy metals elements in the electroplating sludge can be effective cured in cement pastes and reduce the pollution to the environment.
英文名 : Experimental Research on Auxiliary Cementitious Materials Prepared by Electroplating Sludge
刊期 : 2018年第8期
关键词 : 电镀污泥;辅助性胶凝材料;力学性能;重金属溶出率;无害化处理
Key words : Electroplating sludge; Auxiliary cementitious material; Mechanical properties; Heavy metal dissolution; Innocuous treatment
刊期 : 2018年第8期
DOI :
文章编号 : 1000-4637(2018)08-81-04
基金项目 : 国家自然科学基金项目(51672236);江苏高校品牌专业建设工程资助项目(PPZY2015A025)
作者 : 王效良,张长森,倪佳佳,杨 旭,张萌萌
单位 : 盐城工学院材料科学与工程学院,224051

王效良,张长森,倪佳佳,杨 旭,张萌萌

摘要
参数
结论
参考文献
引用本文

摘   要:以工业固体废弃物电镀污泥和钢渣为原料,制备了一种辅助性胶凝材料。研究了不同配比的辅助性胶凝材料及辅助性胶凝材料掺量对水泥力学性能的影响,测定了重金属溶出率,并利用XRD、SEM研究了辅助性胶凝材料对水泥水化产物和微观形貌的影响。结果表明,适当比例的辅助性胶凝材料可以改善水泥强度,当电镀污泥∶钢渣=8∶2时,制备的辅助性胶凝材料在掺量为15%的情况下,其7 d、28 d强度比纯水泥熟料分别高5.9 MPa和1.4 MPa。此外,水泥浆体可以有效固化电镀污泥中的重金属,实现对电镀污泥的无害化处理。

Abstract: The preparation, microstructure and mechanical performance of auxiliary cementitious material prepared with electroplating sludge and steel slag as raw materials are studied. The effect of content and material ratio of auxiliary cementitious material on compressive strength of cement is studied. The microstructure and hydration products of cement with auxiliary cementitious material are characterized by XRD and SEM. In addition, the heavy metals elements in the electroplating sludge are also examined. The results show that the electroplating sludge could be mixed with steel slag at appropriate ratios to make auxiliary cementitious material that posses certain compressive strength. The auxiliary cementitious material could increase the compressive strength of cement when substitute for cement in appropriate proportion. Compared with portland cement, the compressive strength of specimen with 15% S2 at 7 d increases 5.9 MPa, meanwhile, 28 d increases 1.4 MPa. The heavy metals elements in the electroplating sludge can be effective cured in cement pastes and reduce the pollution to the environment.

关键词:
电镀污泥;辅助性胶凝材料;力学性能;重金属溶出率;无害化处理
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(1)电镀污泥和钢渣制备的辅助性胶凝材料以适当的比例取代水泥可以改善水泥的抗压强度,当电镀污泥∶钢渣=8∶2时,以15%取代水泥,可以使水泥的7 d强度提高5.9 MPa,28 d强度提高1.4 MPa。
(2)电镀污泥制备的辅助性胶凝材料掺入到水泥中后,其水化产物形成了更多的钙矾石晶体。
(3)电镀污泥中的重金属元素可有效地被固化在水泥硬化体中,实现对电镀污泥的无害化处理。
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