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常温固化下偏高岭土基高韧性地聚合物复合材料的性能研究
Study on properties of metakaolin based high tenacity geopolymer composite under room temperature curing
2024年第9期
高韧性地聚合物复合材料(HTGC);偏高岭土;常温固化;力学性能;抗拉性能;抗弯性能
High tenacity geopolymer composite(HTGC); Metakaolin; Room temperature curing; Mechanical property;Tensile property; Bending property
2024年第9期
10.19761/j.1000-4637.2024.09.100.06
上海市科委科研计划项目(18DZ2282600);海口市科技计划项目(2022-036);上海建工集团股份有限公司资助项目(22YJKF-34)。
李天歌1,王圣怡1,2,*,占羿箭1,2,3
1.上海建工集团股份有限公司,上海 200080;2.上海高大结构高性能混凝土工程技术研究中心, 上海 201114;3.海南省沪建建设有限公司,海南 海口 570105

李天歌1,王圣怡1,2,*,占羿箭1,2,3

李天歌,王圣怡,占羿箭.常温固化下偏高岭土基高韧性地聚合物复合材料的性能研究[J].混凝土与水泥制品,2024(9):100-105.

LI T G,WANG S Y,ZHAN Y J.Study on properties of metakaolin based high tenacity geopolymer composite under room temperature curing[J].China Concrete and Cement Products,2024(9):100-105.

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摘   要:以偏高岭土为前驱体,在常温固化条件下制备了高韧性地聚合物复合材料(HTGC),研究了不同粒径偏高岭土的复掺比例、激发剂的浓度和模数、养护龄期对HTGC抗压、抗拉和抗弯性能的影响。结果表明:复掺适量不同粒径的偏高岭土有利于提高HTGC的抗压和抗拉性能;随着激发剂浓度从6 mol/L增至14 mol/L,试件的抗拉和抗压强度增大,拉伸和抗弯延性有所降低;随着激发剂模数从1.2增至2.0,试件抗压和抗拉强度基本有所降低;偏高岭土基HTGC具有明显的早强特性,这使其在快速建造项目中具有较大的应用潜力。 Abstract: High tenacity geopolymer composite(HTGC) were prepared by using metakaolin as a precursor under room temperature curing conditions. The effects of mixing ratios of different particle size metakaolin, concentration and modulus of activator, and curing age on the compressive, tensile, and bending properties of HTGC were studied. The results show that adding an appropriate content of metakaolin with different particle sizes is beneficial for improving the compressive and tensile properties of HTGC. As the concentration of activator increases from 6 mol/L to 14 mol/L, the tensile strength and compressive strength of the specimens increase, while the tensile ductility and bending ductility decrease. As the modulus of the activator increases from 1.2 to 2.0, the compressive strength and tensile strength of the specimens generally decrease. Metakaolin based HTGC has obvious early strength characteristics, which makes it have great potential for application in rapid construction projects.
英文名 : Study on properties of metakaolin based high tenacity geopolymer composite under room temperature curing
刊期 : 2024年第9期
关键词 : 高韧性地聚合物复合材料(HTGC);偏高岭土;常温固化;力学性能;抗拉性能;抗弯性能
Key words : High tenacity geopolymer composite(HTGC); Metakaolin; Room temperature curing; Mechanical property;Tensile property; Bending property
刊期 : 2024年第9期
DOI : 10.19761/j.1000-4637.2024.09.100.06
文章编号 :
基金项目 : 上海市科委科研计划项目(18DZ2282600);海口市科技计划项目(2022-036);上海建工集团股份有限公司资助项目(22YJKF-34)。
作者 : 李天歌1,王圣怡1,2,*,占羿箭1,2,3
单位 : 1.上海建工集团股份有限公司,上海 200080;2.上海高大结构高性能混凝土工程技术研究中心, 上海 201114;3.海南省沪建建设有限公司,海南 海口 570105

李天歌1,王圣怡1,2,*,占羿箭1,2,3

李天歌,王圣怡,占羿箭.常温固化下偏高岭土基高韧性地聚合物复合材料的性能研究[J].混凝土与水泥制品,2024(9):100-105.

LI T G,WANG S Y,ZHAN Y J.Study on properties of metakaolin based high tenacity geopolymer composite under room temperature curing[J].China Concrete and Cement Products,2024(9):100-105.

摘要
参数
结论
参考文献
引用本文

摘   要:以偏高岭土为前驱体,在常温固化条件下制备了高韧性地聚合物复合材料(HTGC),研究了不同粒径偏高岭土的复掺比例、激发剂的浓度和模数、养护龄期对HTGC抗压、抗拉和抗弯性能的影响。结果表明:复掺适量不同粒径的偏高岭土有利于提高HTGC的抗压和抗拉性能;随着激发剂浓度从6 mol/L增至14 mol/L,试件的抗拉和抗压强度增大,拉伸和抗弯延性有所降低;随着激发剂模数从1.2增至2.0,试件抗压和抗拉强度基本有所降低;偏高岭土基HTGC具有明显的早强特性,这使其在快速建造项目中具有较大的应用潜力。

Abstract: High tenacity geopolymer composite(HTGC) were prepared by using metakaolin as a precursor under room temperature curing conditions. The effects of mixing ratios of different particle size metakaolin, concentration and modulus of activator, and curing age on the compressive, tensile, and bending properties of HTGC were studied. The results show that adding an appropriate content of metakaolin with different particle sizes is beneficial for improving the compressive and tensile properties of HTGC. As the concentration of activator increases from 6 mol/L to 14 mol/L, the tensile strength and compressive strength of the specimens increase, while the tensile ductility and bending ductility decrease. As the modulus of the activator increases from 1.2 to 2.0, the compressive strength and tensile strength of the specimens generally decrease. Metakaolin based HTGC has obvious early strength characteristics, which makes it have great potential for application in rapid construction projects.

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(1)与单掺CP或XP相比,复掺适量CP和XP有助于提升HTGC的抗压性能;随着激发剂浓度的增加,试件的3 d抗压强度逐渐增大;随着激发剂模数的增加,试件的3 d抗压强度逐渐降低。随着养护龄期的增加,试件的抗压强度增大,且增幅呈先大后小的趋势,说明HTGC具有显著的早强、快硬特性,且激发剂的浓度越大,HTGC的早强、快硬特性越显著,这使得偏高岭土基HTGC适用于有快速施工需求的项目,如道路桥梁快速修补、预制结构快速拼装等。
(2)以偏高岭土为前驱体,掺入适量国产PVA纤维,可制备出常温固化HTGC,其表现出了明显的多缝开裂和应变硬化特征,极限拉伸应变最高可达7.99%。另外,随着激发剂浓度的增加,试件的初裂强度和极限抗拉强度基本呈增大趋势,极限拉伸应变总体上呈显著下降趋势;随着激发剂模数的增加,各组试件的极限拉伸应变均大于2.00%,但极限抗拉强度呈下降趋势。
(3)随着激发剂浓度的增加,试件的极限抗弯承载力先增大后减小,抗弯延性有所降低。

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李天歌,王圣怡,占羿箭.常温固化下偏高岭土基高韧性地聚合物复合材料的性能研究[J].混凝土与水泥制品,2024(9):100-105.

LI T G,WANG S Y,ZHAN Y J.Study on properties of metakaolin based high tenacity geopolymer composite under room temperature curing[J].China Concrete and Cement Products,2024(9):100-105.

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