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干湿循环作用下再生混凝土中硫酸盐传输性能研究
Research on Transmission Properties of Sulfate in Recycled Aggregate Concrete under Wetting-drying Cycles
2017年第7期
再生混凝土;硫酸盐;干湿循环;硫酸根离子含量
Recycled aggregate concrete; Sulfate; Wetting-drying cycles; Sulfate ion content
2017年第7期
1000-4637(2017)07-06-05
国家自然科学基金项目(51578141);国家“973”计划项目(2015CB655102)
祁 兵1,2 ,高建明1,2 ,沈达满1,2
东南大学材料科学与工程学院,南京 211189;2.东南大学江苏省土木工程材料 重点实验室,南京 211189)

祁 兵1,2 ,高建明1,2 ,沈达满1,2

祁兵,高建明,沈达满.干湿循环作用下再生混凝土中硫酸盐传输性能研究[J].混凝土与水泥制品,2017(7):6-10.

QI B, GAO J M, SHEN D M.Research on Transmission Properties of Sulfate in Recycled Aggregate Concrete Under Wetting-drying Cycles[J].China Concrete and Cement Products,2017(7):6-10.

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摘  要:研究了在干湿循环作用下,硫酸根离子在再生混凝土中的传输规律。采用分光光度计法定量表征不同深度处的水溶硫酸根离子浓度,研究再生粗骨料取代率(0,30%,50%,70%,100%)、矿物掺合料、水胶比、腐蚀龄期及干湿循环制度对其传输规律的影响。结果表明,再生粗骨料的掺入对硫酸盐传输有较为明显的影响。试验还表明,硫酸盐-干湿循环耦合作用下,粉煤灰和矿粉等矿物掺合料可阻碍硫酸根离子在再生混凝土中的传输,再生混凝土水胶比越小其水溶硫酸根离子浓度越小。随着腐蚀龄期增长,再生混凝土水溶硫酸根离子浓度大幅增加。与单一盐溶液侵蚀相比,干湿循环加剧了硫酸根离子在再生混凝土中的传输,其水溶硫酸根离子浓度随着循环次数的增加而增大。Abstract:Thetransmissionmechanismofsulfateioninrecycledaggregateconcretemadewithdifferentrecycledcoarseaggregate(RCA)undersulfateattackandwetting-dryingcyclesisinvestigatedinthispaper.Thewater-solublesulfateioncontentsaremeasuredbymeansofultra-violetandvisiblespectrophotometer.TheinfluencesofRCAreplacement,mineraladditions,w/bratio,erosiontimeandwetting-dryingregimeonthetransmissionmechanismofsulfateioninrecycledaggregateconcretearestudied.TheresultsindicatethattheincorporationofRCAshowsanobviousimpactontheresistanceofconcreteagainstsulfateattackunderwetting-dryingcycles.Additional,themineraladditionsmodifiedrecycledaggregateconcretehinderthetransmissionofsulfateionthanplainrecycledaggregateconcrete.Thewater-solublesulfateioncontentsdecreasewiththedecreaseofW/Bratio.Moreover,thewater-solublesulfateioncontentsincreasewiththetimeoferosionunderwetting-dryingcycles.Thewetting-dryingcycleshaveamajorimpactonthetransmissionmechanismofsulfateioninrecycledaggregateconcrete.Thewater-solublesulfateioncontentsincreasewiththenumberofwetting-dryingcycle.
英文名 : Research on Transmission Properties of Sulfate in Recycled Aggregate Concrete under Wetting-drying Cycles
刊期 : 2017年第7期
关键词 : 再生混凝土;硫酸盐;干湿循环;硫酸根离子含量
Key words : Recycled aggregate concrete; Sulfate; Wetting-drying cycles; Sulfate ion content
刊期 : 2017年第7期
DOI :
文章编号 : 1000-4637(2017)07-06-05
基金项目 : 国家自然科学基金项目(51578141);国家“973”计划项目(2015CB655102)
作者 : 祁 兵1,2 ,高建明1,2 ,沈达满1,2
单位 : 东南大学材料科学与工程学院,南京 211189;2.东南大学江苏省土木工程材料 重点实验室,南京 211189)

祁 兵1,2 ,高建明1,2 ,沈达满1,2

祁兵,高建明,沈达满.干湿循环作用下再生混凝土中硫酸盐传输性能研究[J].混凝土与水泥制品,2017(7):6-10.

QI B, GAO J M, SHEN D M.Research on Transmission Properties of Sulfate in Recycled Aggregate Concrete Under Wetting-drying Cycles[J].China Concrete and Cement Products,2017(7):6-10.

摘要
参数
结论
参考文献
引用本文

摘   要:研究了在干湿循环作用下,硫酸根离子在再生混凝土中的传输规律。采用分光光度计法定量表征不同深度处的水溶硫酸根离子浓度,研究再生粗骨料取代率(0,30%,50%,70%,100%)、矿物掺合料、水胶比、腐蚀龄期及干湿循环制度对其传输规律的影响。结果表明,再生粗骨料的掺入对硫酸盐传输有较为明显的影响。试验还表明,硫酸盐-干湿循环耦合作用下,粉煤灰和矿粉等矿物掺合料可阻碍硫酸根离子在再生混凝土中的传输,再生混凝土水胶比越小其水溶硫酸根离子浓度越小。随着腐蚀龄期增长,再生混凝土水溶硫酸根离子浓度大幅增加。与单一盐溶液侵蚀相比,干湿循环加剧了硫酸根离子在再生混凝土中的传输,其水溶硫酸根离子浓度随着循环次数的增加而增大。

Abstract: The transmission mechanism of sulfate ion in recycled aggregate concrete made with different recycled coarse aggregate (RCA) under sulfate attack and wetting-drying cycles is investigated in this paper. The water-soluble sulfate ion contents are measured by means of ultra-violet and visible spectrophotometer. The influences of RCA replacement, mineral additions, w/b ratio, erosion time and wetting-drying regime on the transmission mechanism of sulfate ion in recycled aggregate concrete are studied. The results indicate that the incorporation of RCA shows an obvious impact on the resistance of concrete against sulfate attack under wetting-drying cycles. Additional, the mineral additions modified recycled aggregate concrete hinder the transmission of sulfate ion than plain recycled aggregate concrete. The water-soluble sulfate ion contents decrease with the decrease of W/B ratio. Moreover, the water-soluble sulfate ion contents increase with the time of erosion under wetting-drying cycles. The wetting-drying cycles have a major impact on the transmission mechanism of sulfate ion in recycled aggregate concrete. The water-soluble sulfate ion contents increase with the number of wetting-drying cycle.


关键词:
再生混凝土;硫酸盐;干湿循环;硫酸根离子含量
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(1)再生粗骨料的掺入对硫酸盐传输有较为明显的影响。当再生粗骨料取代率较小时,再生粗骨料高吸水性使混凝土内部结构更为密实,其增强作用大于再生粗骨料自身缺陷所引起的削弱作用,导致在干湿循环作用下再生混凝土中水溶硫酸根离子浓度减小。当再生粗骨料取代率较大时,其削弱作用大于其增强作用,水溶硫酸根离子浓度增大。
(2)粉煤灰及矿粉掺入可以阻碍在干湿循环作用下硫酸盐在再生混凝土中的传输。粉煤灰及矿粉的掺入使再生混凝土内部结构更为密实,阻碍硫酸根离子传输。同时,火山灰反应会消耗一定量氢氧化钙,减少腐蚀产物生成量。
(3)干湿循环加快硫酸根离子向再生混凝土内部传输的速度,随着干湿循环次数的增加,加速作用会更为明显。
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[8] 安新正,易成,赵长彪,等.硫酸盐环境下再生混凝土的损伤演化研究[J].河北工程大学学报:自然科学版,2012(2):1-6.
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[11] 聂宇,杜文汉,王孟,等.不同掺量粉煤灰及再生粗骨料混凝土在硫酸盐侵蚀下的抗压强度研究[J].江西建材,2014,20:4-5.
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祁兵,高建明,沈达满.干湿循环作用下再生混凝土中硫酸盐传输性能研究[J].混凝土与水泥制品,2017(7):6-10.

QI B, GAO J M, SHEN D M.Research on Transmission Properties of Sulfate in Recycled Aggregate Concrete Under Wetting-drying Cycles[J].China Concrete and Cement Products,2017(7):6-10.

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