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超疏水铁尾矿石的制备及其对混凝土性能的影响
Preparation of superhydrophobic iron tailings stone and its effect on performance of concrete
2023年第8期
超疏水性;铁尾矿石;混凝土;疏水性;工作性;耐久性能
Superhydrophobicity; Iron tailings stone; Concrete; Hydrophobicity; Workability; Durability
2023年第8期
10.19761/j.1000-4637.2023.08.097.04
赵寅山1,张小兵2,*
1.山东建筑大学 土木工程学院,山东 济南 250101;2.中铁西北科学研究院有限公司, 甘肃 兰州 730000

赵寅山1,张小兵2,*

赵寅山,张小兵.超疏水铁尾矿石的制备及其对混凝土性能的影响[J].混凝土与水泥制品,2023(8):97-100.

ZHAO Y S,ZHANG X B.Preparation of superhydrophobic iron tailings stone and its effect on performance of concrete[J].China Concrete and Cement Products,2023(8):97-100.

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摘   要:采用硬脂酸和乙醇改性铁尾矿石,制备了超疏水铁尾矿石,研究了硬脂酸的掺量(2%、4%、6%、8%、10%、12%)对超疏水铁尾矿石疏水性的影响,分析了超疏水铁尾矿石的掺量(0、10%、20%、30%)对混凝土疏水性、工作性和吸水率的影响。结果表明:随着硬脂酸掺量的增加,超疏水铁尾矿石的水接触角先增大后减小,当硬脂酸掺量为8%时,超疏水铁尾矿石的水接触角为153°,达到超疏水状态;随着超疏水铁尾矿石掺量的增加,混凝土的疏水性提高,稠度增大,吸水率降低。 Abstract: Superhydrophobic iron tailings stone was prepared by modifying iron tailings powder with stearic acid and ethanol. The effects of the content of stearic acid (2%, 4%, 6%, 8%, 10%, 12%) on the hydrophobicity of superhydrophobic iron tailings stone were studied, and the influence of the content of superhydrophobic iron tailings stone (0%, 10%, 20%, 30%) on the hydrophobicity, workability, and water absorption of concrete was analyzed. The results show that with the increase of stearic acid content, the water contact angle of superhydrophobic iron tailings stone first increases and then decreases. When the stearic acid content is 8%, the water contact angle of superhydrophobic iron tailings stone is 153°, reaching a superhydrophobic state. With the increase of the content of superhydrophobic iron tailings stone, the hydrophobicity of concrete increases, the consistency increases, and the water absorption rate decreases.
英文名 : Preparation of superhydrophobic iron tailings stone and its effect on performance of concrete
刊期 : 2023年第8期
关键词 : 超疏水性;铁尾矿石;混凝土;疏水性;工作性;耐久性能
Key words : Superhydrophobicity; Iron tailings stone; Concrete; Hydrophobicity; Workability; Durability
刊期 : 2023年第8期
DOI : 10.19761/j.1000-4637.2023.08.097.04
文章编号 :
基金项目 :
作者 : 赵寅山1,张小兵2,*
单位 : 1.山东建筑大学 土木工程学院,山东 济南 250101;2.中铁西北科学研究院有限公司, 甘肃 兰州 730000

赵寅山1,张小兵2,*

赵寅山,张小兵.超疏水铁尾矿石的制备及其对混凝土性能的影响[J].混凝土与水泥制品,2023(8):97-100.

ZHAO Y S,ZHANG X B.Preparation of superhydrophobic iron tailings stone and its effect on performance of concrete[J].China Concrete and Cement Products,2023(8):97-100.

摘要
参数
结论
参考文献
引用本文

摘   要:采用硬脂酸和乙醇改性铁尾矿石,制备了超疏水铁尾矿石,研究了硬脂酸的掺量(2%、4%、6%、8%、10%、12%)对超疏水铁尾矿石疏水性的影响,分析了超疏水铁尾矿石的掺量(0、10%、20%、30%)对混凝土疏水性、工作性和吸水率的影响。结果表明:随着硬脂酸掺量的增加,超疏水铁尾矿石的水接触角先增大后减小,当硬脂酸掺量为8%时,超疏水铁尾矿石的水接触角为153°,达到超疏水状态;随着超疏水铁尾矿石掺量的增加,混凝土的疏水性提高,稠度增大,吸水率降低。

Abstract: Superhydrophobic iron tailings stone was prepared by modifying iron tailings powder with stearic acid and ethanol. The effects of the content of stearic acid (2%, 4%, 6%, 8%, 10%, 12%) on the hydrophobicity of superhydrophobic iron tailings stone were studied, and the influence of the content of superhydrophobic iron tailings stone (0%, 10%, 20%, 30%) on the hydrophobicity, workability, and water absorption of concrete was analyzed. The results show that with the increase of stearic acid content, the water contact angle of superhydrophobic iron tailings stone first increases and then decreases. When the stearic acid content is 8%, the water contact angle of superhydrophobic iron tailings stone is 153°, reaching a superhydrophobic state. With the increase of the content of superhydrophobic iron tailings stone, the hydrophobicity of concrete increases, the consistency increases, and the water absorption rate decreases.

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(1)随着硬脂酸掺量的增加,超疏水铁尾矿石的水接触角先增大后减小,最佳硬脂酸掺量为8%,此时,超疏水铁尾矿石达到了超疏水状态,水接触角为153°,而较高的水接触角有利于提高掺超疏水铁尾矿石混凝土的耐久性能。
(2)FTIR分析结果表明,硬脂酸成功接枝到了铁尾矿石上,使得铁尾矿石具备了疏水性。
(3)随着超疏水铁尾矿石掺量的增加,混凝土表面润湿性逐渐降低,即疏水性提高。其中,当超疏水铁尾矿石的掺量为30%时,混凝土的疏水性达到最大,水接触角为100°。
(4)掺入适量超疏水铁尾矿石可以提高混凝土的工作性,随着超疏水铁尾矿石掺量的增加,混凝土的稠度逐渐增大。
(5)随着超疏水铁尾矿石掺量的增加,混凝土的吸水率降低。其中,当超疏水铁尾矿石的掺量为30%时,混凝土的吸水率最低,其100 h吸水率与不掺超疏水铁尾矿石的混凝土相比降低了73.45%,这充分说明了掺入适量超疏水铁尾矿石有利于提高混凝土的耐久性能。
 

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赵寅山,张小兵.超疏水铁尾矿石的制备及其对混凝土性能的影响[J].混凝土与水泥制品,2023(8):97-100.

ZHAO Y S,ZHANG X B.Preparation of superhydrophobic iron tailings stone and its effect on performance of concrete[J].China Concrete and Cement Products,2023(8):97-100.

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