苏州混凝土水泥制品研究院有限公司

头部文案

发布时间:2020-01-06 00:00:00
全国建材科技期刊
全国中文核心期刊
中国科技论文统计源期刊
万方数据-数字化期刊群入网期刊
中国学术期刊(光盘版)全文收录期刊
华东地区优秀科技期刊
江苏省期刊方阵“双效期刊”
中国期刊网全文收录期刊
中国科技期刊数据库全文收录期刊
废弃线路板非金属残渣作填充料对镁质胶凝材料性能的影响
Influence of Non-metallic Residues of Waste Printed Circuit Board as Filling Material on Performance of Magnesium Oxychloride Ce
2017年第8期
废弃线路板;非金属残渣;镁质胶凝材料;水化过程;晶体形貌
Waste printed circuit boards; Non-metallic residues; Magnesium oxychloride cement; Hydration process; Crystal morphology
2017年第8期
1000-4637(2017)08-87-04
王祖润,杜 中,张永贵,余学飞
中国建材检验认证集团安徽有限公司,合肥市环境监测站,230051)

王祖润,杜 中,张永贵,余学飞

王祖润,杜中,张永贵,等.废弃线路板非金属残渣作填充料对镁质胶凝材料性能的影响[J].混凝土与水泥制品,2017(8):87-90.

WANG Z R, DU Z, ZHANG Y G,et al.Influence of Non-metallic Residues of Waste Printed Circuit Board as Filling Material on Performance of Magnesium Oxychloride Cement[J].China Concrete and Cement Products,2017(8):87-90.

浏览量:
1000
摘 要:研究了废弃线路板非金属残渣对镁质胶凝材料的水化过程、抗压强度、镁质胶凝材料晶体形貌的影响,结合扫描电镜对其反应机理进行了分析。结果表明,非金属残渣能抑制镁质胶凝材料的早期水化,使水化放热减缓,早期水化率降低,凝结时间延长;非金属残渣对镁质胶凝材料晶体形貌影响较大,使镁质胶凝材料晶体尺寸明显增大;非金属残渣通过多种途径的作用对镁质胶凝材料产生了缓凝作用。当非金属残渣掺量超过15%时,抗压强度下降较大。 Abstract: The effect of non-metallic residues of waste printed circuit boards on the hydration process, compressive strength, and crystal morphology of magnesium oxychloride cement are investigated. By using the SEM, its retarding mechanism is also studied. The results indicate that the addition of non-metallic residues can lead to the delay in the hydration heat evolution. It can also decrease the hydration ratio at in the early stage and delay the prolong induction period of magnesium oxychloride cement. Non-metallic residues has a major effect on the crystal morphology of magnesium oxychloride cement, it can make the crystal sizes larger. Retardation to magnesium oxychloride cement is caused by a variety of ways with the non-metallic residues. When the content of non-metallic residue is more than 15%, the compressive strength decreases quickly.
英文名 : Influence of Non-metallic Residues of Waste Printed Circuit Board as Filling Material on Performance of Magnesium Oxychloride Ce
刊期 : 2017年第8期
关键词 : 废弃线路板;非金属残渣;镁质胶凝材料;水化过程;晶体形貌
Key words : Waste printed circuit boards; Non-metallic residues; Magnesium oxychloride cement; Hydration process; Crystal morphology
刊期 : 2017年第8期
DOI :
文章编号 : 1000-4637(2017)08-87-04
基金项目 :
作者 : 王祖润,杜 中,张永贵,余学飞
单位 : 中国建材检验认证集团安徽有限公司,合肥市环境监测站,230051)

王祖润,杜 中,张永贵,余学飞

王祖润,杜中,张永贵,等.废弃线路板非金属残渣作填充料对镁质胶凝材料性能的影响[J].混凝土与水泥制品,2017(8):87-90.

WANG Z R, DU Z, ZHANG Y G,et al.Influence of Non-metallic Residues of Waste Printed Circuit Board as Filling Material on Performance of Magnesium Oxychloride Cement[J].China Concrete and Cement Products,2017(8):87-90.

摘要
参数
结论
参考文献
引用本文

摘   要:研究了废弃线路板非金属残渣对镁质胶凝材料的水化过程、抗压强度、镁质胶凝材料晶体形貌的影响,结合扫描电镜对其反应机理进行了分析。结果表明,非金属残渣能抑制镁质胶凝材料的早期水化,使水化放热减缓,早期水化率降低,凝结时间延长;非金属残渣对镁质胶凝材料晶体形貌影响较大,使镁质胶凝材料晶体尺寸明显增大;非金属残渣通过多种途径的作用对镁质胶凝材料产生了缓凝作用。当非金属残渣掺量超过15%时,抗压强度下降较大。

Abstract: The effect of non-metallic residues of waste printed circuit boards on the hydration process, compressive strength, and crystal morphology of magnesium oxychloride cement are investigated. By using the SEM, its retarding mechanism is also studied. The results indicate that the addition of non-metallic residues can lead to the delay in the hydration heat evolution. It can also decrease the hydration ratio at in the early stage and delay the prolong induction period of magnesium oxychloride cement. Non-metallic residues has a major effect on the crystal morphology of magnesium oxychloride cement, it can make the crystal sizes larger. Retardation to magnesium oxychloride cement is caused by a variety of ways with the non-metallic residues. When the content of non-metallic residue is more than 15%, the compressive strength decreases quickly.


关键词:
废弃线路板;非金属残渣;镁质胶凝材料;水化过程;晶体形貌
扫二维码用手机看
未找到相应参数组,请于后台属性模板中添加
(1)非金属残渣对镁质胶凝材料具有一定的缓凝作用,非金属残渣的掺入延长了镁质胶凝材料的凝结时间,并使水化放热速度减缓,在使早期水化率降低的同时,对后期水化率的影响也较小。
(2)镁质胶凝材料晶体形貌在非金属残渣的掺入后发生了较多的改变,且通过电镜图片发现非金属残渣的掺加能明显增加其最终的晶体尺寸。
(3)镁质胶凝材料在非金属残渣的多种途径作用下,可产生缓凝作用,非金属残渣树脂中的一些活性基团,如羟基、羧基等的选择性吸附使晶核的生长被抑制,并使晶核的形成减缓,对镁质胶凝材料的水化产生了一定的妨碍,另外,树脂也对镁质胶凝材料的5·1·8相晶体起到了胶体包裹的作用,抑制了晶核在a轴和b轴方向的生长。
(4)非金属残渣中的玻璃纤维易在镁质胶凝材料晶体水化过程中形成团聚现象,使材料内部产生应力集中区域,造成材料内部的缺陷。当非金属残渣掺量为15%时,这种团聚现象还不是特别明显,形成的孔洞不多,对强度的影响不大,但当掺量超过15%之后,团聚现象变多,形成的孔洞数量变多,导致抗压强度下降明显。
[1] Ogunseitan,O A Schoenung, M J Saphores,et al. The elect ronics revolution:from e-wonderland to e-wasteland[J]. Science,2009,326:670-671.
[2] Widmer R, Oswald-Krapf, H Sinha-Khetriwal, et al. Global perspectives on e-waste.Environ[J].Impact Assess.Rev,2005,25 (5):436-458.
[3] Saphores, J.D.M,Nixon,et al. How much e-waste is there in US basements and attics Results from a national survey[J].J. Environ. Manage,2009,90 (11):3322-3331.
[4] UNU. 2007 Review of Directive 2002/96 on Waste Elect rical and Electronic Equipment(WEEE)[C].Final Report to European Commission, Bonn,2007.
[5] Cui J.,Forssberg,E.Mechanical recycling of waste electric and electronic equipment: a review[J].J.Hazard.Mater,2003,99 (3):243-263.
[6] Veit H.M.,Pernardes C.D.Bernardes A. M. Using mechanical processing in recycling printed wiring boards[J].JOM.2002,54(6):45-47.
[7] 胡天觉,曾光明,袁兴中.从家用电器废物中回收贵金属[J].中国资源综合利用,2001(7):12-15.
[8] Sakai S.,Watanabe J.,Honda Y,et al. Combustion of bromina ted flame retardants and behavior of its byproducts[J]. Chemos phere,2001,42(5-7):519-531.
[9] Mecucci A.,Scott K. Leaching and electrochemical recovery of copper, lead and tin from scrap printed circuit boards[J].J. Chem. Technol. Biotechnol,2002,77(4):449-457.
[10] Quinet P.,Proost J.,Van Lierde A. Recovery of precious metals from electronic scrap by hydrometallurgical processing routes[J].Miner. Metall. Process,2005,22(1):17-22.
[11] Oishi T.,Koyama K.,Alam S,et al.Recovery of high purity copper cathode from printed circuit boards using ammoniacal sulfate or chloride solutions[J].Hydrometallurgy,2007,89:82-88.
[12] 李颖,余红发,董金美,等.镁质胶凝材料的水化产物、相转变规律和抗水性评价方法的研究进展[J].硅酸盐学报,2013(11):1465-1473.
[13] DINNEBIER R E, OESTREICH M, BETTE S, et al. 2Mg(OH)2·MgCl2·2H2O and 2Mg(OH)2·MgCl2·4H2O, two high temperature phases of the magnesia cement system [J]. Z ZAnorgAllgChem, 2012,638(3-4):628-633.
[14] DEWOLFF P M, WALTERLEVY L. The crystal structure of Mg2(OH)3(Cl,Br)·4H2O[J].ActaCrystallogr,1953,6(1):40-44.
[15] SATO H, MORITA A, ONO K, et al. Templating effects on the mineralization of layered inorganic compounds:(1)density functional calculations of the formation of single-layered magnesium hydroxide as a brucite model[J].Langmuir,2003,19(17):7120-7126.
[16] ZHANG Z Y, DAI C L, ZHANG Q C, et al. Formation mechanism on phase 5 and phase 3[J].Sci China Chem,1991,34(12):1501-1509.
[17] JEEVANANDAM P, MULUKUTLA R S, YANG Z, et al. Nanocrystals to nanorods: A precursor approach for the syn thesis of magnesium hydroxide nanorods from magnesium oxych loridenanorods starting from nanocrystalline magnesium oxide [J].Chem Mater,2007,19(22):5395-5403.
[18] 王佩玲,王心磊,黄月鸿,等.氯镁水泥硬化体的显微结构及结构强度[J].无机材料学报,1990,5(1):61-67.
[19] 文静,余红发,吴成友,等.镁质胶凝材料水化历程的影响因素及水化动力学[J].硅酸盐学报,2013,41(5):588-596.
[20] SUGIMOTO K, DINNEBIER R E, SCHLECHT T. Structure determination of Mg3(OH)5Cl·4H2O ( F5 phase ) from laboratory powder diffraction data and its impact on the analysis of problematic magnesia floors[J]. ActaCrystallogra Sect B-Struct Sci,2007,63:805-811.
 

王祖润,杜中,张永贵,.废弃线路板非金属残渣作填充料对镁质胶凝材料性能的影响[J].混凝土与水泥制品,2017(8):87-90.

WANG Z R, DU Z, ZHANG Y G,et al.Influence of Non-metallic Residues of Waste Printed Circuit Board as Filling Material on Performance of Magnesium Oxychloride Cement[J].China Concrete and Cement Products,2017(8):87-90.

相关文件

暂时没有内容信息显示
请先在网站后台添加数据记录。

关注《混凝土与水泥制品》

总访问量 468,401   网站统计

官方微信公众号关闭
苏州混凝土水泥制品研究院有限公司

关于我们    |    联系我们    |    订购杂志    |    回到顶部

版权所有:中国混凝土与水泥制品网  苏ICP备10086386号   网站建设:中企动力 苏州

版权所有:中国混凝土与水泥制品网

苏ICP备10086386号

网站建设:中企动力 苏州