苏州混凝土水泥制品研究院有限公司

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碳纳米管活性粉末混凝土力学性能试验研究
Experimental Study on Mechanical Properties of Carbon Nanotube Reactive Powder Concrete
2021年第8期
活性粉末混凝土;碳纳米管;养护方式;力学性能
RPC; MWCNTs; Curing method; Mechanical property
2021年第8期
10.19761/j.1000-4637.2021.08.005.05
国家自然科学基金项目(51478345)。
刘桂凤1,朱 鼎1,陈正发1,张华娣1,李 岩2
1.常州大学 环境与安全工程学院,江苏 常州 213164;2.山东大展纳米材料有限公司,山东 滨州 256600

刘桂凤1,朱 鼎1,陈正发1,张华娣1,李 岩2

刘桂凤,朱鼎,陈正发,等.碳纳米管活性粉末混凝土力学性能试验研究[J].混凝土与水泥制品,2021(8):5-9.

LIU G F,ZHU D,CHEN Z F,et al.Experimental Study on Mechanical Properties of Carbon Nanotube Reactive Powder Concrete[J].CHINA CONCRETE AND CEMENT PRODUCTS,2021(8):5-9.

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摘   要:选择三种养护方式(标准养护、80 ℃热水养护、洒水养护)、设置5种碳纳米管掺量(0、0.05%、0.10%、0.15%、0.20%),研究了碳纳米管的分散性和掺量、养护方式对碳纳米管活性粉末混凝土力学性能的影响,并基于SEM测试结果对基体进行了微观分析。结果表明:经分散处理后的MWCNTs溶液的分散性和稳定性提高;相较于未分散处理的MWCNTs,MWCNTs分散液对活性粉末混凝土抗压、抗折强度的提高幅度更大;80 ℃热水养护下,当经分散处理后的MWCNTs掺量为0.10%时,MWCNTs活性粉末混凝土的抗压和抗折强度最大;标准养护和洒水养护下,当经分散处理后的MWCNTs掺量为0.15%时,MWCNTs活性粉末混凝土的抗压和抗折强度最大;SEM结果显示,胶凝材料二次水化生成了大量水化硅酸钙,减少了孔隙;碳纳米管能与基体紧密连接,阻止微裂缝的生成和扩展,起到了桥接和填充作用。 Abstract: Three kinds of curing methods(standard curing, 80 ℃ hot water curing and sprinkling curing) were selected, 5 kinds of carbon nanotube(MWCNTs) content(0, 0.05%, 0.10%, 0.15%, 0.20%)were set, the influence of the dispersibility and dosage of MWCNTs and curing methods on the mechanical properties of carbon nanotube reactive powder concrete was studied. The microstructure of matrix was characterized by SEM. The results show that the dispersion and stability of the MWCNTs solution after dispersion treatment are improved. Compared with the undispersed MWCNTs, the MWCNTs dispersion has a greater improvement in the compressive and flexural strength of reactive powder concrete. Under 80 ℃ hot water curing, when the content of dispersed MWCNTs is 0.10%, the compressive and flexural strength of MWCNTs reactive powder concrete reach the maximum. Under standard curing and sprinkling curtain curing, when the content of dispersed MWCNTs is 0.15%, the compressive and flexural strength of MWCNTs reactive powder concrete reach the maximum. SEM results show that the secondary hydration of the cementitious material produces a large amount of hydrated calcium silicate, which reduces porosity. MWCNTs can be closely connected with the matrix, preventing the formation and expansion of micro-cracks, and playing the role of bridging and filling.  
英文名 : Experimental Study on Mechanical Properties of Carbon Nanotube Reactive Powder Concrete
刊期 : 2021年第8期
关键词 : 活性粉末混凝土;碳纳米管;养护方式;力学性能
Key words : RPC; MWCNTs; Curing method; Mechanical property
刊期 : 2021年第8期
DOI : 10.19761/j.1000-4637.2021.08.005.05
文章编号 :
基金项目 : 国家自然科学基金项目(51478345)。
作者 : 刘桂凤1,朱 鼎1,陈正发1,张华娣1,李 岩2
单位 : 1.常州大学 环境与安全工程学院,江苏 常州 213164;2.山东大展纳米材料有限公司,山东 滨州 256600

刘桂凤1,朱 鼎1,陈正发1,张华娣1,李 岩2

刘桂凤,朱鼎,陈正发,等.碳纳米管活性粉末混凝土力学性能试验研究[J].混凝土与水泥制品,2021(8):5-9.

LIU G F,ZHU D,CHEN Z F,et al.Experimental Study on Mechanical Properties of Carbon Nanotube Reactive Powder Concrete[J].CHINA CONCRETE AND CEMENT PRODUCTS,2021(8):5-9.

摘要
参数
结论
参考文献
引用本文

摘   要:选择三种养护方式(标准养护、80 ℃热水养护、洒水养护)、设置5种碳纳米管掺量(0、0.05%、0.10%、0.15%、0.20%),研究了碳纳米管的分散性和掺量、养护方式对碳纳米管活性粉末混凝土力学性能的影响,并基于SEM测试结果对基体进行了微观分析。结果表明:经分散处理后的MWCNTs溶液的分散性和稳定性提高;相较于未分散处理的MWCNTs,MWCNTs分散液对活性粉末混凝土抗压、抗折强度的提高幅度更大;80 ℃热水养护下,当经分散处理后的MWCNTs掺量为0.10%时,MWCNTs活性粉末混凝土的抗压和抗折强度最大;标准养护和洒水养护下,当经分散处理后的MWCNTs掺量为0.15%时,MWCNTs活性粉末混凝土的抗压和抗折强度最大;SEM结果显示,胶凝材料二次水化生成了大量水化硅酸钙,减少了孔隙;碳纳米管能与基体紧密连接,阻止微裂缝的生成和扩展,起到了桥接和填充作用。

Abstract: Three kinds of curing methods(standard curing, 80 ℃ hot water curing and sprinkling curing) were selected, 5 kinds of carbon nanotube(MWCNTs) content(0, 0.05%, 0.10%, 0.15%, 0.20%)were set, the influence of the dispersibility and dosage of MWCNTs and curing methods on the mechanical properties of carbon nanotube reactive powder concrete was studied. The microstructure of matrix was characterized by SEM. The results show that the dispersion and stability of the MWCNTs solution after dispersion treatment are improved. Compared with the undispersed MWCNTs, the MWCNTs dispersion has a greater improvement in the compressive and flexural strength of reactive powder concrete. Under 80 ℃ hot water curing, when the content of dispersed MWCNTs is 0.10%, the compressive and flexural strength of MWCNTs reactive powder concrete reach the maximum. Under standard curing and sprinkling curtain curing, when the content of dispersed MWCNTs is 0.15%, the compressive and flexural strength of MWCNTs reactive powder concrete reach the maximum. SEM results show that the secondary hydration of the cementitious material produces a large amount of hydrated calcium silicate, which reduces porosity. MWCNTs can be closely connected with the matrix, preventing the formation and expansion of micro-cracks, and playing the role of bridging and filling.

 

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(1)结合多种分散方式,制备了稳定的MWCNTs分散液。相较于未分散处理的MWCNTs,MWCNTs分散液对活性粉末混凝土抗压强度、抗折强度的提高幅度更大,分别为29.3%和18.7%。
(2)80 ℃热水养护下,MWCNTs活性粉末混凝土的水化进程加快,前期强度增长幅度较高,但后期强度增长缓慢。28 d标准养护强度与洒水养护强度接近。综合考虑实际工程应用,洒水养护更符合实际施工需求。
(3)三种不同养护方式下MWCNTs活性粉末混凝土的强度均随着经分散处理后MWCNTs掺量的增加呈先增加后下降趋势。本文研究中,N组、W组抗压、抗折强度达到最大时,MWCNTs的最佳掺量为0.15%,H组中抗压、抗折强度达到最大时,MWCNTs的最佳掺量为0.10%。
(4)MWCNTs活性粉末混凝土的微观结构致密,其填充、桥接作用是MWCNTs活性粉末混凝土强度提高的关键。

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刘桂凤,朱鼎,陈正发,.碳纳米管活性粉末混凝土力学性能试验研究[J].混凝土与水泥制品,2021(8):5-9.

LIU G F,ZHU D,CHEN Z F,et al.Experimental Study on Mechanical Properties of Carbon Nanotube Reactive Powder Concrete[J].CHINA CONCRETE AND CEMENT PRODUCTS,2021(8):5-9.

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