基于牺牲阳极法的LiBr改性砂浆性能研究
Study on the Performance of LiBr Modified Mortar Based on Sacrificial Anode Method
浏览量:
关键词:
牺牲阳极;导电砂浆;LiBr;电阻率;阳极活性
Key words:
Sacrificial anode; Conductive mortar; Lithium bromide; Resistivity; Anode activity
刊期:
2020年3期 No.287 P24-26+30
DOI:
10.19761/j.1000-4637.2020.03.024.04
文章编号:
基金项目:
国家自然科学基金资助项目(21576300)。
作者:
张东方1,2,3;方 翔1,2;范志宏1,2;陈 龙1,2;王 毅3
单位:
1.水工构造物耐久性技术交通运输行业重点实验室,广州 510230;2.中交四航工程研究院有限 公司,广州 510230;3.中山大学化学工程与技术学院,珠海519082
摘要
摘要: 通过掺入LiBr制备了高活性导电砂浆,研究了LiBr掺量与砂浆电阻率及阳极活性之间的关系。结果表明:LiBr能显著降低砂浆的电阻率,并随掺量增加电阻率降低。当掺量为160 g时,砂浆的电阻率小于100 Ω·cm。LiBr的掺入能够活化阳极及促进溶解产物扩散,使阳极具备可持续发出保护电流的能力。
Abstract: High active conductive mortar was prepared by adding LiBr, and the relationship between the content of lithium bromide and the resistivity of mortar and anodic activity was systematically studied. The results show that the resistivity decreases with increasing the content of lithium bromide, and the resistivity is less than 100 Ω·cm when the content is 160 g. Moreover, the addition of lithium bromide helps to activate the anode and promote the diffusion of dissolved products, thus enable anode to generate a continuous protective current.
结论
(1)掺LiBr活性组分能够显著改善砂浆导电性,并且随掺量增加砂浆电阻率逐渐降低,LiBr高掺量160 g的砂浆导电性几乎不受龄期影响。
(2)砂浆内LiBr通过提升锌牺牲阳极表面反应活性及输送阳极溶解产物使阳极具备可持续发出保护电流的能力
参考文献
[1] VASHI R T,KADIYA H K.Corrosion Study of Metals in Marine Environment [J].E-JOURNAL OF CHEMISTRY,2009,6(4):1240-1246.
[2] MELCHERS R E.Extreme value statistics and long-term marine pitting corrosion of steel [J].Probabilistic Engineering Mechanics,2008,23(4):482-488.
[3] SHEHADEH M.Study of sacrificial cathodic protection on marine structures in sea and fresh water in relation to flow conditions[J].Ships and Offshore Structures,2013,8(1):102-110.
[4] CHEN J,HUANG Y,DONG X.Study on the splash zone corrosion protection of carbon steel by sacrificial anode[J].International Journal of Electrochemical Science,2012,7(5):4114-4120.
[5] WILSON K,JAWED M,NGALA V.The selection and use of cathodic protection systems for the repair of reinforced concrete structures[J].Construction and Building Materials,2013,39:19-25.
[6] XU J,YAO W.Current distribution in reinforced concrete cathodic protection system with conductive mortar overlay anode[J].Construction and Building Materials,2009,23(6):2220-2226.
[7] NORAMBUENA C J,GONZALEZ A,CONCHA J L,et al.Effect of metallic waste addition on the electrical, thermophysical and microwave crack-healing properties of asphalt mixtures[J].Construction and Building Materials,2018,187:1039-1050.
[8] 詹树林,王磊.用于牺牲阳极法的碳纤维导电砂浆的导电性能研究[J].中国水运,2013(1):58-59.
[9] 罗宝,赵若红,袁迪,等.不同施工工艺对钢纤维-石墨导电混凝土薄板电阻率的影响[J].新型建筑材料,2017,44(8):123-126.
[10] 李岩,蔡跃波,葛燕,等.用交流阻抗谱研究活性砂浆胶结材料的电化学行为[J].硅酸盐学报,2013,41(2):199-204.
[11] 中国船舶重工集团公司第七二五所.锌-铝-镉合金牺牲阳极:GB/T 4950—2002[S].北京:中国标准出版社,2002.
引用本文
张东方,方翔,范志宏,等.基于牺牲阳极法的LiBr改性砂浆性能研究[J].混凝土与水泥制品,2020(3):24-26+30.
ZHANG D F,FANG X,FAN Z H,et al.Study on the Performance of LiBr Modified Mortar Based on Sacrificial Anode Method[J].China Concrete and Cement Products,2020(3):24-26+30.
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