镍渣和超细硅灰对硅酸盐水泥水化性能的影响

Effects of Nickel Slag and Super Silica Fume on Hydration Performance of Portland Cement

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关键词:

镍渣;超细硅灰;机械活化;水化产物

Key words:

Nickel slag; Super silica fume; Mechanical activation; Hydration products

刊期:

2017年第7期

DOI:

文章编号:

1000-4637(2017)07-81-05

基金项目:

国家自然科学基金项目(51572234和51502259);住房城乡建设部资助项目(2015-K4-007)

作者:

王顺祥1,2,吴其胜1,诸华军1,闵治安3,顾红霞2,吴 阳2

单位:

盐城工学院材料工程学院,224051;2. 江苏大学材料科学与工程学院,镇江 212013; 3. 北京化工大学材料科学与工程学院,100029

摘要

摘   要:富硅镁冶金镍渣是一种具有潜在火山灰活性的固体废弃物,可通过超细硅灰改性激发潜在活性,使其在硅酸盐水泥中火山灰反应充分,形成致密的网络状C-S-H凝胶,针刺状AFt等水化产物。抗压强度、粒度分布、比表面积、水化热、孔径分布、TG-DSC、SEM等宏观及微观测试表明,熟料∶镍渣∶硅灰∶石膏=85%∶5%∶5%∶5%体系的28d抗压强度可达67.1MPa,较空白样高近7MPa;水化诱导前期放热量峰值为0.19379J/g,水化加速期放热量峰值为0.25262J/g;体系1的28d水化试样粉末2~50nm细孔所占比例为51%,可明显观察到C-S-H凝胶,AFt等水化产物。

Abstract: As the solid waste, the nickel slag metallurgically with silicon and magnesium elements(briefly called “nickel slag”) has the potential pozzolanic activity. In order to get pozzolanic activity in the portland cement, the potential activity of slag is stimulated by superfine silica fume. As a result, many hydration Products, such as compact net structure of C-S-H gel and needlelike AFt has formed. Macro and micro testing have been carried out, such as compressive strength test, particle size distribution, special surface area, heat of hydration, pore size distribution, TG-DSC and SEM tests. The results show that the best formula of raw materials is clinker: nickel slag: silica fume: gypsum=85%:5%:5%:5%. Its 28d compressive strength is 67.1MPa and 7MPa larger than the blank sample’s. When it carries on hydration reaction, the peak of induction period hydration heat is 0.19379J/g and the acceleration period is 0.25262J/g. The system No.1 28d sample powder’s 2~50nm micropore proportion is 51%. In all hydrated samples, the different hydration products, such as C-S-H gel and AFt can be dariausly foumd.   

结论

(1)在本试验的5%镍渣-5%硅灰体系中,3d抗压强度为36.37MPa,较未掺镍渣空白组的39MPa降低了6.7%;7d抗压强度为43.5MPa,较未掺镍渣空白组的50.51MPa降低了13.9%,考虑其15%的内掺比例,强度实际提高了1.1%;28d抗压强度达到67.1MPa,较空白样的60.5MPa提高了11.9%,考虑其30%的内掺比例,强度实际增加41.9%。最大水化诱导前期、加速期放热量分别为0.19379J/g和0.25262J/g;28d水化试样粉末的中孔含量达68.41%,微孔含量达26.47%。
(2)将活性混合材超细硅灰和具有潜在火山灰活性的镍渣混合掺入到硅酸盐水泥中,可使体系的水化产物数量增多,水化程度提高,C-S-H凝胶交织成致密的网状结构,AFt发展成体积较大的针状结构,使得各体系的结构缺陷显著降低,显微结构致密。
(3)将低活性镍渣掺入到硅酸盐水泥材料中,并通过物理法激发镍渣潜在的活性,在较好保持水泥基材料物理化学性能前提下,用镍渣代替粉煤灰、火山灰和高炉矿渣等活性混合材,对于富硅镁冶金镍渣等工业废渣在水泥行业中应用具有重要意义。

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引用本文

王顺祥,吴其胜,诸华军,等.镍渣和超细硅灰对硅酸盐水泥水化性能的影响[J].混凝土与水泥制品,2017(7):81-85.

WANG S X, WU Q S, ZHU Hua-jun,et al.Effects of Nickel Slag and Super Silica Fume on Hydration Performance of Portland Cement[J].China Concrete and Cement Products,2017(7):81-85.


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