苏州混凝土水泥制品研究院有限公司

头部文案

发布时间:2020-01-06 00:00:00
全国建材科技期刊
全国中文核心期刊
中国科技论文统计源期刊
万方数据-数字化期刊群入网期刊
中国学术期刊(光盘版)全文收录期刊
华东地区优秀科技期刊
江苏省期刊方阵“双效期刊”
中国期刊网全文收录期刊
中国科技期刊数据库全文收录期刊
硫酸盐环境下水泥砂浆的腐蚀产物及孔结构研究
Research on corrosion products and pore structure of cement mortar under sulfate environment
2024年第2期
硫酸盐腐蚀;水泥砂浆;腐蚀产物;激光拉曼分析;孔结构
Sulfate corrosion; Cement mortar; Corrosion product; Laser Raman analysis; Pore structure
2024年第2期
10.19761/j.1000-4637.2024.02.028.04
湖北省自然科学基金项目(2022CFB323);襄阳市科技计划项目(2022ABH006372)。
王学兵1,郭声波1,潘志华2
1.湖北文理学院 土木工程与建筑学院,湖北 襄阳 441053;2.南京工业大学 材料科学与工程学院,江苏 南京 210009

王学兵1,郭声波1,潘志华2

王学兵,郭声波,潘志华.硫酸盐环境下水泥砂浆的腐蚀产物及孔结构研究[J].混凝土与水泥制品,2024(2):28-30,40.

WANG X B,GUO S B,PAN Z H.Research on corrosion products and pore structure of cement mortar under sulfate environment[J].China Concrete and Cement Products,2024(2):28-30,40.

浏览量:
1000
摘   要:采用激光拉曼光谱和压汞法研究了硫酸盐环境下水泥砂浆的腐蚀产物及孔结构,并引入分形维数,建立了水泥砂浆的抗折强度与平均孔径和分形维数的关系。结果表明:不同浓度的Na2SO4溶液浸泡下,砂浆表层腐蚀产物有所不同,且腐蚀产物在砂浆表层分布是不均匀的;砂浆的抗折强度与平均孔径r成反比,与分形维数d成正比,通过三种公式拟合可知,d/r2和抗折强度具有较好的相关性。 Abstract: The corrosion products and pore structure of cement mortar under sulfate corrosion were studied by using laser Raman spectroscopy and mercury intrusion method. Fractal dimension was introduced, and the relationship between the flexural strength of cement mortar and the average pore size and fractal dimension was established. The results show that the corrosion products on the surface of mortar are different when soaked in Na2SO4 solutions with different concentrations, and the distribution of corrosion products on the surface of mortar is uneven. The flexural strength of mortar is inversely proportional to the average pore size r and directly proportional to the fractal dimension d. By fitting three formulas, d/r2 and flexural strength has a good correlation.
英文名 : Research on corrosion products and pore structure of cement mortar under sulfate environment
刊期 : 2024年第2期
关键词 : 硫酸盐腐蚀;水泥砂浆;腐蚀产物;激光拉曼分析;孔结构
Key words : Sulfate corrosion; Cement mortar; Corrosion product; Laser Raman analysis; Pore structure
刊期 : 2024年第2期
DOI : 10.19761/j.1000-4637.2024.02.028.04
文章编号 :
基金项目 : 湖北省自然科学基金项目(2022CFB323);襄阳市科技计划项目(2022ABH006372)。
作者 : 王学兵1,郭声波1,潘志华2
单位 : 1.湖北文理学院 土木工程与建筑学院,湖北 襄阳 441053;2.南京工业大学 材料科学与工程学院,江苏 南京 210009

王学兵1,郭声波1,潘志华2

王学兵,郭声波,潘志华.硫酸盐环境下水泥砂浆的腐蚀产物及孔结构研究[J].混凝土与水泥制品,2024(2):28-30,40.

WANG X B,GUO S B,PAN Z H.Research on corrosion products and pore structure of cement mortar under sulfate environment[J].China Concrete and Cement Products,2024(2):28-30,40.

摘要
参数
结论
参考文献
引用本文

摘   要:采用激光拉曼光谱和压汞法研究了硫酸盐环境下水泥砂浆的腐蚀产物及孔结构,并引入分形维数,建立了水泥砂浆的抗折强度与平均孔径和分形维数的关系。结果表明:不同浓度的Na2SO4溶液浸泡下,砂浆表层腐蚀产物有所不同,且腐蚀产物在砂浆表层分布是不均匀的;砂浆的抗折强度与平均孔径r成反比,与分形维数d成正比,通过三种公式拟合可知,d/r2和抗折强度具有较好的相关性。

Abstract: The corrosion products and pore structure of cement mortar under sulfate corrosion were studied by using laser Raman spectroscopy and mercury intrusion method. Fractal dimension was introduced, and the relationship between the flexural strength of cement mortar and the average pore size and fractal dimension was established. The results show that the corrosion products on the surface of mortar are different when soaked in Na2SO4 solutions with different concentrations, and the distribution of corrosion products on the surface of mortar is uneven. The flexural strength of mortar is inversely proportional to the average pore size r and directly proportional to the fractal dimension d. By fitting three formulas, d/r2 and flexural strength has a good correlation.

扫二维码用手机看
未找到相应参数组,请于后台属性模板中添加

(1)基于激光拉曼光谱分析,不同浓度的硫酸盐对砂浆的腐蚀机理不同,当外界硫酸盐浓度较低时,腐蚀产物主要以AFt为主;当外界硫酸盐浓度较高时,腐蚀产物主要以AFt和石膏两者共存;腐蚀产物在砂浆表层分布是不均匀的。
(2)通过引入分形维数,建立了宏观力学性能和孔隙结构的联系,d/r2和抗折强度具有较好的相关性。

[1] 申爱琴.水泥与水泥混凝土[M].北京:人民交通出版社,2004.
[2] WANG X,PAN Z,SHEN X,et al.Stability and decomposition mechanism of ettringite in presence of ammonium sulfate solution[J].Construction and Building Materials,2016,124:786-793.
[3] 沈威.水泥工艺学[M].武汉:武汉理工大学出版社,1991.
[4] SCHMIDI T,LOTHENBACH B,ROMER M,et al.A thermodynamic and experimental study of the conditions of thaumasite formation[J].Cement and Concrete Research,2008,38(3):337-349.
[5] 梁咏宁,袁迎曙.硫酸钠和硫酸镁溶液中混凝土腐蚀破坏的机理[J].硅酸盐学报,2007(4):114-118.
[6] SANTHANAM M,COHEN M D,OLEK J.Sulfate attack research-whither now?[J].Cement and Concrete Research,2001,31(6):845-851.
[7] YASEEN S A,YISEEN G A,POON C S,et al.The effectuation of seawater on the microstructural features and the compressive strength of fly ash blended cement at early and later ages[J].Journal of the American Ceramic Society,2023,106:4967-4986.
[8] WANG X,GUO S,LI Y.Formation of thaumasite in ammonium salt solution based on Raman spectroscopy and thermodynamic analysis[J].Journal of Applied Spectroscopy,2022,89(4):658-664.
[9] 吴萌,张云升,刘志勇,等.水泥基材料碳硫硅钙石型硫酸盐侵蚀的研究进展[J].硅酸盐学报,2022,50(8):2270-2283.
[10] 李相国,田博,何超,等.SO42-/C3A对单矿C3S水泥浆体中碳硫硅钙石形成的影响[J].硅酸盐通报,2022,41(8):2637-2643.

[11] 段永辉,李想.掺合料对混凝土胶空比及其抗压强度的影响[J].混凝土,2020(2):82-83,88.
[12] 田梦云,张恩,曹瑞东,等.基于细观尺度的混凝土单轴力学性能仿真计算分析[J].应用力学学报,2020,37(3):975-981,1384.
[13] 陆平.水泥材料科学导论[M].上海:同济大学出版社,1991.
[14] 孙嘉卿,丛干文,刘君实,等.再生骨料生态混凝土预测模型抗压强度试验研究[J].建筑结构学报,2020,41(增刊):381-389.
[15] ZHENG G,SUN J,GUO X,et al.Research on the relationship between pore structure and the compressive strength of oil-well cement[J].Energies,2023,16(15):1-18.
[16] 于成鑫,闫浩康,王硕,等.压力成型对砂浆孔结构、强度及分形维数的影响[J].混凝土与水泥制品,2023(4):34-38.
[17] 伍怡璇,李静,黄子锐,等.丁苯橡胶泡沫混凝土的孔结构与宏观性能研究[J].混凝土与水泥制品,2023(1):66-69,73.
[18] 柯国军.土木工程材料[M].北京:北京大学出版社,2012. 
[19] 杨南如.无机非金属材料测试方法[M].武汉:武汉理工大学出版社,1993.
[20] ZHANG K,YIO M,WONG H,et al.Real-time monitoring of carbonation of hardened cement pastes using Raman microscopy[J].Journal of Microscopy,2022(2):126-133.

王学兵,郭声波,潘志华.硫酸盐环境下水泥砂浆的腐蚀产物及孔结构研究[J].混凝土与水泥制品,2024(2):28-30,40.

WANG X B,GUO S B,PAN Z H.Research on corrosion products and pore structure of cement mortar under sulfate environment[J].China Concrete and Cement Products,2024(2):28-30,40.

相关文件

暂时没有内容信息显示
请先在网站后台添加数据记录。

关注《混凝土与水泥制品》

总访问量 468,401   网站统计

官方微信公众号关闭
苏州混凝土水泥制品研究院有限公司

关于我们    |    联系我们    |    订购杂志    |    回到顶部

版权所有:中国混凝土与水泥制品网  苏ICP备10086386号   网站建设:中企动力 苏州

版权所有:中国混凝土与水泥制品网

苏ICP备10086386号

网站建设:中企动力 苏州