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聚酰胺热熔胶水泥砂浆的基本性能研究
Study on Basic Performance of Cement Mortar with Polyamides (PA) Hot-melt Adhesive
2016年第2期
PA热熔胶;力学性能;耐久性能;热循环;自修复
PA hot-melt adhesive; Mechanical property; Durability; Heat cycle; Self-healing
2016年第2期
1000-4637(2016)02-06-05
中国博士后基金项目(2013M531875);国家自然科学基金项目(51308344)。
袁雄洲1,3,孙 伟2,邢 锋1,3,徐畏婷1
1. 深圳信息职业技术学院,518172;2. 东南大学材料科学与工程学院,南京 211189; 3. 深圳大学土木工程学院,518060

袁雄洲1,3,孙 伟2,邢 锋1,3,徐畏婷1

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摘  要:形状记忆合金(SMA)驱动下热熔胶水泥基材料具有优良的自修复能力。本文对聚酰胺热熔胶水泥砂浆(PA砂浆)的工作性能、力学性能和耐久性能以及处于多次热循环条件下PA砂浆的力学性能及耐久性能进行了研究。结果表明,体积掺量1%、3%和5%热熔胶的掺入没有降低砂浆的工作性能,反而有略微的提升;随聚酰胺(PA)掺量的增加,砂浆的抗压强度和抗渗性能略有下降,而抗折强度随掺量的增加先增后减;热循环环境中PA水泥砂浆的力学性能与耐久性能都得到了很大的提升,说明PA水泥砂浆在常温马氏体状态、具有预应变的SMA的驱动下具备反复修复水泥基裂缝的潜力。Abstract:Recentresearchesresultsshowthat,whendrivenbyshapememoryally(SMA),hot-meltadhesivehavegoodself-healingproperties.Inthisarticle,theeffectsofaddingPAhot-meltadhesiveonthepropertiesofcementmortar,suchasworkingperformance,macroscopicmechanicalpropertiesanddurabilitywereinvestigated.Andthermalpropertiesofhot-meltadhesivecontainedcementmortarwerealsostudied.Experimentalresultsshowthathot-meltadhesivecanimprovetheworkabilityofmotar,andthepromotioneffectwillbeenhancedbytheincreaseofhot-meltadhesivedosage.However,theadditionofhot-meltadhesivewillleadtothedegradationofcompressivestrengthanddurability.Moreover,theappropriatecontentofthehot-meltadhesive(Vf<5%)canconsiderablyimprovetheflexuralstrengthofspecimens.Incontrasttoordinarycement-basedmaterials,macroscopicmechanicalproperties,especiallytoughness,anddurabilityofspecimenscontaininghot-meltadhesivearegreatlyenhancedafterbeingexposedtothermalcyclicenvironments.SoaconclusioncanbedrawnthatPAhot-meltadhesivemayrepaircrackincementitiousmaterialsrepeatedlycoupledwithSMA.
英文名 : Study on Basic Performance of Cement Mortar with Polyamides (PA) Hot-melt Adhesive
刊期 : 2016年第2期
关键词 : PA热熔胶;力学性能;耐久性能;热循环;自修复
Key words : PA hot-melt adhesive; Mechanical property; Durability; Heat cycle; Self-healing
刊期 : 2016年第2期
DOI :
文章编号 : 1000-4637(2016)02-06-05
基金项目 : 中国博士后基金项目(2013M531875);国家自然科学基金项目(51308344)。
作者 : 袁雄洲1,3,孙 伟2,邢 锋1,3,徐畏婷1
单位 : 1. 深圳信息职业技术学院,518172;2. 东南大学材料科学与工程学院,南京 211189; 3. 深圳大学土木工程学院,518060

袁雄洲1,3,孙 伟2,邢 锋1,3,徐畏婷1

摘要
参数
结论
参考文献
引用本文

摘   要:形状记忆合金(SMA)驱动下热熔胶水泥基材料具有优良的自修复能力。本文对聚酰胺热熔胶水泥砂浆(PA砂浆)的工作性能、力学性能和耐久性能以及处于多次热循环条件下PA砂浆的力学性能及耐久性能进行了研究。结果表明,体积掺量1%、3%和5%热熔胶的掺入没有降低砂浆的工作性能,反而有略微的提升;随聚酰胺(PA)掺量的增加,砂浆的抗压强度和抗渗性能略有下降,而抗折强度随掺量的增加先增后减;热循环环境中PA水泥砂浆的力学性能与耐久性能都得到了很大的提升,说明PA水泥砂浆在常温马氏体状态、具有预应变的SMA的驱动下具备反复修复水泥基裂缝的潜力。

Abstract: Recent researches results show that, when driven by shape memory ally (SMA), hot-melt adhesive have good self-healing properties. In this article, the effects of adding PA hot-melt adhesive on the properties of cement mortar, such as working performance, macroscopic mechanical properties and durability were investigated. And thermal properties of hot-melt adhesive contained cement mortar were also studied. Experimental results show that hot-melt adhesive can improve the workability of motar, and the promotion effect will be enhanced by the increase of hot-melt adhesive dosage. However, the addition of hot-melt adhesive will lead to the degradation of compressive strength and durability. Moreover, the appropriate content of the hot-melt adhesive (Vf<5%) can considerably improve the flexural strength of specimens. In contrast to ordinary cement-based materials, macroscopic mechanical properties, especially toughness, and durability of specimens containing hot-melt adhesive are greatly enhanced after being exposed to thermal cyclic environments. So a conclusion can be drawn that PA hot-melt adhesive may repair crack in cementitious materials repeatedly coupled with SMA.

关键词:
PA热熔胶;力学性能;耐久性能;热循环;自修复
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(1)PA热熔胶的掺入有助于增强砂浆的工作性能,砂浆的工作性能随掺量的增加而提升,掺量5%时砂浆的工作性能可提升13.21%。
(2)PA热熔胶试件的抗压强度与初期表面吸水性能均比不掺热熔胶的基准试件低,且性能的降低随掺量的增加而加剧,掺量5%时砂浆的抗压强度降低了19.85%。然而,适量热熔胶的掺入能够提高材料的韧性,这是因为热熔胶能够发挥柔性中心质的作用,减小材料内部的应力集中,同时实现应变能的转化。
(3)经受过热循环的PA试件,其抗压强度变化不大,而抗折性能与ISAT性能得到了很大的提升;性能提升幅度随着PA掺量的增加而增大。经历三次热循环、掺量5%的试件抗折强度增加了32.65%,ISAT性能增强了47.73%。性能改善的原因是高温环境改变了热熔胶-水泥基材料之间的界面,以及在高温环境中热熔胶颗粒融化并修复了周围的缺陷。
(4)尽管标养试件的抗压强度与ISAT性能因为热熔胶的掺入而有所下降,但本文采用的是高强砂浆,试件的抗压强度和ISAT性能表现还是比较理想的。此外,PA水泥砂浆在反复受热的条件下各项性能不降反升,因此,在优选热熔胶掺量和尺寸的前提下,PA水泥砂浆在常温马氏体状态、具有预应变的SMA的驱动下具备反复修复水泥基裂缝的潜力。
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