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偏高岭土对水泥基复合材料抗氯离子侵蚀性能的影响
Effect of Metakaolin on Chloride Ion Erosion Resistance of Cement- based Composites
2023年第2期
高活性偏高岭土;固化率;氯离子迁移系数;抗氯离子渗透性;Friedel盐
Highly active metakaolin; Curing rate; Chloride migration coefficient; Chloride ion penetration resistance; Friedel’s salt
2023年第2期
10.19761/j.1000-4637.2023.02.010.05
中国博士后科学基金资助项目(2019M662917);中铁十一局集团第六工程有限公司科技计划项目(SG88-2018-444B2);广州市科技计划项目(201902010072);广东省基础与应用基础研究基金区域联合基金项目(2019A1515110836)。
王军平
中铁十一局集团第六工程有限公司,湖北 襄阳 441000

王军平

王军平.偏高岭土对水泥基复合材料抗氯离子侵蚀性能的影响[J].混凝土与水泥制品,2023(2):10-14.

WANG Jun-ping.Effect of Metakaolin on Chloride Ion Erosion Resistance of Cement-based Composites[J].China Concrete and Cement Products,2023(2):10-14.

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摘   要:研究了偏高岭土(MK)对水泥基复合材料的氯离子固化能力和抗氯离子渗透性的影响。试验结果表明:掺入MK能够提高水泥基复合材料的氯离子固化能力,改善抗氯离子渗透性;当MK掺量为15%时,水泥基复合材料的氯离子固化率和抗氯离子渗透性最佳。XRD和DTG分析表明:MK能够通过参与水泥水化反应生成无机聚合物凝胶和Friedel盐,从而提高对氯离子的固化能力;孔结构分析验证了MK的填充效应可有效降低和延缓氯离子在水泥基复合材料中的迁移,优化了孔径分布,降低了孔隙率。 Abstract: The effect of highly active metakaolin (MK) on chloride curing ability and chloride penetration resistance of cement-based composites was studied. The results show that the addition of MK can improve the chloride ion curing ability of cement-based composites, and improve the resistance to chloride ion penetration. When the content of MK is 15%, the chloride ion curing rate and chloride ion penetration resistance of cement-based composite are the best. XRD and DTG results show that MK can produce inorganic polymer gel and Friedel’s salt by participating in the cement hydration reaction, thus improving the chloride ion curing ability. The pore structure analysis verifies that the filling effect of MK can effectively reduce and delay the migration of chloride ions in the cement-based composite, optimize the pore size distribution and reduce the porosity.
英文名 : Effect of Metakaolin on Chloride Ion Erosion Resistance of Cement- based Composites
刊期 : 2023年第2期
关键词 : 高活性偏高岭土;固化率;氯离子迁移系数;抗氯离子渗透性;Friedel盐
Key words : Highly active metakaolin; Curing rate; Chloride migration coefficient; Chloride ion penetration resistance; Friedel’s salt
刊期 : 2023年第2期
DOI : 10.19761/j.1000-4637.2023.02.010.05
文章编号 :
基金项目 : 中国博士后科学基金资助项目(2019M662917);中铁十一局集团第六工程有限公司科技计划项目(SG88-2018-444B2);广州市科技计划项目(201902010072);广东省基础与应用基础研究基金区域联合基金项目(2019A1515110836)。
作者 : 王军平
单位 : 中铁十一局集团第六工程有限公司,湖北 襄阳 441000

王军平

王军平.偏高岭土对水泥基复合材料抗氯离子侵蚀性能的影响[J].混凝土与水泥制品,2023(2):10-14.

WANG Jun-ping.Effect of Metakaolin on Chloride Ion Erosion Resistance of Cement-based Composites[J].China Concrete and Cement Products,2023(2):10-14.

摘要
参数
结论
参考文献
引用本文

摘   要:研究了偏高岭土(MK)对水泥基复合材料的氯离子固化能力和抗氯离子渗透性的影响。试验结果表明:掺入MK能够提高水泥基复合材料的氯离子固化能力,改善抗氯离子渗透性;当MK掺量为15%时,水泥基复合材料的氯离子固化率和抗氯离子渗透性最佳。XRD和DTG分析表明:MK能够通过参与水泥水化反应生成无机聚合物凝胶和Friedel盐,从而提高对氯离子的固化能力;孔结构分析验证了MK的填充效应可有效降低和延缓氯离子在水泥基复合材料中的迁移,优化了孔径分布,降低了孔隙率。

Abstract: The effect of highly active metakaolin (MK) on chloride curing ability and chloride penetration resistance of cement-based composites was studied. The results show that the addition of MK can improve the chloride ion curing ability of cement-based composites, and improve the resistance to chloride ion penetration. When the content of MK is 15%, the chloride ion curing rate and chloride ion penetration resistance of cement-based composite are the best. XRD and DTG results show that MK can produce inorganic polymer gel and Friedel’s salt by participating in the cement hydration reaction, thus improving the chloride ion curing ability. The pore structure analysis verifies that the filling effect of MK can effectively reduce and delay the migration of chloride ions in the cement-based composite, optimize the pore size distribution and reduce the porosity.

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(1)掺入MK能提高水泥净浆的氯离子固化能力,降低氯离子迁移系数。当MK掺量为15%时,固化率均超过60%,氯离子迁移系数最低,抗氯离子渗透性最佳。
(2)微观分析测试表明,MK中活性SiO2能与水泥水化产生的Ca(OH)2反应生成不定型的三维凝胶,可以通过物理吸附将游离氯离子进行固化;掺入MK可以提高水泥中活性C3A的含量,C3A与水泥水化产物Ca(OH)2和氯离子结合生成Friedel盐,从而起到固化氯离子的作用;MK的填充效应可以有效降低和延缓氯离子在水泥基复合材料中的迁移,优化了孔径分布,降低了孔隙率。

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王军平.偏高岭土对水泥基复合材料抗氯离子侵蚀性能的影响[J].混凝土与水泥制品,2023(2):10-14.

WANG Jun-ping.Effect of Metakaolin on Chloride Ion Erosion Resistance of Cement-based Composites[J].China Concrete and Cement Products,2023(2):10-14.

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