纳米碳化硅改性水玻璃对再生骨料的强化作用机制研究

Research on Reinforcement Mechanism of Sodium Silicate Modified by Nano-SiC on Recycled Aggregate

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关键词:

纳米碳化硅;水玻璃;再生骨料;再生混凝土;性能;强化机制

Key words:

Nano-SiC; Sodium silicate; Recycled aggregate; Recycled concrete; Property; Strengthening mechanism

刊期:

DOI:

10.19761/j.1000-4637.2019.07.091.05

文章编号:

基金项目:

国家自然科学基金资助项目(U1504508);河南省教育厅高等学校重点科研项目(15A430015);河南省省级新型墙体材料专项基金项目(20160304)。

作者:

徐开东,王继娜,李志新,马先伟,牛季收,杨 欢,金 彪

单位:

河南城建学院材料与化工学院,平顶山 467036

摘要

摘   要:为了进一步强化再生骨料、改善再生骨料混凝土的性能,研究了纳米碳化硅改性水玻璃对再生骨料的强化效果,并分析了作用机制。结果表明,纳米碳化硅改性水玻璃对再生骨料的强化作用明显,但会受水玻璃浓度和纳米碳化硅掺量的影响。水玻璃浓度增大,经水玻璃强化处理的再生骨料表观密度和堆积密度先增大后减小,吸水率逐渐降低,含水率逐渐增加,压碎指标先减小后增大;经水玻璃溶液+纳米碳化硅复合强化的再生骨料随着纳米碳化硅加入量的增加,表观密度和堆积密度先增大后减小,吸水率和含水率均先降低后增大,压碎指标先减小后增大。经浓度为30%的水玻璃溶液+0.75%纳米碳化硅浸泡强化的再生骨料,孔隙和裂缝被改性水玻璃填充,再生骨料表面均匀,综合性能较好,拌制的再生混凝土28 d抗压强度较未处理的再生骨料拌制的混凝土提高约45%,较天然骨料拌制的混凝土低约10%。
Abstract: In order to intensify the recycled aggregate and improve the properties of recycled concrete further, the strengthening effect and mechanism of sodium silicate modified by nano-SiC on the recycled aggregate concrete were studied. The results show that the strengthening effect is obvious ,but it is influenced by concentration of sodium silicate and addition of nano-SiC. As the concentration of water glass is increased, the apparent density and bulk density of the recycled aggregate treated with water glass are firstly increased, the water absorption is gradually reduced, the water content is gradually increased, and the crushing index is increased firstly. With the increase of nano-SiC content, the apparent density and bulk density of recycled aggregate reinforced by nano-SiC solution increased firstly and then decreased, the water absorption and water content decreased first and then increased, and the crushing index decreased first and then increased. The properties of the recycled aggregate which intensified by modified sodium silicate solution with a concentration of 30% and addition of 0.75% nano-SiC are relatively good. The surface of recycled aggregate is even. Pores and cracks are filled with modified sodium silicate. The 28 d compressive strength of corresponding recycled concrete is about 45% higher than the recycled concrete when the recycled aggregate without any treatment, but it is about 10% lower than that of natural aggregate. 

结论

(1)采用纳米碳化硅改性水玻璃强化处理再生骨料的过程中,水玻璃的浓度和纳米碳化硅的掺量均对强化效果影响较大。随着水玻璃浓度的增大,经水玻璃强化处理的再生骨料表观密度和堆积密度先增大后减小,吸水率逐渐降低,含水率逐渐增加,压碎指标先减小后增大;经水玻璃溶液+纳米碳化硅复合强化的再生骨料,随着纳米碳化硅加入量的增加,表观密度和堆积密度先增大后减小,吸水率和含水率均先降低后增大,压碎指标则先减小后增大。
(2)未经处理的再生骨料表面存在较多的裂缝和孔洞;水玻璃浓度较小时,强化处理后的再生骨料表面较均匀,裂缝和孔洞不明显;随着水玻璃浓度的增加,强化处理后的再生骨料表面附着了一层水玻璃硬化膜,但内部的孔洞和裂缝依然可以看到;水玻璃掺入纳米碳化硅之后,可以改善强化处理之后再生骨料的微观结构,但纳米碳化硅掺量过多时,会影响改性水玻璃的均匀性,从而影响强化效果。
(3)纳米碳化硅可以细化水玻璃胶粒,改善水玻璃对再生骨料的强化效果。经浓度为30%的水玻璃溶液+0.75%纳米碳化硅浸泡强化的再生骨料,孔隙和裂缝被改性水玻璃填充,再生骨料表面均匀,综合性能较好,拌制的再生混凝土28 d抗压强度较未处理的再生骨料拌制的混凝土提高约45%,较天然骨料拌制的混凝土降低约10%。

参考文献

[1] M. Chakradhara Rao. Properties of recycled aggregate and recycled aggregate concrete: effect of parent concrete [J]. Asian Journal of Civil Engineering,2018(19):103-110.
[2] 丁小雅,张鹏,刘庆.水分与氯离子在再生混凝土中的迁移规律[J].混凝土与水泥制品,2018(9):32-35.
[3] B.González-Fonteboa,S.Seara-Paz,J.de Brito,et al.Recycled concrete with coarse recycled aggregate: An overview and analysis [J].Materials De Construccion,2018,68:1-29.
[4] 史才军,曹芷杰,谢昭彬.再生混凝土力学性能的研究进展[J].材料导报,2016,30(12):96-103,126.
[5] GUO H,SHI C J,GUAN X M, et al. Durability of recycled aggregate concrete-A review [J].Cement & Concrete Composites, 2018,89:251-259.
[6] 应敬伟,蒙秋江,肖建庄.再生骨料CO2强化及其对混凝土抗压强度的影响[J].建筑材料学报,2017,20(2):277-282.
[7] YANG L X, QIAN Y L, FANG Q Q, et al. Effects of Recycled Coarse Aggregate Reinforcing Treated by Water-Glass on the Performance of Recycled Concrete [J]. Proceedings of the 3RD International Conference on Material Engineering and Application (ICMEA 2016),2016,103:181-186.
[8] 程海丽,张迪.水玻璃强化再生骨料混凝土的抗冻性和抗侵蚀性探析[J].新型建筑材料,2008(8):5-7.
[9] 张津践.再生混凝土纳米强化技术及微观结构分析[D].杭州:浙江大学,2012.
[10] 闫洪生.纳米SiO2强化再生粗骨料混凝土力学性能的试验研究[D].青岛:青岛理工大学,2017.
[11] SINGH L P, BISHT V, ASWATHY M S, et al. Studies on performance enhancement of recycled aggregate by incorpo rating bio and nano materials [J]. Construction and Building Materials,2018,181:217-226.

引用本文

徐开东,王继娜,李志新,等.纳米碳化硅改性水玻璃对再生骨料的强化作用机制研究[J].混凝土与水泥制品,2019(7):91-95.

XU K D,WANG J N,LI Z X,et al.Research on Reinforcement Mechanism of Sodium Silicate Modified by Nano-SiC on Recycled Aggregate[J].China Concrete and Cement Products,2019(7):91-95.


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