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发布时间:2020-01-06 00:00:00
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高低温环境下混凝土有机-无机复合抗裂养护剂的制备及性能研究
Preparation and performance study of organic-inorganic composite anti-cracking curing agent for concrete in high and low temperature environments
2024年第12期
有机-无机复合抗裂养护剂;混凝土;保水性能;力学性能;耐久性能;作用机理
Organic-inorganic composite anti-cracking curing agent; Concrete; Water retention; Mechanical property; Durability; Mechanism of action
2024年第12期
10.19761/j.1000-4637.2024.12.001.08
国家自然科学基金项目(52072171)。
吉久发1,叶梦煊2,曹志国1,谷雷雷1,王倩倩2,*
1.中交一公局海威工程建设有限公司,北京 101119;2.南京工业大学 材料科学与工程学院, 江苏 南京 211816

吉久发1,叶梦煊2,曹志国1,谷雷雷1,王倩倩2,*

吉久发,叶梦煊,曹志国,等.高低温环境下混凝土有机-无机复合抗裂养护剂的制备及性能研究[J].混凝土与水泥制品,2024(12):1-8.

JI J F,YE M X,CAO Z G,et al.Preparation and performance study of organic-inorganic composite anti-cracking curing agent for concrete in high and low temperature environments[J].China Concrete and Cement Products,2024(12):1-8.

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摘   要:制备了适用于高低温环境的混凝土有机-无机复合抗裂养护剂(OICCA养护剂),研究了其对混凝土保水性能、力学性能及耐久性能的影响,并与两种市售养护剂(E-201、TSD)进行了对比,分析了其作用机理。结果表明:在40 ℃高温和-8 ℃低温环境下,与未涂覆养护剂的空白组相比,涂覆OICCA养护剂试件的抗裂性能显著提高;涂覆养护剂有效提高了混凝土的保水性能、力学性能及耐久性能;与E-201、TSD养护剂相比,OICCA养护剂的养护效果总体上相对较好;OICCA养护剂中的有机组分能使其成膜效果较好,无机组分能与水泥水化产物反应生成结晶物质密实孔隙,二者协同作用提升了混凝土的性能。 A concrete organic-inorganic composite anti-cracking curing agent(OICCA curing agent) suitable for high and low temperature environments was prepared. Its effects on the water retention, mechanical properties, and durability of concrete were studied, and compared with two commercially available curing agents(E-201, TSD) to analyze their mechanisms of action. The results show that under high temperature of 40 ℃ and low temperature of -8 ℃, compared with the blank group without coating curing agent, the crack resistance of OICCA curing agent coated specimens is significantly improved. The application of curing agents effectively improves the water retention, mechanical properties, and durability of concrete. Compared with E-201 and TSD curing agents, OICCA curing agent has a relatively better overall curing effect. The organic components in OICCA curing agent can achieve better film-forming effect, while the inorganic components can react with cement hydration products to form crystalline substances and compact pores. The synergistic effect of the two enhances the performance of concrete.
英文名 : Preparation and performance study of organic-inorganic composite anti-cracking curing agent for concrete in high and low temperature environments
刊期 : 2024年第12期
关键词 : 有机-无机复合抗裂养护剂;混凝土;保水性能;力学性能;耐久性能;作用机理
Key words : Organic-inorganic composite anti-cracking curing agent; Concrete; Water retention; Mechanical property; Durability; Mechanism of action
刊期 : 2024年第12期
DOI : 10.19761/j.1000-4637.2024.12.001.08
文章编号 :
基金项目 : 国家自然科学基金项目(52072171)。
作者 : 吉久发1,叶梦煊2,曹志国1,谷雷雷1,王倩倩2,*
单位 : 1.中交一公局海威工程建设有限公司,北京 101119;2.南京工业大学 材料科学与工程学院, 江苏 南京 211816

吉久发1,叶梦煊2,曹志国1,谷雷雷1,王倩倩2,*

吉久发,叶梦煊,曹志国,等.高低温环境下混凝土有机-无机复合抗裂养护剂的制备及性能研究[J].混凝土与水泥制品,2024(12):1-8.

JI J F,YE M X,CAO Z G,et al.Preparation and performance study of organic-inorganic composite anti-cracking curing agent for concrete in high and low temperature environments[J].China Concrete and Cement Products,2024(12):1-8.

摘要
参数
结论
参考文献
引用本文

摘   要:制备了适用于高低温环境的混凝土有机-无机复合抗裂养护剂(OICCA养护剂),研究了其对混凝土保水性能、力学性能及耐久性能的影响,并与两种市售养护剂(E-201、TSD)进行了对比,分析了其作用机理。结果表明:在40 ℃高温和-8 ℃低温环境下,与未涂覆养护剂的空白组相比,涂覆OICCA养护剂试件的抗裂性能显著提高;涂覆养护剂有效提高了混凝土的保水性能、力学性能及耐久性能;与E-201、TSD养护剂相比,OICCA养护剂的养护效果总体上相对较好;OICCA养护剂中的有机组分能使其成膜效果较好,无机组分能与水泥水化产物反应生成结晶物质密实孔隙,二者协同作用提升了混凝土的性能。

A concrete organic-inorganic composite anti-cracking curing agent(OICCA curing agent) suitable for high and low temperature environments was prepared. Its effects on the water retention, mechanical properties, and durability of concrete were studied, and compared with two commercially available curing agents(E-201, TSD) to analyze their mechanisms of action. The results show that under high temperature of 40 ℃ and low temperature of -8 ℃, compared with the blank group without coating curing agent, the crack resistance of OICCA curing agent coated specimens is significantly improved. The application of curing agents effectively improves the water retention, mechanical properties, and durability of concrete. Compared with E-201 and TSD curing agents, OICCA curing agent has a relatively better overall curing effect. The organic components in OICCA curing agent can achieve better film-forming effect, while the inorganic components can react with cement hydration products to form crystalline substances and compact pores. The synergistic effect of the two enhances the performance of concrete.

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(1)当丙烯酸乳液和石蜡乳液的质量比例为5∶10、成膜助剂掺量为0.6%时,所制备的OICCA养护剂的保水性能及成膜性能最佳。
(2)涂覆养护剂可有效提高混凝土的保水性能,与E-201和TSD养护剂相比,OICCA养护剂的保水效果显著,保水率达到66.25%。
(3)涂覆养护剂有效提高了混凝土在高、低温环境下的抗裂性能。与E-201养护剂相比,OICCA养护剂对高温下混凝土抗裂性能的提高效果更好,但可能会导致低温下混凝土的抗裂性能略有降低。
(4)涂覆养护剂可显著提升混凝土的力学性能,但与标准养护相比,涂覆养护剂养护试件的抗压强度略低。3种养护剂中,OICCA和E-201养护剂养护试件的抗压强度相近,与之相比,TSD养护剂养护试件的抗压强度较低。另外,由回弹强度计算得到的养护效率指数可知,OICCA养护剂的养护效率指数高于E-201和TSD养护剂。
(5)涂覆养护剂有效降低了混凝土的表面吸水速率,且与标准养护相比,OICCA养护剂养护试件28 d的表面吸水速率较低。与OICCA和E-201养护剂相比,TSD养护剂养护试件的表面吸水速率较高。
(6)涂覆养护剂能提高混凝土的抗渗性能,但养护剂养护效果不如标准养护效果。3种养护剂中,OICCA养护剂对混凝土抗渗性能的提高效果最好,其次为E-201养护剂,最后为TSD养护剂。
(7)OICCA养护剂中的无机渗透增密组分和有机成膜组分协同作用,不仅在混凝土塑性收缩阶段起到了保水防裂作用,而且在混凝土服役阶段起到了一定的外防护作用,从而提升了混凝土的养护效果和耐久性能。

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吉久发,叶梦煊,曹志国,.高低温环境下混凝土有机-无机复合抗裂养护剂的制备及性能研究[J].混凝土与水泥制品,2024(12):1-8.

JI J F,YE M X,CAO Z G,et al.Preparation and performance study of organic-inorganic composite anti-cracking curing agent for concrete in high and low temperature environments[J].China Concrete and Cement Products,2024(12):1-8.

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