苏州混凝土水泥制品研究院有限公司

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发布时间:2020-01-06 00:00:00
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改性硅灰、粉煤灰对超高性能混凝土(UHPC)性能的影响
Influence of Modified Silica Fume or Fly Ash on the Performance of Ultra-high Performance Concrete (UHPC)
2021年第11期
超高性能混凝土;辅助胶凝材料;自分散颗粒;工作性;抗压强度;硅灰;粉煤灰
Ultra-high performance concrete; Supplementary cementitious material; Self-dispersing particle; Workability; Compressive strength; Silica fume; Fly ash
2021年第11期
10.19761/j.1000-4637.2021.11.001.06
国家自然科学基金资助项目(U1604117)。
王东明1,张世宇1,姚苏皖1,邹定华1,2
1.河南理工大学 材料科学与工程学院,河南 焦作 454000;2.河南理工大学 河南省深地材料科学与技术重点实验室,河南 焦作 454000

王东明1,张世宇1,姚苏皖1,邹定华1,2

王东明,张世宇,姚苏皖,等.改性硅灰、粉煤灰对超高性能混凝土(UHPC)性能的影响[J].混凝土与水泥制品,2021(11):1-5,11.

WANG D M,ZHANG S Y,YAO S W,et al.Influence of Modified Silica Fume or Fly Ash on the Performance of Ultra-high Performance Concrete (UHPC)[J].China Concrete and Cement Products,2021(11):1-5,11.

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摘   要:为降低超高性能混凝土(UHPC)黏度、提高工作性,采用辅助胶凝材料(硅灰、粉煤灰)和硅烷(γ-缩水甘油醚氧丙基三甲氧基硅烷、十二烷基三甲氧基硅烷)进行改性制备了自分散颗粒,并研究了其对UHPC工作性、抗压强度及微观结构的影响。结果表明:自分散颗粒降低了UHPC的黏度,提高了工作性;不同自分散颗粒对UHPC工作性的影响有较大差别,其中,粉煤灰和十二烷基三甲氧基硅烷制备的自分散颗粒效果最好;自分散颗粒抑制胶凝材料的早期水化,降低UHPC早期抗压强度;不同自分散颗粒对UHPC的28 d抗压强度影响也各不相同,采用粉煤灰和十二烷基三甲氧基硅烷制备的自分散颗粒提高了UHPC的28 d抗压强度,其他自分散颗粒降低了28 d抗压强度。 Abstract: In order to reduce viscosity and promote workability of fresh ultra-high performance concrete(UHPC), self-dispersing particles were prepared by using supplementary cementitious materials(fly ash and silica fume) modified by silanes( γ-glycidoxypropyltrimethoxysilan and dodecyltrimethoxysilane), and the workability, compressive strength and microstructure of UHPC were investigated. The results show that viscosity of fresh UHPC decreases, and the workability increases when self-dispersing particles are employed. The influence of different self-dispersing particles on workability is quite different. Self-dispersing particles prepared from fly ash modified by dodecyltrimethoxysilane show the highest effectiveness. Early age hydration of cementitious materials is inhibited by self-dispersing particles and compressive strength of UHPC decreases. Different self-dispersing particles have different effects on the 28 d compressive strength of UHPC. Self-dispersing particles prepared from fly ash and dodecyltrimethoxysilane increase the 28 d compressive strength of UHPC, while other self-dispersing particles reduce the 28 d compressive strength of UHPC.
英文名 : Influence of Modified Silica Fume or Fly Ash on the Performance of Ultra-high Performance Concrete (UHPC)
刊期 : 2021年第11期
关键词 : 超高性能混凝土;辅助胶凝材料;自分散颗粒;工作性;抗压强度;硅灰;粉煤灰
Key words : Ultra-high performance concrete; Supplementary cementitious material; Self-dispersing particle; Workability; Compressive strength; Silica fume; Fly ash
刊期 : 2021年第11期
DOI : 10.19761/j.1000-4637.2021.11.001.06
文章编号 :
基金项目 : 国家自然科学基金资助项目(U1604117)。
作者 : 王东明1,张世宇1,姚苏皖1,邹定华1,2
单位 : 1.河南理工大学 材料科学与工程学院,河南 焦作 454000;2.河南理工大学 河南省深地材料科学与技术重点实验室,河南 焦作 454000

王东明1,张世宇1,姚苏皖1,邹定华1,2

王东明,张世宇,姚苏皖,等.改性硅灰、粉煤灰对超高性能混凝土(UHPC)性能的影响[J].混凝土与水泥制品,2021(11):1-5,11.

WANG D M,ZHANG S Y,YAO S W,et al.Influence of Modified Silica Fume or Fly Ash on the Performance of Ultra-high Performance Concrete (UHPC)[J].China Concrete and Cement Products,2021(11):1-5,11.

摘要
参数
结论
参考文献
引用本文

摘   要:为降低超高性能混凝土(UHPC)黏度、提高工作性,采用硅烷(γ-缩水甘油醚氧丙基三甲氧基硅烷、十二烷基三甲氧基硅烷)对辅助胶凝材料(硅灰、粉煤灰)进行改性制备了自分散颗粒,并研究了其对UHPC工作性、抗压强度及微观结构的影响。结果表明:自分散颗粒降低了UHPC的黏度,提高了工作性;不同自分散颗粒对UHPC工作性的影响有较大差别,其中,粉煤灰和十二烷基三甲氧基硅烷制备的自分散颗粒效果最好;自分散颗粒抑制胶凝材料的早期水化,降低UHPC早期抗压强度;不同自分散颗粒对UHPC的28 d抗压强度影响也各不相同,采用粉煤灰和十二烷基三甲氧基硅烷制备的自分散颗粒提高了UHPC的28 d抗压强度,其他自分散颗粒降低了28 d抗压强度。

Abstract: In order to reduce viscosity and promote workability of fresh ultra-high performance concrete(UHPC), self-dispersing particles were prepared by using supplementary cementitious materials(fly ash and silica fume) modified by silanes( γ-glycidoxypropyltrimethoxysilan and dodecyltrimethoxysilane), and the workability, compressive strength and microstructure of UHPC were investigated. The results show that viscosity of fresh UHPC decreases, and the workability increases when self-dispersing particles are employed. The influence of different self-dispersing particles on workability is quite different. Self-dispersing particles prepared from fly ash modified by dodecyltrimethoxysilane show the highest effectiveness. Early age hydration of cementitious materials is inhibited by self-dispersing particles and compressive strength of UHPC decreases. Different self-dispersing particles have different effects on the 28 d compressive strength of UHPC. Self-dispersing particles prepared from fly ash and dodecyltrimethoxysilane increase the 28 d compressive strength of UHPC, while other self-dispersing particles reduce the 28 d compressive strength of UHPC.

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(1)自分散颗粒可降低UHPC的黏度,提高其工作性,但不同硅烷与辅助胶凝材料制备的自分散颗粒对UHPC工作性改善效果不同。
(2)虽然自分散颗粒未生成新的水化产物,但其对胶凝材料的水化过程、特别是火山灰反应有明显影响。自分散颗粒抑制了水泥的早期水化,UHPC早期抗压强度降低。
(3)UHPC的孔结构受自分散颗粒的影响,且不同自分散颗粒对不同种孔体积的影响也不同。
(4)自分散颗粒中,粉煤灰和DTMS制备的自分散颗粒对UHPC性能的提高效果最好。掺这种自分散颗粒的UHPC工作性良好,早期抗压强度降低幅度小,28 d抗压强度提高。

(5)自分散颗粒对UHPC工作性、水化、微观结构及强度发展的影响均表现出复杂的规律。解释这些现象需要进一步研究硅烷在硅灰和粉煤灰表面的吸附行为以及孔溶液作用下的脱附行为,明确产生这些现象的机理,以更好地指导自分散颗粒的设计与制备。

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王东明,张世宇,姚苏皖,.改性硅灰、粉煤灰对超高性能混凝土(UHPC)性能的影响[J].混凝土与水泥制品,2021(11):1-5,11.

WANG D M,ZHANG S Y,YAO S W,et al.Influence of Modified Silica Fume or Fly Ash on the Performance of Ultra-high Performance Concrete (UHPC)[J].China Concrete and Cement Products,2021(11):1-5,11.

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