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AMPS/NNDMA共聚物和聚羧酸系分散剂在油井水泥中的性能研究
Research on Properties of AMPS/NNDMA Copolymer and PCE Dispersant in Oil Well Cement
2016年第4期
油井水泥;AMPS/NNDMA共聚物;降失水剂;聚羧酸;分散剂
Oil well cement; AMPS/NNDMA copolymer; Fluid loss additive; PCE; Dispersant
2016年第4期
1000-4637(2016)04-17-04
上海建筑外加剂工程技术研究中心能力提升项目(15DZ2282500)
温 虹1,王伟山2,郑柏存2
1.华东理工大学,上海 200237;2.上海建筑外加剂工程技术研究中心,200232

温 虹1,王伟山2,郑柏存2

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摘 要:以不同摩尔比的AMPS/NNDMA二元线性共聚物降失水剂和聚羧酸系分散剂(PCE)作为主要外加剂,研究了其对油井水泥浆抗滤失、流变、稠化、固结等性能的影响。试验结果表明,少量的AMPS/NNDMA共聚物就能有效控制水泥浆抗滤失性能;降失水剂使水泥浆流变性变差,但加入分散剂可大大改善体系流变性;同时两种外加剂复配有一定缓凝作用且稠化时间可调,水泥石强度也满足施工要求;随着NNDMA在降失水剂中含量的增加,水泥浆体系失水量、游离液含量减少,稠度增加,流变性和水泥石强度变差。 Abstract: Different mole ratio of AMPS/NNDMA binary linear copolymer fluid loss reducer and PCE dispersant as the main additives, the oil well cement slurry filtration resistance, rheology, thickening, the influence of consolidation are studied.The results show that the AMPS/NNDMA copolymer under little amount can effectively control the slurry filtration performance and free fluid content. Fluid loss reducer made the bad slurry rheological property, the dispersant can greatly improve the rheological property. With high temperature and high pressure thickening the consistency of cement slurry and thickening time, experiments show that additive offers certain retarding action and adjustable thickening time. By cement compressive strength test, the results show that under the reasonable dosage, cement strength also satisfies the requirement of construction. The increasing of NNDMA in the fluid loss additive reduces water loss and free fluid content, increases the consistency, and leads the poor rheology and strength of cement. In addition, the two additives have good thermal stability and heat resistance &salt resistance.
英文名 : Research on Properties of AMPS/NNDMA Copolymer and PCE Dispersant in Oil Well Cement
刊期 : 2016年第4期
关键词 : 油井水泥;AMPS/NNDMA共聚物;降失水剂;聚羧酸;分散剂
Key words : Oil well cement; AMPS/NNDMA copolymer; Fluid loss additive; PCE; Dispersant
刊期 : 2016年第4期
DOI :
文章编号 : 1000-4637(2016)04-17-04
基金项目 : 上海建筑外加剂工程技术研究中心能力提升项目(15DZ2282500)
作者 : 温 虹1,王伟山2,郑柏存2
单位 : 1.华东理工大学,上海 200237;2.上海建筑外加剂工程技术研究中心,200232

温 虹1,王伟山2,郑柏存2

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参考文献
引用本文

摘   要:以不同摩尔比的AMPS/NNDMA二元线性共聚物降失水剂和聚羧酸系分散剂(PCE)作为主要外加剂,研究了其对油井水泥浆抗滤失、流变、稠化、固结等性能的影响。试验结果表明,少量的AMPS/NNDMA共聚物就能有效控制水泥浆抗滤失性能;降失水剂使水泥浆流变性变差,但加入分散剂可大大改善体系流变性;同时两种外加剂复配有一定缓凝作用且稠化时间可调,水泥石强度也满足施工要求;随着NNDMA在降失水剂中含量的增加,水泥浆体系失水量、游离液含量减少,稠度增加,流变性和水泥石强度变差。

Abstract: Different mole ratio of AMPS/NNDMA binary linear copolymer fluid loss reducer and PCE dispersant as the main additives, the oil well cement slurry filtration resistance, rheology, thickening, the influence of consolidation are studied.The results show that the AMPS/NNDMA copolymer under little amount can effectively control the slurry filtration performance and free fluid content. Fluid loss reducer made the bad slurry rheological property, the dispersant can greatly improve the rheological property. With high temperature and high pressure thickening the consistency of cement slurry and thickening time, experiments show that additive offers certain retarding action and adjustable thickening time. By cement compressive strength test, the results show that under the reasonable dosage, cement strength also satisfies the requirement of construction. The increasing of NNDMA in the fluid loss additive reduces water loss and free fluid content, increases the consistency, and leads the poor rheology and strength of cement. In addition, the two additives have good thermal stability and heat resistance &salt resistance.

关键词:
油井水泥;AMPS/NNDMA共聚物;降失水剂;聚羧酸;分散剂
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(1)AMPS/NNDMA降失水剂与聚羧酸系分散剂配伍性良好,聚羧酸在AMPS水泥浆中分散性良好,同时对其抗滤失性能影响不大。两者都有很好的耐高温耐盐性。
(2)降失水剂抗滤失效果和分散剂改善流变性效果明显,同时降失水剂对控制游离液和增强水泥石强度都有很好的作用,外加剂使水泥浆稠化时间变长。两者合理配比综合性能良好且可调。
(3)降失水剂中NNDMA是主要保水基团,随着其含量增加,体系失水量、游离液含量减少,稠度增加,流变性和水泥石强度变差。
[1] 李晓岚,国安平,孙举,等. 抗高温油井水泥降失水剂的合成及性能评价[J]. 油田化学,2013, 30(2):470-473.
[2] 李焕明,庄稼,张梁. 耐高温耐盐油井水泥降失水剂的合成及性能研究[J].钻井液与完井液,2009,26(5):39-42.
[3] 郭锦棠,周贤明,靳建洲. 抗高温耐盐AMPS/AM/AA降失水剂的合成及其性能表征[J].石油学报,2011,32(3):470-473.
[4] 何英,徐依吉,王槐平. 新型油井水泥分散剂SDJZ-1的研制与应用[J].钻井液与完井液,2005,26(3):18-21.
[5] 易明新. 油井水泥分散剂的研究与应用[J].油田化学,2000(1):82-84.
[6] Wahedi Y A, Bassioni G, Awayes J. Influence of classic and modern superplasticizers on the chemical and rheological behavior of oil well cement :a comparative study [J]. advance in cement research,2011,23(4):175-184.
[7] 段建平,吕生华,高瑞军,等. 减水剂中磺酸基和羧基吸附特点及其影响因素探讨[J].混凝土,2012(1):84-87.
 

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