苏州混凝土水泥制品研究院有限公司

头部文案

发布时间:2020-01-06 00:00:00
全国建材科技期刊
全国中文核心期刊
中国科技论文统计源期刊
万方数据-数字化期刊群入网期刊
中国学术期刊(光盘版)全文收录期刊
华东地区优秀科技期刊
江苏省期刊方阵“双效期刊”
中国期刊网全文收录期刊
中国科技期刊数据库全文收录期刊
水泥基自修复微胶囊的制备及其修复效果研究
study on preparation of cement-based self-healing microcapsules and its repair effects
2024年第5期
水泥基材料;微胶囊;自修复;力学性能;养护
Cement-based material; Microcapsule; Self-repair; Mechanical property; Curing
2024年第5期
10.19761/j.1000-4637.2024.05.029.05
浙江省建设科研项目(2020K138);浙江省教育厅科研项目(Y202043252、Y201941554)。
吴承卉,李俊虎*,杨英豪,雷 航
金华职业技术学院,浙江 金华 321017

吴承卉,李俊虎*,杨英豪,雷 航

吴承卉,李俊虎,杨英豪,等.水泥基自修复微胶囊的制备及其修复效果研究[J].混凝土与水泥制品,2024(5):29-33.

WU C H,LI J H,YANG Y H,et al.Study on preparation of cement-based self-healing microcapsules and its repair effects[J].China Concrete and Cement Products,2024(5):29-33.

浏览量:
1000
摘   要:采用原位聚合法制备了以脲醛树脂为囊壁、环氧树脂GCC-135为囊芯的微胶囊,以抗压强度恢复率为指标评价了微胶囊的修复性能,研究了干燥养护、浸水养护(干养、湿养)条件下不同微胶囊掺量(水泥质量的0、1.5%、3.0%、4.5%、6.0%)对砂浆试件的修复效果。结果表明:在干养、湿养条件下,随着微胶囊掺量的增加,试件的抗折强度、抗压强度均降低;在不同微胶囊掺量下,干养试件的抗压强度恢复率为106.60%~124.29%,湿养试件的抗压强度恢复率为98.74%~110.12%,湿养条件下的修复效果明显低于干养条件;随着微胶囊掺量的增加,其修复效果先增加后略微降低,当微胶囊掺量为4.5%时,微胶囊的修复效果最佳。 Abstract: Microcapsules with urea formaldehyde resin as the wall and epoxy resin GCC-135 as the core were prepared by in-situ polymerization method. The self-healing performance of microcapsules was evaluated by using compressive strength recovery rate as an indicator. The repair effect of different microcapsule contents(0, 1.5%, 3.0%, 4.5%, 6.0% of cement mass) on mortar specimens was studied under dry curing and immersion curing (dry curing, wet curing). The results show that under dry and wet curing conditions, as the content of microcapsules increases, the flexural strength and compressive strength of the specimens decrease. Under different microcapsule contents, the compressive strength recovery rate of dry curing specimens is 106.60%~124.29%, and the compressive strength recovery rate of wet curing specimens is 98.74%~110.12%. The repair effect under wet curing conditions is significantly lower than that under dry curing. As the content of microcapsules increases, the repair effect first increases and then slightly decreases. When the content of microcapsules is 4.5%, the repair effect of microcapsules is the best.
英文名 : study on preparation of cement-based self-healing microcapsules and its repair effects
刊期 : 2024年第5期
关键词 : 水泥基材料;微胶囊;自修复;力学性能;养护
Key words : Cement-based material; Microcapsule; Self-repair; Mechanical property; Curing
刊期 : 2024年第5期
DOI : 10.19761/j.1000-4637.2024.05.029.05
文章编号 :
基金项目 : 浙江省建设科研项目(2020K138);浙江省教育厅科研项目(Y202043252、Y201941554)。
作者 : 吴承卉,李俊虎*,杨英豪,雷 航
单位 : 金华职业技术学院,浙江 金华 321017

吴承卉,李俊虎*,杨英豪,雷 航

吴承卉,李俊虎,杨英豪,等.水泥基自修复微胶囊的制备及其修复效果研究[J].混凝土与水泥制品,2024(5):29-33.

WU C H,LI J H,YANG Y H,et al.Study on preparation of cement-based self-healing microcapsules and its repair effects[J].China Concrete and Cement Products,2024(5):29-33.

摘要
参数
结论
参考文献
引用本文

摘   要:采用原位聚合法制备了以脲醛树脂为囊壁、环氧树脂GCC-135为囊芯的微胶囊,以抗压强度恢复率为指标评价了微胶囊的修复性能,研究了干燥养护、浸水养护(干养、湿养)条件下不同微胶囊掺量(水泥质量的0、1.5%、3.0%、4.5%、6.0%)对砂浆试件的修复效果。结果表明:在干养、湿养条件下,随着微胶囊掺量的增加,试件的抗折强度、抗压强度均降低;在不同微胶囊掺量下,干养试件的抗压强度恢复率为106.60%~124.29%,湿养试件的抗压强度恢复率为98.74%~110.12%,湿养条件下的修复效果明显低于干养条件;随着微胶囊掺量的增加,其修复效果先增加后略微降低,当微胶囊掺量为4.5%时,微胶囊的修复效果最佳。

Abstract: Microcapsules with urea formaldehyde resin as the wall and epoxy resin GCC-135 as the core were prepared by in-situ polymerization method. The self-healing performance of microcapsules was evaluated by using compressive strength recovery rate as an indicator. The repair effect of different microcapsule contents(0, 1.5%, 3.0%, 4.5%, 6.0% of cement mass) on mortar specimens was studied under dry curing and immersion curing (dry curing, wet curing). The results show that under dry and wet curing conditions, as the content of microcapsules increases, the flexural strength and compressive strength of the specimens decrease. Under different microcapsule contents, the compressive strength recovery rate of dry curing specimens is 106.60%~124.29%, and the compressive strength recovery rate of wet curing specimens is 98.74%~110.12%. The repair effect under wet curing conditions is significantly lower than that under dry curing. As the content of microcapsules increases, the repair effect first increases and then slightly decreases. When the content of microcapsules is 4.5%, the repair effect of microcapsules is the best.

扫二维码用手机看
未找到相应参数组,请于后台属性模板中添加

(1)以环氧树脂GCC-135为囊芯、脲醛树脂为囊壁,采用原位聚合法制备了微胶囊。微胶囊颗粒形态近似球状,平均粒径为198 μm。
(2)掺入微胶囊会对砂浆的抗折、抗压强度产生一定影响,随着微胶囊掺量的增加,抗折、抗压强度基本均呈现降低趋势。
(3)掺入微胶囊的砂浆具有较好的自修复效果,当微胶囊掺量为4.5%时,干养和湿养抗压强度恢复率均最大,此时微胶囊掺量为最佳掺量。
(4)养护条件对掺入微胶囊砂浆的自修复效果影响较大,在干养条件下,砂浆的自修复效果明显优于湿养。

[1] IDIQ A,GRAVINA R,GIUSTOZZI.Is concrete healing really efficent? A review[J].Construction and Building Materials,2019,205:257-273.
[2] 高明亮.微胶囊与微生物复合材料修复混凝土裂缝的研究[D].天津:河北工业大学,2020.
[3] JIALAN Y,CHEN P Y,CHENG F Z,et al.Preparation process of epoxy resin microcapsules for self-healing coatings[J].Progress in Organic Coatings,2019,132:440-444.
[4] GARCIA A,SCHLANGEN E,VEN M,et al.Preparation of capsules containing rejuvenators for their use in asphalt concrete[J].Journal of Hazardous Materials,2010,184(1-3):603-611.
[5] 赵晓艳,高明亮,周健,等.微胶囊复合芽孢杆菌修复水泥基材料裂缝研究[J].混凝土,2021(8):83-87.
[6] SIDIQ A,SETUNGE S,GRAVINA R J,et al.Self-repairing cement mortars with microcapsules: A microstructural evaluation approach[J].Construction and Building Materials,2015,232:117239.
[7] LI X H,LIU R T,LI S C,et al.Properties and mechanism of self-healing cement paste containing microcapsule under different curing conditions[J].Construction and Building Materials,2014,357:129410.
[8] 濮琦,邓建良,李龙梓,等.微胶囊在自修复混凝土制品中的试验研究[J].混凝土与水泥制品,2017(12):44-49.
[9] 戴民,王飏,张静娟.微胶囊自修复砂浆的试验研究[J].硅酸盐通报,2018,37(4):1282-1287.
[10] 王险峰,孙培培,邢锋,等.微胶囊自修复水泥基材料的微观结构研究[J].防灾减灾工程学报,2016,36(1):126-131.
[11] 张鸣,陈令坤,邢锋,等.UF/E微胶囊用于水泥基材料自修复的渗流结构性能研究[J].建筑材料学报,2014,17(4):706-710.
[12] 金城阳,杨杨,金海东,等.微胶囊自修复水泥基材料修复效果及机理研究[J].新型建筑材料,2019,46(11):108-111,114.
[13] 周凤梅.水泥混凝土微胶囊自修复技术研究[D].重庆:重庆交通大学,2015.
[14] 李海燕,王荣国,刘文博,等.原位聚合法制备复合材料自修复用微胶囊的研究[C]//中国力学学会.第十五届全国复合材料学术会议论文集.哈尔滨:中国力学学会,2008:263-266.
[15] BROWN E N,KESSKLERS M R,SOTTOST N T,et al.Insitu poly(urea-formaldehyde) microencapsulation of dicyclopentadiene[J].Journal of Microencapsulation,2003,20(6):719-730.
[16] 李东光.脲醛树脂胶粘剂[M].北京:化学工业出版社,2002.
[17] 鲁博,张林文,曾竟成,等.天然纤维复合材料[M].北京:化学工业出版社,2005.
[18] 孙金城.微胶囊自修复水泥基材料的性能及修复效果研究[D].杭州:浙江大学,2019.
[19] 张鸣.水泥基材料用微胶囊自修复技术与原理的研究[D].长沙:中南大学,2013.
[20] 孙培培.微胶囊自修复水泥基材料的强度与孔结构研究[D].深圳:深圳大学,2016.
[21] 王信刚,张轩哲,邹府兵,等.水泥基混杂自修复微胶囊的二次修复特性与机理[J].功能材料,2023,54(2):2001-2005.
[22] WAN P,WU S P,LIU Q T,et al.Sustained-release calcium alginate/diatomite capsules for sustainable self-healing asphalt concrete[J].Journal of Cleaner Production,2022,372:133639.
[23] 赵刹.自修复复合材料中微胶囊破裂行为研究[D].天津:天津大学,2014.

吴承卉,李俊虎,杨英豪,.水泥基自修复微胶囊的制备及其修复效果研究[J].混凝土与水泥制品,2024(5):29-33.

WU C H,LI J H,YANG Y H,et al.Study on preparation of cement-based self-healing microcapsules and its repair effects[J].China Concrete and Cement Products,2024(5):29-33.

相关文件

暂时没有内容信息显示
请先在网站后台添加数据记录。

关注《混凝土与水泥制品》

总访问量 468,401   网站统计

官方微信公众号关闭
苏州混凝土水泥制品研究院有限公司

关于我们    |    联系我们    |    订购杂志    |    回到顶部

版权所有:中国混凝土与水泥制品网  苏ICP备10086386号   网站建设:中企动力 苏州

版权所有:中国混凝土与水泥制品网

苏ICP备10086386号

网站建设:中企动力 苏州