王东明1,张世宇1,姚苏皖1,邹定华1,2
王东明,张世宇,姚苏皖,等.改性硅灰、粉煤灰对超高性能混凝土(UHPC)性能的影响[J].混凝土与水泥制品,2021(11):1-5,11.
WANG D M,ZHANG S Y,YAO S W,et al.Influence of Modified Silica Fume or Fly Ash on the Performance of Ultra-high Performance Concrete (UHPC)[J].China Concrete and Cement Products,2021(11):1-5,11.
改性硅灰、粉煤灰对超高性能混凝土(UHPC)性能的影响
王东明1,张世宇1,姚苏皖1,邹定华1,2
王东明,张世宇,姚苏皖,等.改性硅灰、粉煤灰对超高性能混凝土(UHPC)性能的影响[J].混凝土与水泥制品,2021(11):1-5,11.
WANG D M,ZHANG S Y,YAO S W,et al.Influence of Modified Silica Fume or Fly Ash on the Performance of Ultra-high Performance Concrete (UHPC)[J].China Concrete and Cement Products,2021(11):1-5,11.
摘 要:为降低超高性能混凝土(UHPC)黏度、提高工作性,采用硅烷(γ-缩水甘油醚氧丙基三甲氧基硅烷、十二烷基三甲氧基硅烷)对辅助胶凝材料(硅灰、粉煤灰)进行改性制备了自分散颗粒,并研究了其对UHPC工作性、抗压强度及微观结构的影响。结果表明:自分散颗粒降低了UHPC的黏度,提高了工作性;不同自分散颗粒对UHPC工作性的影响有较大差别,其中,粉煤灰和十二烷基三甲氧基硅烷制备的自分散颗粒效果最好;自分散颗粒抑制胶凝材料的早期水化,降低UHPC早期抗压强度;不同自分散颗粒对UHPC的28 d抗压强度影响也各不相同,采用粉煤灰和十二烷基三甲氧基硅烷制备的自分散颗粒提高了UHPC的28 d抗压强度,其他自分散颗粒降低了28 d抗压强度。
Abstract: In order to reduce viscosity and promote workability of fresh ultra-high performance concrete(UHPC), self-dispersing particles were prepared by using supplementary cementitious materials(fly ash and silica fume) modified by silanes( γ-glycidoxypropyltrimethoxysilan and dodecyltrimethoxysilane), and the workability, compressive strength and microstructure of UHPC were investigated. The results show that viscosity of fresh UHPC decreases, and the workability increases when self-dispersing particles are employed. The influence of different self-dispersing particles on workability is quite different. Self-dispersing particles prepared from fly ash modified by dodecyltrimethoxysilane show the highest effectiveness. Early age hydration of cementitious materials is inhibited by self-dispersing particles and compressive strength of UHPC decreases. Different self-dispersing particles have different effects on the 28 d compressive strength of UHPC. Self-dispersing particles prepared from fly ash and dodecyltrimethoxysilane increase the 28 d compressive strength of UHPC, while other self-dispersing particles reduce the 28 d compressive strength of UHPC.
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