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碱矿渣-粉煤灰砂浆的耐高温性能及孔结构研究
Study on High Temperature Resistance and Pore Structure of Alkali Slag-Fly Ash Mortar
2021年第1期
碱激发胶凝材料;耐高温性能;抗压强度;孔结构;粉煤灰;砂浆
Alkali-activat cementitious materials; High temperature resistance; Compressive strength; Pore structure; Fly ash; Mortar
2021年第1期
10.19761/j.1000-4637.2021.01.090.05
海南省自然科学基金项目(519QN185);中国人民解放军海军科研项目(岛礁XX研究)。
高 帅1,吴岳峻2,唐海涛3,汪峻峰2,4,鲁刘磊3
1.海南大学 材料科学与工程学院,海南 海口 570228;2.海南大学 南海海洋资源利用国家重点实验室,海南 海口 570228;3.海南大学 土木建筑工程学院,海南 海口 570228;4.佛山科学技术学院 交通与土木建筑学院,广东 佛山 528225

高 帅1,吴岳峻2,唐海涛3,汪峻峰2,4,鲁刘磊3

高帅,吴岳峻,唐海涛,等.碱矿渣-粉煤灰砂浆的耐高温性能及孔结构研究[J].混凝土与水泥制品,2021(1):90-94.

GAO S,WU Y J,TANG H T,et al. Study on High Temperature Resistance and Pore Structure of Alkali Slag-fly Ash Mortar[J].CHINA CONCRETE AND CEMENT PRODUCTS,2021(1):90-94.

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摘   要:研究了不同粉煤灰掺量的碱矿渣-粉煤灰砂浆在20 ℃、200 ℃、400 ℃、600 ℃、800 ℃下力学性能的变化规律,并通过X射线衍射(XRD)、红外光谱(FTIR)和压汞法(MIP)分析了浆体的水化及孔结构。结果表明:掺粉煤灰可优化浆体的孔径分布,降低内部孔隙率,提高砂浆的耐高温性能,粉煤灰的适宜掺量为30%~50%;200 ℃时,掺30%粉煤灰砂浆的抗压强度最高,较20 ℃时提高了49.3%;600 ℃时,发生了固相反应,C-S-H凝胶减少,少害孔(20~50 nm)数量增加,砂浆保持了与20 ℃相当的抗压强度;800 ℃时,浆体生成大量钙黄长石,砂浆的抗压强度为20 ℃时的11.5%,基本失去工作性能。综合考虑,碱矿渣-粉煤灰砂浆的使用温度不宜超过600 ℃。 Abstract: The mechanical properties of alkali slag-fly ash mortar with different fly ash content at 20 ℃, 200 ℃, 400 ℃, 600 ℃, 800 ℃ were studied, and the hydration and pore structure were examined by using XRD, FTIR and MIP. The results show that adding fly ash can optimize the pore size distribution of the slurry, reduce the internal porosity, and improve the high-temperature resistance of the mortar, and the suitable blending amount is 30%~50%. At 200 ℃, the compressive strength of 30% fly ash mortar is the highest, which is 49.3% higher than that at 20 ℃. At 600 ℃, the mortar maintains the same compressive strength as 20 ℃, but the solid phase reaction occurs in the slurry, the number of less harmful pores (20~50 nm) increases and the C-S-H decreases. At 800 ℃, a large amount of calcium feldspar is formed in the slurry, and the compressive strength of the mortar is 11.5% of that at 20 ℃, which basically loses the working performance. Comprehensive consideration, the use temperature of alkali slag-fly ash mortar should not exceed 600 ℃.
英文名 : Study on High Temperature Resistance and Pore Structure of Alkali Slag-Fly Ash Mortar
刊期 : 2021年第1期
关键词 : 碱激发胶凝材料;耐高温性能;抗压强度;孔结构;粉煤灰;砂浆
Key words : Alkali-activat cementitious materials; High temperature resistance; Compressive strength; Pore structure; Fly ash; Mortar
刊期 : 2021年第1期
DOI : 10.19761/j.1000-4637.2021.01.090.05
文章编号 :
基金项目 : 海南省自然科学基金项目(519QN185);中国人民解放军海军科研项目(岛礁XX研究)。
作者 : 高 帅1,吴岳峻2,唐海涛3,汪峻峰2,4,鲁刘磊3
单位 : 1.海南大学 材料科学与工程学院,海南 海口 570228;2.海南大学 南海海洋资源利用国家重点实验室,海南 海口 570228;3.海南大学 土木建筑工程学院,海南 海口 570228;4.佛山科学技术学院 交通与土木建筑学院,广东 佛山 528225

高 帅1,吴岳峻2,唐海涛3,汪峻峰2,4,鲁刘磊3

高帅,吴岳峻,唐海涛,等.碱矿渣-粉煤灰砂浆的耐高温性能及孔结构研究[J].混凝土与水泥制品,2021(1):90-94.

GAO S,WU Y J,TANG H T,et al. Study on High Temperature Resistance and Pore Structure of Alkali Slag-fly Ash Mortar[J].CHINA CONCRETE AND CEMENT PRODUCTS,2021(1):90-94.

摘要
参数
结论
参考文献
引用本文

摘   要:研究了不同粉煤灰掺量的碱矿渣-粉煤灰砂浆在20 ℃、200 ℃、400 ℃、600 ℃、800 ℃下力学性能的变化规律,并通过X射线衍射(XRD)、红外光谱(FTIR)和压汞法(MIP)分析了浆体的水化及孔结构。结果表明:掺粉煤灰可优化浆体的孔径分布,降低内部孔隙率,提高砂浆的耐高温性能,粉煤灰的适宜掺量为30%~50%;200 ℃时,掺30%粉煤灰砂浆的抗压强度最高,较20 ℃时提高了49.3%;600 ℃时,发生了固相反应,C-S-H凝胶减少,少害孔(20~50 nm)数量增加,砂浆保持了与20 ℃相当的抗压强度;800 ℃时,浆体生成大量钙黄长石,砂浆的抗压强度为20 ℃时的11.5%,基本失去工作性能。综合考虑,碱矿渣-粉煤灰砂浆的使用温度不宜超过600 ℃。

Abstract: The mechanical properties of alkali slag-fly ash mortar with different fly ash content at 20 ℃, 200 ℃, 400 ℃, 600 ℃, 800 ℃ were studied, and the hydration and pore structure were examined by using XRD, FTIR and MIP. The results show that adding fly ash can optimize the pore size distribution of the slurry, reduce the internal porosity, and improve the high-temperature resistance of the mortar, and the suitable blending amount is 30%~50%. At 200 ℃, the compressive strength of 30% fly ash mortar is the highest, which is 49.3% higher than that at 20 ℃. At 600 ℃, the mortar maintains the same compressive strength as 20 ℃, but the solid phase reaction occurs in the slurry, the number of less harmful pores (20~50 nm) increases and the C-S-H decreases. At 800 ℃, a large amount of calcium feldspar is formed in the slurry, and the compressive strength of the mortar is 11.5% of that at 20 ℃, which basically loses the working performance. Comprehensive consideration, the use temperature of alkali slag-fly ash mortar should not exceed 600 ℃.

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(1)粉煤灰取代率为30%~50%时,可以提高碱矿渣-粉煤灰砂浆的耐高温性能。200 ℃时,掺加30%粉煤灰砂浆的抗压强度最高,较20 ℃时提高了49.3%;温度高于400 ℃后,抗压强度有所降低,600 ℃时,掺30%~50%粉煤灰的砂浆仍保持与20 ℃相当的抗压强度;碱矿渣-粉煤灰砂浆的使用温度不宜超过600 ℃。
(2)20 ℃时,碱矿渣与碱矿渣-粉煤灰砂浆的主要水化产物为C-S-H凝胶,掺粉煤灰会导致砂浆强度降低,掺70%粉煤灰砂浆的抗压强度较空白组降低了30.7%。
(3)200 ℃时,浆体中的C-S-H凝胶数量增加,细化了孔径,结构最致密;随着温度升高,C-S-H凝胶数量减少,不利于孔的优化; 800 ℃时,C-S-H凝胶基本消失,生成了大量的钙黄长石,砂浆抗压强度降至20 ℃时的11.5%,基本失去工作性能。

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高帅,吴岳峻,唐海涛,等.碱矿渣-粉煤灰砂浆的耐高温性能及孔结构研究[J].混凝土与水泥制品,2021(1):90-94.

GAO S,WU Y J,TANG H T,et al. Study on High Temperature Resistance and Pore Structure of Alkali Slag-fly Ash Mortar[J].CHINA CONCRETE AND CEMENT PRODUCTS,2021(1):90-94.

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