王方刚1,2,陆加越1,2,杨 勇1,2,林 玮1,2,刘建忠1,2,龚志炜3
摘 要:通过净浆流动度、流变特性、吸附行为对自研发的减水剂进行了评价,优选出了降黏型超支化聚羧酸减水剂(PCE)。结果表明:同掺量时,超支化PCE-2、PCE-3的流动度大于梳状PCE-1;随着时间的延长,PCE-1流动度逐渐降低,而PCE-2和PCE-3的流动度在60 min内不损失,且略有提升;相同剪切速率下PCE-2和PCE-3的剪切应力和黏度均明显低于PCE-1,PCE-1存在剪切变稠现象,尤其是低水灰比(0.2)时剪切变稠现象更明显;PCE-2和PCE-3的吸附量远高于PCE-1,低水灰比(0.2)时PCE-1的吸附量与PCE-2和PCE-3的差距变小,但PCE-1在20 min后吸附量增长缓慢,明显低于PCE-2和PCE-3。降黏型超支化聚羧酸减水剂在实际工程应用中效果较好。
Abstract: The degree of paste fluidity, rheological behavior, and adsorption performance tests were used to evaluate the dispersion properties of PCE, and a viscosity reducing hyperbranched polycarboxylate superplasticizer was selected. The results show that the fluidity of hyperbranched PCE-2 and PCE-3 is greater than that of comb-like PCE-1 when the dosage is mixed, and the fluidity of PCE-1 decreases gradually with time, while the fluidity of PCE-2 and PCE-3 won′t lose within 60 min and increases slightly. At the same shear rate, the shear stress and viscosity of PCE-2 and PCE-3 are significantly lower than that of PCE-1, and PCE-1 has the phenomenon of shear thickening, especially at a low water-cement ratio(0.2). The adsorption capacity of PCE-2 and PCE-3 is much higher than that of PCE-1, and the difference between the adsorption capacity of PCE-1 and that of PCE-2 and PCE-3 is smaller at low water-cement ratio(0.2), and the adsorption capacity of PCE-1 increases very slowly after 20 min, which is significantly lower than that of PCE-2 and PCE-3. Viscosity reducing hyperbranched polycarboxylate superplasticizer has been successfully applied in actual engineering project.
王方刚,陆加越,杨勇,等.超高强混凝土降黏型超支化聚羧酸减水剂的应用研究[J].混凝土与水泥制品,2020(10):8-11,16.
WANG F G,LU J Y,YANG Y,etal.Study on the Application of Viscosity Reducing Hyperbranched Polycarboxylate Superplasticizer for UHSC[J].CHINA CONCRETE AND CEMENT PRODUCTS,2020(10):8-11,16.
超高强混凝土降黏型超支化聚羧酸减水剂的应用研究
王方刚1,2,陆加越1,2,杨 勇1,2,林 玮1,2,刘建忠1,2,龚志炜3
摘 要:通过净浆流动度、流变特性、吸附行为对自研发的减水剂进行了评价,优选出了降黏型超支化聚羧酸减水剂(PCE)。结果表明:同掺量时,超支化PCE-2、PCE-3的流动度大于梳状PCE-1;随着时间的延长,PCE-1流动度逐渐降低,而PCE-2和PCE-3的流动度在60 min内不损失,且略有提升;相同剪切速率下PCE-2和PCE-3的剪切应力和黏度均明显低于PCE-1,PCE-1存在剪切变稠现象,尤其是低水灰比(0.2)时剪切变稠现象更明显;PCE-2和PCE-3的吸附量远高于PCE-1,低水灰比(0.2)时PCE-1的吸附量与PCE-2和PCE-3的差距变小,但PCE-1在20 min后吸附量增长缓慢,明显低于PCE-2和PCE-3。降黏型超支化聚羧酸减水剂在实际工程应用中效果较好。
Abstract: The degree of paste fluidity, rheological behavior, and adsorption performance tests were used to evaluate the dispersion properties of PCE, and a viscosity reducing hyperbranched polycarboxylate superplasticizer was selected. The results show that the fluidity of hyperbranched PCE-2 and PCE-3 is greater than that of comb-like PCE-1 when the dosage is mixed, and the fluidity of PCE-1 decreases gradually with time, while the fluidity of PCE-2 and PCE-3 won′t lose within 60 min and increases slightly. At the same shear rate, the shear stress and viscosity of PCE-2 and PCE-3 are significantly lower than that of PCE-1, and PCE-1 has the phenomenon of shear thickening, especially at a low water-cement ratio(0.2). The adsorption capacity of PCE-2 and PCE-3 is much higher than that of PCE-1, and the difference between the adsorption capacity of PCE-1 and that of PCE-2 and PCE-3 is smaller at low water-cement ratio(0.2), and the adsorption capacity of PCE-1 increases very slowly after 20 min, which is significantly lower than that of PCE-2 and PCE-3. Viscosity reducing hyperbranched polycarboxylate superplasticizer has been successfully applied in actual engineering project.
王方刚,陆加越,杨勇,等.超高强混凝土降黏型超支化聚羧酸减水剂的应用研究[J].混凝土与水泥制品,2020(10):8-11,16.
WANG F G,LU J Y,YANG Y,etal.Study on the Application of Viscosity Reducing Hyperbranched Polycarboxylate Superplasticizer for UHSC[J].CHINA CONCRETE AND CEMENT PRODUCTS,2020(10):8-11,16.
摘 要:通过净浆流动度、流变特性、吸附行为对自研发的减水剂进行了评价,优选出了降黏型超支化聚羧酸减水剂(PCE)。结果表明:同掺量时,超支化PCE-2、PCE-3的流动度大于梳状PCE-1;随着时间的延长,PCE-1流动度逐渐降低,而PCE-2和PCE-3的流动度在60 min内不损失,且略有提升;相同剪切速率下PCE-2和PCE-3的剪切应力和黏度均明显低于PCE-1,PCE-1存在剪切变稠现象,尤其是低水灰比(0.2)时剪切变稠现象更明显;PCE-2和PCE-3的吸附量远高于PCE-1,低水灰比(0.2)时PCE-1的吸附量与PCE-2和PCE-3的差距变小,但PCE-1在20 min后吸附量增长缓慢,明显低于PCE-2和PCE-3。降黏型超支化聚羧酸减水剂在实际工程应用中效果较好。
Abstract: The degree of paste fluidity, rheological behavior, and adsorption performance tests were used to evaluate the dispersion properties of PCE, and a viscosity reducing hyperbranched polycarboxylate superplasticizer was selected. The results show that the fluidity of hyperbranched PCE-2 and PCE-3 is greater than that of comb-like PCE-1 when the dosage is mixed, and the fluidity of PCE-1 decreases gradually with time, while the fluidity of PCE-2 and PCE-3 won′t lose within 60 min and increases slightly. At the same shear rate, the shear stress and viscosity of PCE-2 and PCE-3 are significantly lower than that of PCE-1, and PCE-1 has the phenomenon of shear thickening, especially at a low water-cement ratio(0.2). The adsorption capacity of PCE-2 and PCE-3 is much higher than that of PCE-1, and the difference between the adsorption capacity of PCE-1 and that of PCE-2 and PCE-3 is smaller at low water-cement ratio(0.2), and the adsorption capacity of PCE-1 increases very slowly after 20 min, which is significantly lower than that of PCE-2 and PCE-3. Viscosity reducing hyperbranched polycarboxylate superplasticizer has been successfully applied in actual engineering project.
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