锌化合物改变水泥混凝土水化历程的研究进展

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锌化合物改变水泥混凝土水化历程的研究进展

Research Progress of the Hydrate Process of Cement Concrete in the Presence of Zinc-compounds

２０18年第3期

锌化合物；水泥混凝土；水化；缓凝效果；固化

Zinc compounds; Cement concrete; Hydrate; Retarding effect; Solidification

２０18年第3期

1000-4637（2018）03-11-05

国家自然科学基金项（51472227）

岳汉威，单文华，赵宝铖，汤军安

中国建筑材料科学研究总院中国建材检验认证集团股份有限公司，北京100024

岳汉威，单文华，赵宝铖，汤军安

岳汉威,单文华,赵宝铖,等.锌化合物改变水泥混凝土水化历程的研究进展[J].混凝土与水泥制品,2018(3):11-15.

YUE H W,SHAN W H,ZHAO B C,et al.Research Progress of the Hydrate Process of Cement Concrete in the Presence of Zinc-compounds[J].China Concrete and Cement Products,2018(3):11-15.

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摘要：随着工业化的发展，大量含锌废物对环境造成了严重污染，采用水泥对含锌废物进行固化是常用的处理办法。而确定锌化合物对水泥水化历程作用的机理是固化利用和建筑功能化应用的前提。本文综述了国内外锌化合物改变水泥水化历程的研究进展，指出了目前研究中存在的不足，并结合研究现状对下阶段研究方向进行了展望。 Abstract: With the development of industrialization, a large number of zinc-containing waste has caused serious pollution to environment. These wastes are usually treated by means of solidification/stabilisation techniques, using cement. The mechanism of the hydration of cement in the presence of zinc-compounds is the prerequisite for the application of cement solidification/stabilisation and building functional application. The research progress of zinc-compounds influencing the hydration process of cement is reviewed. The current problems and the research area in the future are also pointed out.

英文名 : Research Progress of the Hydrate Process of Cement Concrete in the Presence of Zinc-compounds

刊期 : ２０18年第3期

关键词 : 锌化合物；水泥混凝土；水化；缓凝效果；固化

Key words : Zinc compounds; Cement concrete; Hydrate; Retarding effect; Solidification

刊期 : ２０18年第3期

DOI :

文章编号 : 1000-4637（2018）03-11-05

基金项目 : 国家自然科学基金项（51472227）

作者 : 岳汉威，单文华，赵宝铖，汤军安

单位 : 中国建筑材料科学研究总院中国建材检验认证集团股份有限公司，北京100024

岳汉威，单文华，赵宝铖，汤军安

岳汉威,单文华,赵宝铖,等.锌化合物改变水泥混凝土水化历程的研究进展[J].混凝土与水泥制品,2018(3):11-15.

YUE H W,SHAN W H,ZHAO B C,et al.Research Progress of the Hydrate Process of Cement Concrete in the Presence of Zinc-compounds[J].China Concrete and Cement Products,2018(3):11-15.

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摘要

参数

结论

参考文献

引用本文

摘要：随着工业化的发展，大量含锌废物对环境造成了严重污染，采用水泥对含锌废物进行固化是常用的处理办法。而确定锌化合物对水泥水化历程作用的机理是固化利用和建筑功能化应用的前提。本文综述了国内外锌化合物改变水泥水化历程的研究进展，指出了目前研究中存在的不足，并结合研究现状对下阶段研究方向进行了展望。

Abstract: With the development of industrialization, a large number of zinc-containing waste has caused serious pollution to environment. These wastes are usually treated by means of solidification/stabilisation techniques, using cement. The mechanism of the hydration of cement in the presence of zinc-compounds is the prerequisite for the application of cement solidification/stabilisation and building functional application. The research progress of zinc-compounds influencing the hydration process of cement is reviewed. The current problems and the research area in the future are also pointed out.

关键词:

锌化合物；水泥混凝土；水化；缓凝效果；固化

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（1）作为硅酸盐水泥混凝土缓凝剂，Zn化合物缓凝效果强于传统的有机缓凝剂（羟基羧酸盐等），缓凝稳定性也要比某些无机缓凝剂（如硼化合物等）好得多，但是工程应用非常少见。Zn化合物大都以固体形式存在，尽管某些Zn盐易溶于水，但是与减水剂等水性外加剂复配时稳定性和相容性不理想，单独将固态Zn化合物添加又缺乏充足的研究基础。Zn作为功能性助剂的应用仍处于观望阶段。

（2）与普通硅酸盐水泥相比，铝酸盐水泥和硫铝酸盐水泥用量较少，导致Zn化合物影响其水化历程的研究程度远远不足，从目前少量的研究进展来看，研究结果是一致的。

（3）Zn化合物除了影响水泥的水化历程外，对水泥混凝土的物理力学性能、耐久性和体积稳定性都有积极的改善效果，同时某些Zn化合物（如ZnO、AZO等）还具备优异的光催化效果、自清洁性和热电性能，这在提倡建筑功能化的当今，具有实际意义。这些应用效果的实现，都要以确保水泥混凝土正常凝结为前提。铝酸盐水泥和硫铝酸盐水泥具有快凝快硬的特点，其中，硫铝酸盐水泥还具备良好的体积稳定性和耐久性，Zn化合物的存在对其水化历程和凝结时间没有延缓效果，将硅酸盐水泥和铝酸盐水泥/硫铝酸盐水泥进行复配，使二者使用特点有机结合，实现Zn化合物对体系水化进程作用的人为控制，对实现Zn化合物改进水泥混凝土产品功能化应用有实际意义。

（4）综上所述，下阶段Zn化合物与水泥水化的相互作用机理的研究方向可概括如下：①不同掺合料替代水平下，Zn化合物对水泥水化历程的影响；②Zn化合物协同其他功能性助剂（减水剂、阻锈剂、早强剂等）对水泥流变性能和水化历程的影响；③多元体系中（硅酸盐水泥+铝酸盐水泥、硅酸盐水泥+硫铝酸盐水泥等），Zn化合物对水化历程的影响。

[1] 许亚华.电炉粉尘的处理和综合利用[J].钢铁,1996,31(6):66-69.

[2] 彭兵,张传福,彭及.CO还原氧化锌速率的研究[J].中南工业大学学报,2001,32(2):189-191.

[3] 彭兵,张传福,彭及.电弧炉炼钢粉尘的固化处理[J].中南工业大学学报,2000,31(2):124-126.

[4] 林本兰,吴兰兰,崔升,等.新型重金属离子吸附剂的研究进展[J].材料导报:综述篇,2015,29(10):18-23.

[5] Kakali G, Tsivilis S, Tsialtas A. Hydration of ordinary Portland cements made from raw mix containing transition element oxides[J].Cement and Concrete Research,1998,28(3):335-340.

[6] Lai Z Y, LAI X C, Shi JB,et al. Effect of Zn2+ on the early hydration behavior of potassium phosphate based magnesium phosphate cement[J].2016,129:70-78.

[7] Auer S,Kuzel H J, P llmann H, et al.Investigation on msw fly ash treatment by reactive calcium aluminates and phases formed[J].1995,25(6):1347-1359.

[8] Weeks C, Hand R J, Sharp J H.Retardation of cement hydration caused by heavy metals present in ISF slag used as aggregate[J].Cement & Concrete Composites,2008,30:970-978.

[9] Stephan D,Mallmann R, Knfel D, et al.High intakes of Cr, Ni, and Zn in clinker Part II. Influence on the hydration properties[J].1999,29:1959-1967.

[10] Stephan D, Maleki H, Kn fel D, et al.Influence of Cr, Ni, and Zn on the properties of pure clinker phases Part I. C3S[J].1999,29:545-552

[11] Falchi L, Zendri E, Müller U,et al. The influence of water-repellent admixtures on the behavior and the effectiveness of Portland limestone cement mortars[J].Cement & Concrete Composites,2015,59:107-118.

[12] Ataie F F, Juenger M C G, Taylor-Lange S C, et al. Comparison of the retarding mechanisms of zinc oxide and sucrose on cement hydration and interactions with supplementary cementitious materials[J].Cement and Concrete Research,2015,72:128-136.

[13] Ghahari S, Ghafari E, LU N. Effect of ZnO nanoparticleson thermoelectric properties of cement composite for waste heat harvesting[J]. Construction and Building Materials,2017,146:755-763.

[14] 黄稳,余洲,张勇,等.AZO薄膜制备工艺及其性能研究[J],材料导报:综述篇,2012,26(1):35-39.

[15] Nochaiya T, Sekine Y, Choopun S, et al. Microstructure, characterizations, functionality and compressive strength of cement-based materials using zinc oxide nanoparticles as an additive[J]. Journal of Alloys and Compounds,2015,630:1-10.

[16] Liu J T, Xu S L. Influence of nanoparticles on fluidity and mechanical properties of cement mortar[J].Construction and Building Materials,2015,101:892-901.

[17] Rincón O T de, Perez O, Paredes E,et al.Long-term performance of ZnO as a rebar corrosion inhibiter[J].Cement & Concrete Composites,2002,24:79-87.

[18] Arliguie G, Grandet J. Etude de l’hydratation du ciment en presence de zinc influence de la teneur en gypse[J].Cement and Concrete Research,1990,20:346-354.

[19] Kochova K, Schollbach K, Gauvin F, et al. Effect of saccharides on the hydration of ordinary Portland cement[J]. Construction and Building Materials, 2017,150:268-275.

[20] 马保国,张莉,董荣珍,等.锌盐对水泥水化历程的影响[J].建筑材料学报,2004,7(4):442-446.

[21] Trezza M A. Hydration study of ordinary Portland cement in the presence of zine ions[J], Mater. Res,2007,10:331-334.

[22] Olmo I F, Chacon E, Irabien A. Influence of lead, zinc, iron(III) and chromium(III) oxides on the setting time and strength development of Portland cement[J].Cement and Concrete Research,2001,31:1213-1219.

[23] Morrison C, Hooper R, Lardner K. The use of ferro-silicate slag from ISF zinc production as a sand replacement in concrete[J].Cement and Concrete Research,2003,2085-2089.

[24] Sneff L, Tobaldi D M, Rachadel P L, et al. The influence of TiO2 and ZnO powder mixtures on photocatalytic activity and rheological behavior of cement pastes[J].Construction and Buil-ding Materials,2014,65:191-200.

[25] Asavapisit S,Fowler G, Cheeseman C R.Solution chemistry during cement hydration in the presence of metal hydroxide wastes[J].Cement and Concrete Research,1997,27(8):1249-1260.

[26] Rossetti V A, Medlci F. Inertization of toxic metals in cement matrices:effects on hydration , setting and hardening[J]. Cement and Concrete Research,1995,25(6):1147-1152

[27] Bordoloi D, Baruah A CH, Barkakati P, et al. Influence of ZnO on clinkerization and properties of vsk cement[J].Cement and Concrete Research,1998,28(3):329-333.

[28] Gawlicki M, Czamarska D. Effect of ZnO on the hydration of Portland cement[J].Journal of Thermal Analysis,1992,38:2157-2161.

[29] Gineys N, Aouad G, Damidot D.Managing trace elements in Portland cement-Part I: Interactions between cement paste and heavy metals added during mixing as soluble salts[J].Cement & Concrete Composites,2010,32:563-570.

[30] Gineys N, Aouad G, Damidot D. Managing trace elements in Portland cement-Part II:Comparison of two methods to incorporate Zn in a cement[J]. Cement & Concrete Composites, 2011,33:629-636.

[31] Bela d F, Arliguie G, Francois R. Porous structure of the ITZ around galvanized and ordinary steel reinforcements[J]. Cement and Concrete Research,2001,1561-1566.

[32] Ziegler F, Johnson C A. The solubility of cacium zincate(CaZn2(OH)6·2H2O)[J].Cement and Concrete Research,2001,31:1327-1332.

[33] Vargas A S de, Masuero B, Vilela A C F. Investigations on the use of electric-arc furnace dust(EAFD) in Pozzolan-modified Portland cement I(MP) paste[J].Cement and Concrete Research,2006,36:1833-1841.

[34] Evans N D M. Binding mechanisms of radionuclides to cement[J], Cement and Concrete Research,2008,38:543-553.

[35] Arliguie G, Grandet J. Influence de la composition d’un ciment Portland sur son hydratation en presence de zinc[J].Cement and Concrete Research,1990,20:517-524.

[36] Brehm F A, Moraes C A M, Modolo R C E, et al. Oxide zinc addition in cement paste aiming electric arc furnace dust(EFED) recycling[J].Construction and Building Materials, 2017,139:172-182.

[37] Berger S, Coumes C C D, Bescop P L, et al. Hydration of calcium sulfoaluminate cement by a ZnCl2 solution:Investigation at early age[J]. Cement and Concrete Research,2009,39:1180-1187.

[38] 马保国,吴贝,李相国,等.Zn2+对硫铝酸盐和硅酸盐水泥水化性能的影响[J].武汉理工大学学报,2010,32(14):30-34.

[39] Duran A, Sirera R, Pérez-Nicolás M, et al. Study of the early hydration of calcium aluminates in the presence of different metallic salts[J].Cement and Concrete Research, 2016,18:1-15.

[40] Qian G R, Sun D D, Tay J H. Characterization of mercury- and zinc-doped alkali-activated slag matrix[J].Cement and Concrete Research, 2003,1257-1262.

[41] Hamilton I W, Sammes N M. Encapsulation of steel foundry bag house dusts in cement mortar[J]. Cement and Concrete Research,1999,29:55-61.

[42] Al-Zaid R Z, Al-Sugair F H, Al-Negheimish A I. Investigation of potential uses of electric-arc furnace dust(EAFD) in concrete[J].Cement and Concrete Research,1997,27(2):267-278.

[43] Rajeh G F, Al-Zaid R Z, Fauzi A, et al. Performance of optimized electric arc furnace dust-based cementitious matrix compared to conventional supplementary cementitious materials[J].Construction and Building Materials,2016,112:210-221.

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