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低温环境下石灰岩机制砂砂浆抗硫酸盐侵蚀性能研究
Sulfate Resistance of Limestone Manufactured Sand Mortar in Low Temperature Environment
2022年第1期
石灰岩机制砂;石粉;硫酸盐侵蚀;低温;碳硫硅钙石
Limestone manufactured sand; Rock fine; Sulfate attack; Low temperature; Thaumasite
2022年第1期
10.19761/j.1000-4637.2022.01.022.05
江西省交通运输厅科技计划项目(2020H0002)。
邓俊双1,徐志华1,李北星2,李 龙2
1.江西省交通工程集团有限公司,江西 南昌330000;2.武汉理工大学 硅酸盐建筑材料国家重点实验室,湖北 武汉430070

邓俊双1,徐志华1,李北星2,李 龙2

邓俊双,徐志华,李北星,等.低温环境下石灰岩机制砂砂浆抗硫酸盐侵蚀性能研究[J].混凝土与水泥制品,2022(1):22-26.

DENG J S,XU Z H,LI B X,et al.Sulfate Resistance of Limestone Manufactured Sand Mortar in Low Temperature Environment[J].China Concrete and Cement Products,2022(1):2022(1):22-26.

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摘   要:为研究低温环境下石灰岩机制砂及石粉对混凝土抗硫酸盐侵蚀性能的影响,以掺/未掺石灰岩石粉的机制砂砂浆、掺/未掺石灰岩石粉的天然砂砂浆为模拟对象,结合硫酸盐腐蚀介质及低温环境特点,采用温度(5±1)℃的5%的MgSO4溶液模拟服役环境,对比研究了不同腐蚀龄期(0 d、60 d、90 d、210 d、270 d、360 d)试件的外观和强度变化,并基于XRD、FTIR测试分析了侵蚀产物。结果表明:随着龄期的增长,侵蚀方式由传统的钙矾石型硫酸盐侵蚀逐渐过渡到以碳硫硅酸钙为侵蚀产物的TSA岩侵蚀;石灰岩机制砂和石粉均能促使砂浆产生TSA侵蚀,且石粉的影响更加明显。 Abstract: In order to study the influence of limestone manufactured sand and limestone rock fines on the sulfate resistance of concrete under low temperature environment, the two kinds of manufactured sand mortars mixed with or without limestone rock fines, and the two kinds of natural sand mortars incorporated with or without limestone rock fines were used as the simulate objects. Combined with the characteristics of sulfate corrosion medium and low temperature environment, 5% magnesium sulfate solution at (5±1)℃ was used to simulate the service environment. The changes of appearance and strength for the mortar specimens at different corrosion ages (0 d, 60 d, 90 d, 210 d, 270 d, 360 d) were compared and studied, and the corrosion products were analyzed by X-ray diffraction (XRD) and fourier transform infrared spectroscopy (FTIR). The results show that with the increase of erosion age, the erosion mode gradually transits from traditional ettringite type sulfate attack to thaumasite sulfate attack (TSA) with thaumasite as the erosion product. Limestone manufactured sand and limestone rock fines all can promote the TSA of mortar and concrete, and the effect of limestone rock fines is more obvious. 
英文名 : Sulfate Resistance of Limestone Manufactured Sand Mortar in Low Temperature Environment
刊期 : 2022年第1期
关键词 : 石灰岩机制砂;石粉;硫酸盐侵蚀;低温;碳硫硅钙石
Key words : Limestone manufactured sand; Rock fine; Sulfate attack; Low temperature; Thaumasite
刊期 : 2022年第1期
DOI : 10.19761/j.1000-4637.2022.01.022.05
文章编号 :
基金项目 : 江西省交通运输厅科技计划项目(2020H0002)。
作者 : 邓俊双1,徐志华1,李北星2,李 龙2
单位 : 1.江西省交通工程集团有限公司,江西 南昌330000;2.武汉理工大学 硅酸盐建筑材料国家重点实验室,湖北 武汉430070

邓俊双1,徐志华1,李北星2,李 龙2

邓俊双,徐志华,李北星,等.低温环境下石灰岩机制砂砂浆抗硫酸盐侵蚀性能研究[J].混凝土与水泥制品,2022(1):22-26.

DENG J S,XU Z H,LI B X,et al.Sulfate Resistance of Limestone Manufactured Sand Mortar in Low Temperature Environment[J].China Concrete and Cement Products,2022(1):2022(1):22-26.

摘要
参数
结论
参考文献
引用本文

摘   要:为研究低温环境下石灰岩机制砂及石粉对混凝土抗硫酸盐侵蚀性能的影响,以掺/未掺石灰岩石粉的机制砂砂浆、掺/未掺石灰岩石粉的天然砂砂浆为模拟对象,结合硫酸盐腐蚀介质及低温环境特点,采用温度(5±1)℃的5%的MgSO4溶液模拟服役环境,对比研究了不同腐蚀龄期(0 d、60 d、90 d、210 d、270 d、360 d)试件的外观和强度变化,并基于XRD、FTIR测试分析了侵蚀产物。结果表明:随着龄期的增长,侵蚀方式由传统的钙矾石型硫酸盐侵蚀逐渐过渡到以碳硫硅酸钙为侵蚀产物的TSA岩侵蚀;石灰岩机制砂和石粉均能促使砂浆产生TSA侵蚀,且石粉的影响更加明显。

Abstract: In order to study the influence of limestone manufactured sand and limestone rock fines on the sulfate resistance of concrete under low temperature environment, the two kinds of manufactured sand mortars mixed with or without limestone rock fines, and the two kinds of natural sand mortars incorporated with or without limestone rock fines were used as the simulate objects. Combined with the characteristics of sulfate corrosion medium and low temperature environment, 5% magnesium sulfate solution at (5±1)℃ was used to simulate the service environment. The changes of appearance and strength for the mortar specimens at different corrosion ages (0 d, 60 d, 90 d, 210 d, 270 d, 360 d) were compared and studied, and the corrosion products were analyzed by X-ray diffraction (XRD) and fourier transform infrared spectroscopy (FTIR). The results show that with the increase of erosion age, the erosion mode gradually transits from traditional ettringite type sulfate attack to thaumasite sulfate attack (TSA) with thaumasite as the erosion product. Limestone manufactured sand and limestone rock fines all can promote the TSA of mortar and concrete, and the effect of limestone rock fines is more obvious. 

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(1)在低温下,4组试件的抗硫盐侵蚀性能为:NS-A>MS-A>NS-B>MS-B。
(2)浸泡在MgSO4溶液中的4组试件强度发展类似,都呈现先增长后下降趋势,90 d时强度发展到最大,90 d后,内掺石粉的天然砂和机制砂试件强度下降更为明显。
(3)NS-B、MS-A、MS-B 试件不同龄期的硫酸盐侵蚀方式为:90 d以前,侵蚀为传统的钙矾石型硫酸盐侵蚀;90~270 d,侵蚀为传统的钙矾石型硫酸盐侵蚀和以碳硫硅酸钙为侵蚀产物的TSA侵蚀共存,且钙矾石型硫酸盐侵蚀随侵蚀龄期延长逐渐向TSA侵蚀转化;270~360 d,侵蚀以TSA侵蚀为主;360 d以后,完全呈现TSA侵蚀。而NS-A试件在210 d才出现微弱的TSA侵蚀,且随龄期进一步增长TSA侵蚀产物变化不大。表明石灰岩机制砂和石粉均能促进TSA侵蚀,且石灰岩石粉的促进作用更显著。

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邓俊双,徐志华,李北星,.低温环境下石灰岩机制砂砂浆抗硫酸盐侵蚀性能研究[J].混凝土与水泥制品,2022(1):22-26.

DENG J S,XU Z H,LI B X,et al.Sulfate Resistance of Limestone Manufactured Sand Mortar in Low Temperature Environment[J].China Concrete and Cement Products,2022(1):2022(1):22-26.

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