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毛细作用下硫酸盐溶液在水泥基材料中的传输研究
Transmission Study on Sulfate Solution in Cement-based Materials under Capillary Roles
2017年第7期
水泥砂浆;传输;毛细吸收;水灰比;硫酸盐
Cement mortar; Transport; Capillary absorption; Water cement ratio; Sulfate
2017年第7期
1000-4637(2017)07-11-06
国家973项目资助(2011CB013800)
李洪马,潘志华,姜海东,王 毅
江苏中铁奥莱特新材料股份有限公司,南京 211500

李洪马,潘志华,姜海东,王 毅

李洪马,潘志华,姜海东,等.毛细作用下硫酸盐溶液在水泥基材料中的传输研究[J].混凝土与水泥制品,2017(7):11-16.

LI H M, PAN Z H, JIANG H D,et al.Transmission Study on Sulfate Solution in Cement-based Materials Under Capillary Roles[J].China Concrete and Cement Products,2017(7):11-16.

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摘 要:硫酸盐溶液在混凝土中的传输速率是造成硫酸盐对混凝土侵蚀破坏的主要控制因素,硫酸盐溶液在混凝土中传输速率越大,单位时间内进入混凝土中的硫酸盐溶液越多,溶液中水分蒸发速率越快,则对混凝土造成的侵蚀就越显著。通过试验研究了毛细作用下硫酸盐溶液在水泥基材料中传输的影响因素。试验结果表明,低水灰比条件下水泥砂浆的硫酸盐溶液的传输能力显著降低;掺入适量的超细矿渣粉和粉煤灰可以改善水泥砂浆的抗渗性能;在相同浓度下,水泥基材料对硫酸钠的吸附能力最强,硫酸铵次之,硫酸镁最弱。 Abstract: The transfer rate of sulfate solution in concrete is the main controlling factor of sulfate damage to concrete, when the transfer rate of sulfate solution in concrete is larger, sulfate solution entering concrete in unit time, water evaporation rate in solution, the erosion of concrete is more significant. The influence factors of sulfate solution on cement-based materials were studied by capillary experiments. Test results show that the transfer capacity of sulfate solution of cement mortar under low water cement ratio was significantly lower, adding appropriate amount of superfine slag powder and fly ash can improve the impermeability of cement mortar, at the same concentration, the adsorption ability of cement-based materials to sodium sulfate is the strongest, ammonium sulfate is the second, and magnesium sulfate is the weakest.
英文名 : Transmission Study on Sulfate Solution in Cement-based Materials under Capillary Roles
刊期 : 2017年第7期
关键词 : 水泥砂浆;传输;毛细吸收;水灰比;硫酸盐
Key words : Cement mortar; Transport; Capillary absorption; Water cement ratio; Sulfate
刊期 : 2017年第7期
DOI :
文章编号 : 1000-4637(2017)07-11-06
基金项目 : 国家973项目资助(2011CB013800)
作者 : 李洪马,潘志华,姜海东,王 毅
单位 : 江苏中铁奥莱特新材料股份有限公司,南京 211500

李洪马,潘志华,姜海东,王 毅

李洪马,潘志华,姜海东,等.毛细作用下硫酸盐溶液在水泥基材料中的传输研究[J].混凝土与水泥制品,2017(7):11-16.

LI H M, PAN Z H, JIANG H D,et al.Transmission Study on Sulfate Solution in Cement-based Materials Under Capillary Roles[J].China Concrete and Cement Products,2017(7):11-16.

摘要
参数
结论
参考文献
引用本文

摘   要:硫酸盐溶液在混凝土中的传输速率是造成硫酸盐对混凝土侵蚀破坏的主要控制因素,硫酸盐溶液在混凝土中传输速率越大,单位时间内进入混凝土中的硫酸盐溶液越多,溶液中水分蒸发速率越快,则对混凝土造成的侵蚀就越显著。通过试验研究了毛细作用下硫酸盐溶液在水泥基材料中传输的影响因素。试验结果表明,低水灰比条件下水泥砂浆的硫酸盐溶液的传输能力显著降低;掺入适量的超细矿渣粉和粉煤灰可以改善水泥砂浆的抗渗性能;在相同浓度下,水泥基材料对硫酸钠的吸附能力最强,硫酸铵次之,硫酸镁最弱。

Abstract: The transfer rate of sulfate solution in concrete is the main controlling factor of sulfate damage to concrete, when the transfer rate of sulfate solution in concrete is larger, sulfate solution entering concrete in unit time, water evaporation rate in solution, the erosion of concrete is more significant. The influence factors of sulfate solution on cement-based materials were studied by capillary experiments. Test results show that the transfer capacity of sulfate solution of cement mortar under low water cement ratio was significantly lower, adding appropriate amount of superfine slag powder and fly ash can improve the impermeability of cement mortar, at the same concentration, the adsorption ability of cement-based materials to sodium sulfate is the strongest, ammonium sulfate is the second, and magnesium sulfate is the weakest.

关键词:
水泥砂浆;传输;毛细吸收;水灰比;硫酸盐
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(1)硫酸钠在水泥基材料中的吸附规律基本上与水泥基材料毛细吸水规律相似,也满足“时间平方根”规律。
(2)水灰比和矿物掺合料对硫酸钠溶液的吸收性能影响显著,低水灰比以及矿物掺合料的掺入,都会使硫酸钠吸附变慢,吸收量也变小,从而有效抵制硫酸钠的侵入。
(3)不同硫酸盐种类下,水泥基材料的吸收曲线呈现不同的规律。在相同浓度下,水泥基材料对硫酸钠的吸附能力最强,硫酸铵次之,硫酸镁最弱。因此,在实际工程中,应当着重考虑硫酸钠对水泥基材料的影响。
(4)硫酸钠溶液作为传输介质的混凝土毛细吸收量和毛细吸收系数都比在纯水中的小,但是氯化钠溶液的毛细吸收量和毛细吸收系数比纯水的大。而在水泥砂浆试样中,纯水的毛细传输速率最大,硫酸钠溶液的传输速率次之,氯化钠溶液的传输速率最小。单位面积液相的吸收量也是:纯水>5%硫酸钠>5%氯化钠。
[1] M.L. Nehdi, A.R. Suleiman, A.M. Soliman. Investigation of concrete exposed to dual sulfate attack[J]. Cement and Concrete Research, 2014(64): 42-53.
[2] Wei-yi Ouyang, Jian-kang Chen, Min-qiang Jiang. Cement paste content and water absorption of recycled concrete coarse aggregates[J]. Construction and Building Materials, 2014 (53):419-424.
[3] Caijun Shi, Dehui Wang, Alibehnood. Review of Thaumasite sulfate attack on cement mortar and concrete[J]. Journal of materials in civil engineering, 2012(24):1450-1460.
[4] Santhanam M, Cohen M D,Olek J. Sulfate attack research- whither now[J]. Cement and concrete research, 2001,31(6): 845-851.
[5] A.R. Suleiman, A.M. Soliman, M.L. Nehdi. Effect of surface treatment on durability of concrete exposed to physicalsulfate attack[J]. Construction and Building Materials, 2014 (73): 674-681.
[6] M.L. Nehdi, A.R. Suleiman, A.M. Soliman. Investigation of concrete exposed to dual sulfate attack[J]. Cement and Concrete Research, 2014(64): 42-53.
[7] Florian Mittermayr, Moien Rezvani, Andre Baldermann, et al. Sulfate resistance of cement-reduced eco-friendly concretes[J]. Cement and Composites, 2015(55):364-373.
[8] M.M. Rahman, M.T. Bassuoni. Thaumasite sulfate attack on concrete: Mechanisms, influential factors and mitigation[J]. Construction and Building Materials, 2014 (73):652-662.
[9] Hall C. Watersorptivity of motar and concrete[J]. Magazine of Concrete Research,1989(41):51-61.
 

李洪马,潘志华,姜海东,.毛细作用下硫酸盐溶液在水泥基材料中的传输研究[J].混凝土与水泥制品,2017(7):11-16.

LI H M, PAN Z H, JIANG H D,et al.Transmission Study on Sulfate Solution in Cement-based Materials Under Capillary Roles[J].China Concrete and Cement Products,2017(7):11-16.

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