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聚丙二醇掺量对碱矿渣水泥砂浆性能和水化过程的影响
Effect of Polypropylene Glycol Content on Performance and Hydration Process of Alkali Activated Slag Cement Mortar
2020年第9期
碱激发矿渣;聚丙二醇;流动度;力学性能;干缩;电化学交流阻抗法
Alkali activated slag; Polypropylene glycol; Fluidity; Mechanical property; Shrinkage; EIS
2020年第9期
10.19761/j.1000-4637.2020.09.092.04
国家自然科学基金青年基金项目(51502029);山区桥梁结构与材料教育部工程研究中心开放基金项目(QLGCZX-JJ2017-1);广西道路结构与材料重点实验室开放课题项目(2018gxjgc1kf00);材料工程重庆市研究生联合培养基地基金资助项目(201905);重庆市教育委员会科学技术研究项目(KJQN201805502)。
张兰芳1,2,付彬鸿2,3,宋松松2,3,梁秋爽4
1.山区桥梁结构与材料教育部工程研究中心,重庆 400074;2.重庆交通大学 材料科学与工程学院,重庆 400074;3.重庆市智翔铺道技术工程有限公司,重庆 400074;4.重庆电讯职业学院,重庆402247

张兰芳1,2,付彬鸿2,3,宋松松2,3,梁秋爽4

张兰芳,付彬鸿,宋松松,等.聚丙二醇掺量对碱矿渣水泥砂浆性能和水化过程的影响[J].混凝土与水泥制品,2020(9):92-95.

ZHANG L F,FU B H,SONG S S,Effect of Polypropylene Glycol Content on Performance and Hydration Process of Alkali Activated Slag Cement Mortar[J].CHINA CONCRETE AND CEMENT PRODUCTS,2020(9):92-95.

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摘   要:研究了不同掺量聚丙二醇对碱激发矿渣(AAS)水泥砂浆流动度、力学性能和干缩的影响,并通过电化学交流阻抗法(EIS)探讨了其对砂浆水化过程的影响。结果表明,聚丙二醇的掺入能够显著提高AAS水泥砂浆的流动性,且掺量越大,流动性提高越明显,但砂浆密度有轻微降低。聚丙二醇的掺入降低了AAS水泥砂浆的抗折、抗压强度,但是随着龄期的增长,抗折、抗压强度均有所提高。掺入聚丙二醇能有效降低AAS砂浆的干缩。当聚丙二醇掺量为1%~3%时,各龄期的孔溶液电阻值(R1)较基准组有所减小,聚丙二醇抑制了AAS砂浆的水化反应。当掺量为5%~9%时,各龄期的R1大于基准组,AAS砂浆水化反应加快,且R1随着聚丙二醇掺量的增加而增大。 Abstract: The effect of different content of polypropylene glycol on the fluidity, mechanical properties and shrinkage of alkali-activated slag(AAS) cement mortar was studied, and its influence on hydration process of AAS mortar was discussed by electrochemical impedance spectroscopy(EIS). The results show that the polypropylene glycol can improve the fluidity of AAS cement mortar, and the greater the content of polypropylene glycol, the more obvious the fluidity increase, but the density of the mortar slightly decreases. The flexural and compressive strength of AAS cement mortar decrease with the addition of polypropylene glycol, but with the increase of age, the flexural and compressive strength increase. Polypropylene glycol can effectively reduce the shrinkage of AAS mortar. The pore solution resistance(R1) of AAS mortar is lower than that of the control group when the polypropylene glycol content is 1%~3%, polypropylene glycol inhibits the hydration reaction. When the content is 5%~9%, R1 is greater than that of the control group, the hydration reaction of AAS mortar is accelerated, and R1 increases with the increase of the polypropylene glycol content.
英文名 : Effect of Polypropylene Glycol Content on Performance and Hydration Process of Alkali Activated Slag Cement Mortar
刊期 : 2020年第9期
关键词 : 碱激发矿渣;聚丙二醇;流动度;力学性能;干缩;电化学交流阻抗法
Key words : Alkali activated slag; Polypropylene glycol; Fluidity; Mechanical property; Shrinkage; EIS
刊期 : 2020年第9期
DOI : 10.19761/j.1000-4637.2020.09.092.04
文章编号 :
基金项目 : 国家自然科学基金青年基金项目(51502029);山区桥梁结构与材料教育部工程研究中心开放基金项目(QLGCZX-JJ2017-1);广西道路结构与材料重点实验室开放课题项目(2018gxjgc1kf00);材料工程重庆市研究生联合培养基地基金资助项目(201905);重庆市教育委员会科学技术研究项目(KJQN201805502)。
作者 : 张兰芳1,2,付彬鸿2,3,宋松松2,3,梁秋爽4
单位 : 1.山区桥梁结构与材料教育部工程研究中心,重庆 400074;2.重庆交通大学 材料科学与工程学院,重庆 400074;3.重庆市智翔铺道技术工程有限公司,重庆 400074;4.重庆电讯职业学院,重庆402247

张兰芳1,2,付彬鸿2,3,宋松松2,3,梁秋爽4

张兰芳,付彬鸿,宋松松,等.聚丙二醇掺量对碱矿渣水泥砂浆性能和水化过程的影响[J].混凝土与水泥制品,2020(9):92-95.

ZHANG L F,FU B H,SONG S S,Effect of Polypropylene Glycol Content on Performance and Hydration Process of Alkali Activated Slag Cement Mortar[J].CHINA CONCRETE AND CEMENT PRODUCTS,2020(9):92-95.

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参考文献
引用本文

摘   要:研究了不同掺量聚丙二醇对碱激发矿渣(AAS)水泥砂浆流动度、力学性能和干缩的影响,并通过电化学交流阻抗法(EIS)探讨了其对砂浆水化过程的影响。结果表明,聚丙二醇的掺入能够显著提高AAS水泥砂浆的流动性,且掺量越大,流动性提高越明显,但砂浆密度有轻微降低。聚丙二醇的掺入降低了AAS水泥砂浆的抗折、抗压强度,但是随着龄期的增长,抗折、抗压强度均有所提高。掺入聚丙二醇能有效降低AAS砂浆的干缩。当聚丙二醇掺量为1%~3%时,各龄期的孔溶液电阻值(R1)较基准组有所减小,聚丙二醇抑制了AAS砂浆的水化反应。当掺量为5%~9%时,各龄期的R1大于基准组,AAS砂浆水化反应加快,且R1随着聚丙二醇掺量的增加而增大。

Abstract: The effect of different content of polypropylene glycol on the fluidity, mechanical properties and shrinkage of alkali-activated slag(AAS) cement mortar was studied, and its influence on hydration process of AAS mortar was discussed by electrochemical impedance spectroscopy(EIS). The results show that the polypropylene glycol can improve the fluidity of AAS cement mortar, and the greater the content of polypropylene glycol, the more obvious the fluidity increase, but the density of the mortar slightly decreases. The flexural and compressive strength of AAS cement mortar decrease with the addition of polypropylene glycol, but with the increase of age, the flexural and compressive strength increase. Polypropylene glycol can effectively reduce the shrinkage of AAS mortar. The pore solution resistance(R1) of AAS mortar is lower than that of the control group when the polypropylene glycol content is 1%~3%, polypropylene glycol inhibits the hydration reaction. When the content is 5%~9%, R1 is greater than that of the control group, the hydration reaction of AAS mortar is accelerated, and R1 increases with the increase of the polypropylene glycol content.

关键词:
水泥砂浆
the
of
aas
glycol
polypropylene
丙二醇
mortar
and
r1
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(1)PPG的掺入能提高AAS砂浆的流动度,且流动度随着PPG掺量的增加而逐渐增大,但砂浆的密度随着PPG掺量的增加有轻微降低。
(2)PPG的掺入降低了AAS砂浆的抗折、抗压强度;当掺量为3%时,砂浆28 d的抗折、抗压强度与基准组接近,即掺入3%的PPG对AAS砂浆的强度是有利的。
(3)PPG作为减缩剂掺入到AAS砂浆中能有效降低AAS砂浆的干缩,且PPG掺量越大,降低干缩效果越明显,但当掺量大于3%时,继续增大PPG掺量对AAS砂浆的干缩影响不大,即PPG的最佳掺量为3%。
(4)AAS砂浆3 d、7 d、28 d交流阻抗谱的变化趋势基本一致,都表现为典型的准Randles曲线。当PPG的掺量为1%~3%时,AAS砂浆的孔溶液电阻值减小,PPG抑制了AAS砂浆的水化反应。当掺量超过3%以后,孔溶液电阻值增大,水化反应加快。

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张兰芳,付彬鸿,宋松松,.聚丙二醇掺量对碱矿渣水泥砂浆性能和水化过程的影响[J].混凝土与水泥制品,2020(9):92-95.

ZHANG L F,FU B H,SONG S S,Effect of Polypropylene Glycol Content on Performance and Hydration Process of Alkali Activated Slag Cement Mortar[J].CHINA CONCRETE AND CEMENT PRODUCTS,2020(9):92-95.

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