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硅灰类型对碱集料反应的影响及机理分析
Effect of Silica Fume Type on Alkali-aggregate Reaction and Its Mechanism Analysis
2023年第3期
碱集料反应(AAR);碱硅酸反应(ASR);火山灰反应;ASR凝胶;膨胀;原状硅灰;增密硅灰
Alkali-aggregate reaction; Alkali-silica reaction(ASR); Pozzolanic reaction; ASR gel; Expansion; Undensified silica fume; Densified silica fume
2023年第3期
10.19761/j.1000-4637.2023.03.087.05
赵 明,汪冬冬,张悦然
中交上海港湾工程设计研究院有限公司,上海 200032

赵 明,汪冬冬,张悦然

赵明,汪冬冬,张悦然.硅灰类型对碱集料反应的影响及机理分析[J].混凝土与水泥制品,2023(3):87-91.

ZHAO M,WANG D D,ZHANG Y R.Effect of Silica Fume Type on Alkali-aggregate Reaction and Its Mechanism Analysis[J].China Concrete and Cement Products,2023(3):87-91.

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摘   要:采用快速砂浆棒法研究了原状硅灰和增密硅灰对活性骨料碱集料反应(AAR)的影响,采用岩相法分析了增密硅灰发生反应后的形貌及膨胀开裂现象。结果表明:原状硅灰可以明显地抑制活性骨料发生AAR,增密硅灰则会加剧碱硅酸反应(ASR);原状硅灰颗粒微小,在砂浆中分散均匀,主要发生火山灰反应,消耗砂浆孔溶液中的碱,降低孔溶液的pH值,且形成的低钙硅比C-S-H凝胶还能进一步捕捉体系中的碱,从而抑制发生AAR;增密硅灰中的部分颗粒难以在砂浆搅拌过程中充分破碎和分散,会与碱发生ASR而非火山灰反应,形成的ASR凝胶吸水膨胀,加剧了活性骨料的AAR和膨胀。 Abstract: The effect of undensified silica fume and densified silica fume on the alkali-aggregate reaction(AAR) of reactive aggregates was studied by using the accelerated mortar bar method. The morphology and expansion cracking of densified silica fume after reaction were analyzed by using the petrographic method. The results show that the undensified silica fume can obviously inhibit the AAR of the reactive aggregates, but the densified silica fume aggravates the alkali-silica reaction(ASR). The undensified silica fume particles are small and evenly dispersed in the mortar, mainly producing pozzolanic reaction, consuming the alkali in the mortar pore solution, reducing the pH value of the pore solution, and the formed low calcium silica ratio C-S-H gel can further capture the alkali in the system, thus inhibiting the AAR. Some particles in densified silica fume are difficult to be fully broken and dispersed during mortar mixing, and will react with alkali in ASR rather than pozzolanic reaction, and the formed ASR gel absorbs water and expands, which intensifies the AAR and the expansion of reactive aggregates.
英文名 : Effect of Silica Fume Type on Alkali-aggregate Reaction and Its Mechanism Analysis
刊期 : 2023年第3期
关键词 : 碱集料反应(AAR);碱硅酸反应(ASR);火山灰反应;ASR凝胶;膨胀;原状硅灰;增密硅灰
Key words : Alkali-aggregate reaction; Alkali-silica reaction(ASR); Pozzolanic reaction; ASR gel; Expansion; Undensified silica fume; Densified silica fume
刊期 : 2023年第3期
DOI : 10.19761/j.1000-4637.2023.03.087.05
文章编号 :
基金项目 :
作者 : 赵 明,汪冬冬,张悦然
单位 : 中交上海港湾工程设计研究院有限公司,上海 200032

赵 明,汪冬冬,张悦然

赵明,汪冬冬,张悦然.硅灰类型对碱集料反应的影响及机理分析[J].混凝土与水泥制品,2023(3):87-91.

ZHAO M,WANG D D,ZHANG Y R.Effect of Silica Fume Type on Alkali-aggregate Reaction and Its Mechanism Analysis[J].China Concrete and Cement Products,2023(3):87-91.

摘要
参数
结论
参考文献
引用本文

摘   要:采用快速砂浆棒法研究了原状硅灰和增密硅灰对活性骨料碱集料反应(AAR)的影响,采用岩相法分析了增密硅灰发生反应后的形貌及膨胀开裂现象。结果表明:原状硅灰可以明显地抑制活性骨料发生AAR,增密硅灰则会加剧碱硅酸反应(ASR);原状硅灰颗粒微小,在砂浆中分散均匀,主要发生火山灰反应,消耗砂浆孔溶液中的碱,降低孔溶液的pH值,且形成的低钙硅比C-S-H凝胶还能进一步捕捉体系中的碱,从而抑制发生AAR;增密硅灰中的部分颗粒难以在砂浆搅拌过程中充分破碎和分散,会与碱发生ASR而非火山灰反应,形成的ASR凝胶吸水膨胀,加剧了活性骨料的AAR和膨胀。

Abstract: The effect of undensified silica fume and densified silica fume on the alkali-aggregate reaction(AAR) of reactive aggregates was studied by using the accelerated mortar bar method. The morphology and expansion cracking of densified silica fume after reaction were analyzed by using the petrographic method. The results show that the undensified silica fume can obviously inhibit the AAR of the reactive aggregates, but the densified silica fume aggravates the alkali-silica reaction(ASR). The undensified silica fume particles are small and evenly dispersed in the mortar, mainly producing pozzolanic reaction, consuming the alkali in the mortar pore solution, reducing the pH value of the pore solution, and the formed low calcium silica ratio C-S-H gel can further capture the alkali in the system, thus inhibiting the AAR. Some particles in densified silica fume are difficult to be fully broken and dispersed during mortar mixing, and will react with alkali in ASR rather than pozzolanic reaction, and the formed ASR gel absorbs water and expands, which intensifies the AAR and the expansion of reactive aggregates.

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(1)原状硅灰的微粉颗粒细小,具有抑制活性骨料发生AAR膨胀的作用,且该抑制作用随着原状硅灰取代率的增加而提高,当原状硅灰取代率为10%~12%时,可以达到显著的抑制效果。
(2)原状硅灰抑制AAR的作用机理主要是火山灰反应消耗体系中的碱,降低孔溶液的pH值,且形成的低钙硅比C-S-H凝胶能进一步捕捉体系中碱,从而减少与活性骨料发生反应的碱含量,起到抑制AAR的作用。
(3)增密硅灰以球形颗粒为主,颗粒尺寸较大,部分未充分破碎和分散的增密硅灰颗粒会像活性骨料那样与碱发生ASR而非火山灰反应,形成ASR凝胶,从而加剧AAR膨胀。
(4)硅灰对AAR的影响与硅灰类型、颗粒大小及其反应类型有关,实际应用时,需选择合适的硅灰类型、颗粒尺寸、搅拌工艺,尽量保证硅灰均匀分散,正常进行火山灰反应,从而起到抑制掺活性骨料砂浆或混凝土发生AAR的作用。

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赵明,汪冬冬,张悦然.硅灰类型对碱集料反应的影响及机理分析[J].混凝土与水泥制品,2023(3):87-91.

ZHAO M,WANG D D,ZHANG Y R.Effect of Silica Fume Type on Alkali-aggregate Reaction and Its Mechanism Analysis[J].China Concrete and Cement Products,2023(3):87-91.

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